| R32 | 6 |  David FerrerClay | 195 |  Adrian UngurClay | 6-1 6-3 | 3 | 62 | 0 | 1 | 65.3% | 71.9% | 52.9% | 3/4 |
| R32 | 261 |  Santiago GonzalezClay | 439 | Daniel GarzaClay | 6-2 7-6(5) | 3 | 94 | 8 | 4 | 58.0% | 80.0% | 44.8% | 0/1 |
| R32 | 64 |  Pablo CuevasClay | 46 |  Potito StaraceClay | 6-4 6-4 | 3 | 81 | 2 | 1 | 51.9% | 77.8% | 68.0% | 3/4 |
| R32 | 30 |  Juan MonacoClay | 101 | Horacio ZeballosClay | 7-5 7-6(3) | 3 | 139 | 7 | 1 | 53.3% | 75.0% | 57.1% | 3/6 |
| R32 | 15 |  Stan WawrinkaClay | 67 | Pablo AndujarClay | 7-6(5) 3-6 6-0 | 3 | 123 | 3 | 3 | 59.2% | 65.5% | 55.0% | 9/13 |
| R32 | 56 | Fabio FogniniClay | 126 | Maximo GonzalezClay | 6-3 6-4 | 3 | 92 | 1 | 4 | 52.5% | 59.5% | 52.6% | 7/10 |
| R32 | 71 | Carlos BerlocqClay | 146 | Daniel Munoz de la NavaClay | 6-3 5-7 6-1 | 3 | 157 | 2 | 1 | 53.8% | 59.2% | 57.1% | 5/9 |
| R32 | 26 |  Alexandr DolgopolovClay | 171 |  Paul CapdevilleClay | 7-5 6-2 | 3 | 82 | 10 | 5 | 47.4% | 77.8% | 46.7% | 0/2 |
| R32 | 25 | Albert MontanesClay | 59 | Daniel Gimeno-TraverClay | 6-2 6-1 | 3 | 69 | 2 | 3 | 52.0% | 84.6% | 45.8% | 4/5 |
| R32 | 48 |  Santiago GiraldoClay | 111 | Albert Ramos-VinolasClay | 4-6 7-5 7-5 | 3 | 158 | 3 | 1 | 66.0% | 70.6% | 40.0% | 7/11 |
| R32 | 86 | Filippo VolandriClay | 85 |  Fred GilClay | 6-1 3-6 6-4 | 3 | 132 | 0 | 3 | 68.8% | 53.1% | 51.7% | 11/16 |
| R32 | 13 | Nicolas AlmagroClay | 57 | Victor HanescuClay | 6-3 6-2 | 3 | 81 | 5 | 0 | 54.5% | 72.2% | 53.3% | 1/2 |
| R32 | 104 | Eduardo SchwankClay | 31 | Juan Ignacio ChelaClay | 3-6 6-5 RET | 3 | 80 | 4 | 4 | 57.8% | 64.9% | 48.1% | 2/5 |
| R32 | 134 |  Lukasz KubotClay | 75 | Ruben Ramirez HidalgoClay | 7-5 6-0 | 3 | 103 | 4 | 4 | 54.5% | 87.5% | 50.0% | 0/2 |
| R32 | 191 | Ivan NavarroClay | 547 | Manuel SanchezClay | 6-1 3-6 6-1 | 3 | 111 | 4 | 2 | 67.7% | 79.5% | 57.1% | 2/3 |
| R32 | 36 |  Thomaz BellucciClay | 9 | Fernando VerdascoClay | 6-2 4-6 6-3 | 3 | 127 | 6 | 5 | 71.4% | 80.0% | 45.8% | 7/8 |
| R16 | 6 | David FerrerClay | 261 | Santiago GonzalezClay | 6-2 6-2 | 3 | 52 | 2 | 0 | 61.0% | 76.0% | 81.3% | 0/0 |
| R16 | 30 | Juan MonacoClay | 64 | Pablo CuevasClay | 6-3 6-4 | 3 | 106 | 3 | 2 | 59.2% | 75.6% | 41.9% | 5/6 |
| R16 | 15 | Stan WawrinkaClay | 56 | Fabio FogniniClay | 5-7 6-3 7-5 | 3 | 169 | 2 | 3 | 66.4% | 57.7% | 61.1% | 5/10 |
| R16 | 26 | Alexandr DolgopolovClay | 71 | Carlos BerlocqClay | 6-4 6-1 | 3 | 72 | 4 | 0 | 51.2% | 85.7% | 75.0% | 0/0 |
| R16 | 48 | Santiago GiraldoClay | 25 | Albert MontanesClay | 6-3 6-4 | 3 | 78 | 5 | 0 | 55.0% | 84.8% | 63.0% | 6/6 |
| R16 | 13 | Nicolas AlmagroClay | 86 | Filippo VolandriClay | 6-2 6-2 | 3 | 71 | 4 | 0 | 51.8% | 82.8% | 40.7% | 2/3 |
| R16 | 134 | Lukasz KubotClay | 104 | Eduardo SchwankClay | 6-7(8) 6-4 6-4 | 3 | 179 | 4 | 9 | 60.4% | 70.5% | 60.0% | 3/6 |
| R16 | 36 | Thomaz BellucciClay | 191 | Ivan NavarroClay | 1-6 6-4 6-3 | 3 | 140 | 4 | 1 | 61.7% | 70.0% | 61.3% | 1/3 |
| QF | 6 | David FerrerClay | 30 | Juan MonacoClay | 2-6 7-5 6-2 | 3 | 164 | 1 | 6 | 63.0% | 61.9% | 48.6% | 10/14 |
| QF | 26 | Alexandr DolgopolovClay | 15 | Stan WawrinkaClay | 6-4 7-6(6) | 3 | 115 | 11 | 3 | 54.7% | 71.2% | 48.8% | 9/11 |
| QF | 13 | Nicolas AlmagroClay | 48 | Santiago GiraldoClay | 7-6(0) 5-7 6-4 | 3 | 146 | 7 | 3 | 57.0% | 73.7% | 46.5% | 2/7 |
| QF | 36 | Thomaz BellucciClay | 134 | Lukasz KubotClay | 6-7(5) 6-3 6-4 | 3 | 189 | 5 | 3 | 61.0% | 72.1% | 38.5% | 3/7 |
| SF | 6 | David FerrerClay | 26 | Alexandr DolgopolovClay | 5-7 6-1 6-1 | 3 | 114 | 3 | 5 | 56.3% | 82.5% | 54.8% | 7/9 |
| SF | 13 | Nicolas AlmagroClay | 36 | Thomaz BellucciClay | 7-6(4) 6-4 | 3 | 104 | 9 | 1 | 57.3% | 74.4% | 62.5% | 3/3 |
| F | 6 | David FerrerClay | 13 | Nicolas AlmagroClay | 7-6(4) 6-7(2) 6-2 | 3 | 162 | 6 | 2 | 56.6% | 70.3% | 51.0% | 9/13 |
