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| # | Player | Wins | Losses | Percentage |
|---|---|---|---|---|
| 1 |  Bjorn Borg | 141 | 17 | 89.24% |
| 2 |  Novak Djokovic | 400 | 55 | 87.91% |
| 3 |  Rafael Nadal | 314 | 44 | 87.71% |
| 4 | Carlos Alcaraz | 88 | 13 | 87.13% |
| 5 |  Roger Federer | 369 | 60 | 86.01% |
| 6 |  Rod Laver | 60 | 10 | 85.71% |
| 7 |  Pete Sampras | 203 | 38 | 84.23% |
| 8 | Ken Rosewall | 92 | 19 | 82.88% |
| 9 | Jimmy Connors | 233 | 49 | 82.62% |
| 10 | Ivan Lendl | 222 | 49 | 81.92% |
| 11 |  Jannik Sinner | 90 | 20 | 81.82% |
| 12 | John Newcombe | 93 | 21 | 81.58% |
| 13 | John McEnroe | 167 | 38 | 81.46% |
| 14 | Andre Agassi | 224 | 53 | 80.87% |
| 15 |  Boris Becker | 163 | 40 | 80.30% |
| 16 | Mats Wilander | 144 | 37 | 79.56% |
| 17 | Stefan Edberg | 178 | 47 | 79.11% |
| 18 | Arthur Ashe | 106 | 28 | 79.10% |
| 19 |  Andy Murray | 200 | 57 | 77.82% |
| 20 | Jim Courier | 118 | 38 | 75.64% |