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| # | Player | Wins | Losses | Percentage |
|---|---|---|---|---|
| 1 |  Grigor Dimitrov | 5 | 0 | 100.00% |
| 2 |  Jannik Sinner | 15 | 2 | 88.24% |
| 3 |  Ilie Nastase | 22 | 3 | 88.00% |
| 4 |  Tom Okker | 4 | 1 | 80.00% |
| 5 |  Rod Laver | 4 | 1 | 80.00% |
| 6 |  Ivan Lendl | 39 | 10 | 79.59% |
| 7 |  Roger Federer | 59 | 17 | 77.63% |
| 8 | Gene Mayer | 3 | 1 | 75.00% |
| 9 | Jakob Hlasek | 3 | 1 | 75.00% |
| 10 |  Novak Djokovic | 50 | 18 | 73.53% |
| 11 |  Boris Becker | 36 | 13 | 73.47% |
| 12 |  Bjorn Borg | 16 | 6 | 72.73% |
| 13 | Brian Gottfried | 8 | 3 | 72.73% |
| 14 | Lleyton Hewitt | 13 | 5 | 72.22% |
| 15 | Pete Sampras | 35 | 14 | 71.43% |
| 16 | Stan Smith | 13 | 6 | 68.42% |
| 17 |  Wayne Ferreira | 2 | 1 | 66.67% |
| 18 | John McEnroe | 19 | 11 | 63.33% |
| 19 |  Alex Corretja | 5 | 3 | 62.50% |
| 20 | Michael Stich | 5 | 3 | 62.50% |