| 2013-02-01 | Davis Cup WG R1: USA vs BRA | Hard | RR | 20 |  Sam Querrey | 141 |  Thiago Alves | 4-6 6-3 6-4 7-6(3) | H2H | 5 | - | - | - | - | - | - | - |
| 2013-02-01 | Davis Cup WG R1: USA vs BRA | Hard | RR | 16 | John Isner | 141 | Thiago Alves | 6-3 7-6(4) 6-3 | H2H | 5 | - | - | - | - | - | - | - |
| 2012-07-09 | Bastad | Clay | R32 | 435 |  Evgeny Korolev (Q) | 138 | Thiago Alves (Q) | 6-0 6-3 | H2H | 3 | 60 | 4 | 2 | 58.5% | 79.2% | 35.3% | 0/2 |
| 2011-01-31 | Johannesburg | Hard | R32 | 130 |  Simon Greul | 178 | Thiago Alves (LL) | 6-2 7-5 | H2H | 3 | 78 | 9 | 4 | 52.8% | 78.6% | 72.0% | 0/1 |
| 2010-07-25 | Gstaad | Clay | R32 | 59 |  Jarkko Nieminen | 144 | Thiago Alves | 6-4 4-6 6-3 | H2H | 3 | 127 | 8 | 7 | 63.8% | 63.3% | 47.1% | 3/8 |
| 2010-05-24 | Roland Garros | Clay | R128 | 13 |  Fernando Gonzalez (12) | 107 | Thiago Alves (Q) | 6-2 4-6 6-4 6-4 | H2H | 5 | 137 | 21 | 6 | 57.6% | 82.5% | 57.1% | 4/7 |
| 2010-03-11 | Indian Wells Masters | Hard | R128 | 90 | Rainer Schuettler (Q) | 129 | Thiago Alves (Q) | 7-5 6-0 | H2H | 3 | 76 | 5 | 1 | 58.0% | 82.8% | 66.7% | 2/2 |
| 2010-02-08 | Costa do Sauipe | Clay | R32 | 28 | Thomaz Bellucci (3) | 131 | Thiago Alves (WC) | 6-2 7-5 | H2H | 3 | 92 | 10 | 1 | 64.3% | 72.2% | 60.0% | 2/4 |
| 2010-02-01 | Johannesburg | Hard | R16 | 162 |  Somdev Devvarman | 134 | Thiago Alves | 6-4 6-1 | H2H | 3 | 66 | 6 | 0 | 74.5% | 82.9% | 75.0% | 3/3 |
| 2010-02-01 | Johannesburg | Hard | R32 | 134 | Thiago Alves | 115 |  Alexandr Dolgopolov | 5-7 6-2 6-3 | H2H | 3 | 101 | 8 | 3 | 63.4% | 67.8% | 61.8% | 8/10 |
