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| # | Player | Wins | Losses | Percentage |
|---|---|---|---|---|
| 1 |  Roger Federer | 188 | 27 | 87.44% |
| 2 |  Rafael Nadal | 164 | 27 | 85.86% |
| 3 |  Joachim Johansson | 6 | 1 | 85.71% |
| 4 |  Novak Djokovic | 118 | 20 | 85.51% |
| 5 | Carlos Alcaraz | 64 | 12 | 84.21% |
| 6 |  Pete Sampras | 88 | 17 | 83.81% |
| 7 |  Jannik Sinner | 63 | 13 | 82.89% |
| 8 |  Boris Becker | 100 | 24 | 80.65% |
| 9 | Stefan Edberg | 86 | 22 | 79.63% |
| 10 |  Juan Martin del Potro | 90 | 25 | 78.26% |
| 11 | Ivan Lendl | 76 | 24 | 76.00% |
| 12 | Andy Roddick | 65 | 21 | 75.58% |
| 13 |  Nick Kyrgios | 42 | 14 | 75.00% |
| 14 |  Danie Visser | 3 | 1 | 75.00% |
| 15 |  Arthur Fils | 24 | 9 | 72.73% |
| 16 |  Andy Murray | 105 | 40 | 72.41% |
| 17 | Robin Soderling | 42 | 16 | 72.41% |
| 18 |  Daniil Medvedev | 89 | 34 | 72.36% |
| 19 | Andre Agassi | 78 | 30 | 72.22% |
| 20 | Michael Stich | 61 | 24 | 71.76% |