| 2012-02-27 | Acapulco | Clay | R32 | 6 |  David Ferrer (1) | 563 |  Santiago Gonzalez (WC) | 6-1 6-2 | H2H | 3 | 65 | 2 | 0 | 67.2% | 64.1% | 73.7% | 5/5 |
| 2011-10-28 | Davis Cup G1 PO: MEX vs COL | Clay | RR | 45 |  Santiago Giraldo | 533 | Santiago Gonzalez | 6-4 7-6(5) 6-2 | H2H | 5 | - | - | - | - | - | - | - |
| 2011-02-21 | Acapulco | Clay | R16 | 6 | David Ferrer (1) | 261 | Santiago Gonzalez (WC) | 6-2 6-2 | H2H | 3 | 52 | 2 | 0 | 61.0% | 76.0% | 81.3% | 0/0 |
| 2011-02-21 | Acapulco | Clay | R32 | 261 | Santiago Gonzalez (WC) | 439 | Daniel Garza (WC) | 6-2 7-6(5) | H2H | 3 | 94 | 8 | 4 | 58.0% | 80.0% | 44.8% | 0/1 |
| 2010-02-22 | Acapulco | Clay | R32 | 81 |  Eduardo Schwank (Q) | 177 | Santiago Gonzalez (WC) | 7-6(4) 7-6(4) | H2H | 3 | 118 | 0 | 3 | 53.2% | 76.2% | 54.1% | 0/2 |
| 2009-06-22 | Wimbledon | Grass | R128 | 46 |  Dudi Sela | 228 | Santiago Gonzalez (Q) | 6-4 4-6 7-6(2) 6-3 | H2H | 5 | 146 | 0 | 4 | 64.1% | 72.0% | 58.7% | 8/12 |
| 2009-03-06 | Davis Cup G2 R1: MEX vs JAM | Clay | RR | 230 | Santiago Gonzalez | - |  Damion Johnson | 6-4 6-2 6-0 | H2H | 5 | - | - | - | - | - | - | - |
| 2009-02-23 | Acapulco | Clay | R32 | 21 | Nicolas Almagro (4) | 231 | Santiago Gonzalez (WC) | 6-4 6-2 | H2H | 3 | 63 | 10 | 0 | 58.7% | 85.2% | 73.7% | 0/0 |
| 2008-02-08 | Davis Cup G1 R1: CAN vs MEX | Carpet | RR | 161 |  Frederic Niemeyer | 482 | Santiago Gonzalez | 6-4 6-4 7-6(1) | H2H | 5 | - | - | - | - | - | - | - |
| 2007-07-20 | Davis Cup G1 PO: MEX vs VEN | Hard | RR | 426 | Santiago Gonzalez | - |  Jhonathan Medina-Alvarez | 6-3 6-2 6-2 | H2H | 5 | - | - | - | - | - | - | - |
