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| # | Player | Wins | Losses | Percentage |
|---|---|---|---|---|
| 1 |  Rafael Nadal | 410 | 90 | 82.00% |
| 2 |  Novak Djokovic | 418 | 95 | 81.48% |
| 3 |  Roger Federer | 381 | 108 | 77.91% |
| 4 | Carlos Alcaraz | 84 | 24 | 77.78% |
| 5 |  Jannik Sinner | 94 | 29 | 76.42% |
| 6 |  Paul Kilderry | 3 | 1 | 75.00% |
| 7 |  Andre Agassi | 209 | 73 | 74.11% |
| 8 |  Valentin Vacherot | 11 | 4 | 73.33% |
| 9 | Pete Sampras | 190 | 70 | 73.08% |
| 10 |  Stefan Edberg | 108 | 42 | 72.00% |
| 11 |  Alexander Zverev | 163 | 70 | 69.96% |
| 12 |  Guillermo Coria | 72 | 31 | 69.90% |
| 13 |  Andy Murray | 230 | 101 | 69.49% |
| 14 | Boris Becker | 97 | 43 | 69.29% |
| 15 |  Thomas Muster | 101 | 45 | 69.18% |
| 16 | Andy Roddick | 157 | 70 | 69.16% |
| 17 |  Marcelo Rios | 105 | 48 | 68.63% |
| 18 |  Jakub Mensik | 21 | 10 | 67.74% |
| 19 |  Daniil Medvedev | 121 | 58 | 67.60% |
| 20 | Mikael Pernfors | 10 | 5 | 66.67% |