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| # | Player | Wins | Losses | Percentage |
|---|---|---|---|---|
| 1 |  Pieter Aldrich | 6 | 1 | 85.71% |
| 2 |  Pete Sampras | 177 | 34 | 83.89% |
| 3 | Andy Roddick | 214 | 47 | 81.99% |
| 4 | Andre Agassi | 188 | 48 | 79.66% |
| 5 |  Roger Federer | 195 | 50 | 79.59% |
| 6 |  Novak Djokovic | 109 | 28 | 79.56% |
| 7 |  Rafael Nadal | 125 | 39 | 76.22% |
| 8 |  Lleyton Hewitt | 219 | 69 | 76.04% |
| 9 |  Thomas Muster | 266 | 87 | 75.35% |
| 10 |  Andy Murray | 142 | 47 | 75.13% |
| 11 | Michael Chang | 217 | 72 | 75.09% |
| 12 |  Franco Agamenone | 3 | 1 | 75.00% |
| 13 |  Stefan Edberg | 98 | 34 | 74.24% |
| 14 | Carlos Alcaraz | 23 | 8 | 74.19% |
| 15 |  Juan Martin del Potro | 111 | 42 | 72.55% |
| 16 | Matteo Berrettini | 73 | 28 | 72.28% |
| 17 |  Daniil Medvedev | 87 | 34 | 71.90% |
| 18 |  Jo-Wilfried Tsonga | 138 | 54 | 71.88% |
| 19 | Jim Courier | 112 | 44 | 71.79% |
| 20 | Jack Draper | 28 | 11 | 71.79% |