| R32 | 14 |  Mikhail YouzhnyClay | 149 |  Marc GicquelClay | 6-2 6-2 | 3 | 73 | 5 | 3 | 53.6% | 83.3% | 42.3% | 4/5 |
| R32 | 437 |  Alexander SadeckyClay | 706 | Yann MartiClay | 7-5 1-6 6-0 | 3 | 117 | 3 | 6 | 52.0% | 76.9% | 50.0% | 1/4 |
| R32 | 147 |  Yuri SchukinClay | 37 | Andrey GolubevClay | 7-6(4) 2-6 6-3 | 3 | 123 | 1 | 3 | 53.8% | 74.4% | 62.2% | 2/5 |
| R32 | 83 |  Fred GilClay | 38 |  Tommy RobredoClay | 4-6 7-5 6-1 | 3 | 135 | 0 | 2 | 74.7% | 64.8% | 70.8% | 5/7 |
| R32 | 23 | Albert MontanesClay | 73 | Pere RibaClay | 4-6 6-3 7-6(5) | 3 | 135 | 3 | 3 | 62.6% | 65.7% | 55.0% | 7/12 |
| R32 | 273 |  Andreas Haider-MaurerClay | 53 |  Denis IstominClay | 6-3 6-7(5) 6-4 | 3 | 141 | 8 | 1 | 57.3% | 74.6% | 48.9% | 6/8 |
| R32 | 76 |  Daniel BrandsClay | 93 |  Peter LuczakClay | 6-4 7-5 | 3 | 87 | 15 | 2 | 69.2% | 75.6% | 75.0% | 2/2 |
| R32 | 47 | Richard GasquetClay | 457 | Farrukh DustovClay | 6-3 6-4 | 3 | 78 | 2 | 1 | 59.2% | 72.4% | 95.0% | 0/0 |
| R32 | 74 | Daniel Gimeno-TraverClay | 52 |  Victor HanescuClay | 6-4 6-4 | 3 | 75 | 8 | 1 | 58.3% | 96.4% | 70.0% | 3/3 |
| R32 | 79 | Andreas BeckClay | 676 |  Agustin VelottiClay | 6-3 6-1 | 3 | 70 | 4 | 4 | 54.5% | 87.5% | 60.0% | 0/0 |
| R32 | 88 | Igor AndreevClay | 62 | Florent SerraClay | 6-4 2-6 6-4 | 3 | 104 | 7 | 3 | 60.9% | 66.0% | 55.9% | 7/10 |
| R32 | 63 | Marco ChiudinelliClay | 21 |  Thomaz BellucciClay | 7-6(6) 0-6 6-4 | 3 | 136 | 2 | 6 | 62.8% | 70.4% | 56.3% | 4/7 |
| R32 | 69 | Jeremy ChardyClay | 95 | Paul-Henri MathieuClay | 6-1 6-3 | 3 | 83 | 10 | 5 | 45.9% | 82.1% | 57.6% | 4/4 |
| R32 | 59 |  Jarkko NieminenClay | 144 | Thiago AlvesClay | 6-4 4-6 6-3 | 3 | 127 | 8 | 7 | 63.8% | 63.3% | 47.1% | 3/8 |
| R32 | 209 | Michael LammerClay | 98 |  Dustin BrownClay | 7-5 7-5 | 3 | 85 | 3 | 0 | 64.5% | 77.5% | 72.7% | 2/3 |
| R32 | 18 | Nicolas AlmagroClay | 86 | Marcel GranollersClay | 7-6(5) 3-6 6-3 | 3 | 134 | 8 | 9 | 55.7% | 77.8% | 58.1% | 4/6 |
| R16 | 14 | Mikhail YouzhnyClay | 437 | Alexander SadeckyClay | 7-5 6-4 | 3 | 83 | 7 | 5 | 62.2% | 73.9% | 53.6% | 1/2 |
| R16 | 147 | Yuri SchukinClay | 83 | Fred GilClay | 6-3 6-3 | 3 | 93 | 2 | 4 | 48.4% | 54.8% | 54.5% | 6/9 |
| R16 | 23 | Albert MontanesClay | 273 | Andreas Haider-MaurerClay | 3-6 6-1 6-0 | 3 | 82 | 2 | 1 | 63.6% | 78.6% | 58.3% | 5/6 |
| R16 | 47 | Richard GasquetClay | 76 | Daniel BrandsClay | 6-7(5) 6-3 6-0 | 3 | 96 | 9 | 2 | 59.7% | 82.6% | 67.7% | 1/1 |
| R16 | 74 | Daniel Gimeno-TraverClay | 79 | Andreas BeckClay | 7-5 6-4 | 3 | 90 | 8 | 1 | 60.3% | 71.4% | 73.9% | 1/2 |
| R16 | 88 | Igor AndreevClay | 63 | Marco ChiudinelliClay | 6-3 6-7(6) 7-6(6) | 3 | 149 | 16 | 3 | 56.0% | 78.5% | 52.9% | 9/12 |
| R16 | 69 | Jeremy ChardyClay | 59 | Jarkko NieminenClay | 7-5 6-2 | 3 | 82 | 8 | 3 | 55.7% | 74.4% | 48.4% | 2/4 |
| R16 | 18 | Nicolas AlmagroClay | 209 | Michael LammerClay | 3-6 6-3 6-2 | 3 | 105 | 6 | 4 | 64.9% | 58.3% | 53.8% | 2/7 |
| QF | 147 | Yuri SchukinClay | 14 | Mikhail YouzhnyClay | 6-4 2-6 7-5 | 3 | 133 | 3 | 4 | 70.2% | 69.7% | 46.4% | 4/7 |
| QF | 47 | Richard GasquetClay | 23 | Albert MontanesClay | 7-6(5) 6-4 | 3 | 99 | 9 | 3 | 50.0% | 73.0% | 59.5% | 2/3 |
| QF | 74 | Daniel Gimeno-TraverClay | 88 | Igor AndreevClay | 6-2 6-4 | 3 | 72 | 1 | 2 | 59.6% | 77.4% | 57.1% | 4/5 |
| QF | 18 | Nicolas AlmagroClay | 69 | Jeremy ChardyClay | 6-2 7-6(5) | 3 | 82 | 3 | 2 | 59.7% | 75.0% | 48.1% | 7/9 |
| SF | 47 | Richard GasquetClay | 147 | Yuri SchukinClay | 6-3 6-4 | 3 | 89 | 6 | 6 | 58.3% | 78.6% | 53.3% | 2/2 |
| SF | 18 | Nicolas AlmagroClay | 74 | Daniel Gimeno-TraverClay | 7-6(7) 3-6 6-3 | 3 | 121 | 3 | 3 | 59.8% | 88.5% | 60.0% | 1/2 |
| F | 18 | Nicolas AlmagroClay | 47 | Richard GasquetClay | 7-5 6-1 | 3 | 75 | 17 | 3 | 64.6% | 87.1% | 47.1% | 2/3 |
