| R32 | 116 |  Daniel KoellererClay | 12 |  David NalbandianClay | 1-6 6-3 6-4 | 3 | 140 | 2 | 3 | 60.5% | 63.5% | 47.1% | 8/13 |
| R32 | 85 |  Alberto MartinClay | 88 |  Marcos DanielClay | 6-4 7-5 | 3 | 101 | 2 | 3 | 61.6% | 80.0% | 42.9% | 7/8 |
| R32 | 64 | Martin Vassallo ArguelloClay | 71 | Ivan NavarroClay | 6-3 5-7 7-6(3) | 3 | 172 | 5 | 2 | 68.3% | 78.9% | 51.5% | 4/6 |
| R32 | 46 | Marcel GranollersClay | 111 |  Fabio FogniniClay | 7-6(3) 7-5 | 3 | 143 | 3 | 5 | 54.3% | 68.6% | 51.2% | 4/7 |
| R32 | 21 | Nicolas AlmagroClay | 231 |  Santiago GonzalezClay | 6-4 6-2 | 3 | 63 | 10 | 0 | 58.7% | 85.2% | 73.7% | 0/0 |
| R32 | 70 | Potito StaraceClay | 74 | Oscar HernandezClay | 6-4 6-2 | 3 | 84 | 1 | 1 | 77.2% | 75.0% | 53.8% | 5/6 |
| R32 | 89 | Daniel Gimeno-TraverClay | 108 |  Nicolas LapenttiClay | 6-4 5-7 6-3 | 3 | 148 | 0 | 4 | 66.7% | 63.2% | 50.0% | 6/10 |
| R32 | 38 | Albert MontanesClay | 358 | Bruno EchagarayClay | 6-1 6-4 | 3 | 83 | 3 | 3 | 56.1% | 71.9% | 52.0% | 2/4 |
| R32 | 43 | Jose AcasusoClay | 84 | Brian DabulClay | 6-3 7-5 | 3 | 90 | 10 | 1 | 69.4% | 80.0% | 40.9% | 6/7 |
| R32 | 162 | Juan Ignacio ChelaClay | 134 |  Pablo CuevasClay | 2-6 6-3 6-2 | 3 | 127 | 0 | 6 | 64.8% | 70.2% | 45.2% | 6/9 |
| R32 | 113 |  Kevin KimClay | 56 | Juan MonacoClay | 1-6 3-0 RET | 3 | 33 | 0 | 0 | 50.0% | 66.7% | 26.7% | 0/3 |
| R32 | 15 | Tommy RobredoClay | 126 | Ruben Ramirez HidalgoClay | 6-4 3-6 6-3 | 3 | 122 | 8 | 1 | 60.2% | 74.0% | 45.5% | 5/8 |
| R32 | 48 | Carlos MoyaClay | 90 | Pablo AndujarClay | 6-4 6-7(2) 6-2 | 3 | 128 | 5 | 5 | 53.0% | 71.7% | 48.9% | 7/9 |
| R32 | 110 | Leonardo MayerClay | 69 | Diego JunqueiraClay | 7-6(1) 6-3 | 3 | 90 | 12 | 2 | 58.9% | 81.4% | 46.7% | 2/4 |
| R32 | 68 | Thomaz BellucciClay | 62 |  Nicolas DevilderClay | 3-6 6-4 6-4 | 3 | 162 | 6 | 3 | 67.0% | 65.1% | 38.7% | 7/11 |
| R32 | 10 | Gael MonfilsClay | 139 | Olivier PatienceClay | 7-6(4) 6-4 | 3 | 103 | 17 | 2 | 51.6% | 96.9% | 60.0% | 2/3 |
| R16 | 116 | Daniel KoellererClay | 85 | Alberto MartinClay | 6-4 5-7 7-6(4) | 3 | 177 | 3 | 1 | 69.6% | 70.4% | 51.6% | 3/7 |
| R16 | 64 | Martin Vassallo ArguelloClay | 46 | Marcel GranollersClay | 6-4 6-3 | 3 | 100 | 1 | 1 | 73.7% | 76.2% | 60.0% | 1/2 |
| R16 | 21 | Nicolas AlmagroClay | 70 | Potito StaraceClay | 7-6(1) 6-7(5) 6-3 | 3 | 154 | 18 | 3 | 62.0% | 79.1% | 63.4% | 2/3 |
| R16 | 89 | Daniel Gimeno-TraverClay | 38 | Albert MontanesClay | 7-6(5) 7-6(5) | 3 | 110 | 2 | 1 | 69.5% | 73.7% | 52.0% | 4/6 |
| R16 | 43 | Jose AcasusoClay | 162 | Juan Ignacio ChelaClay | 7-5 6-3 | 3 | 117 | 2 | 0 | 55.1% | 79.1% | 42.9% | 6/7 |
| R16 | 15 | Tommy RobredoClay | 113 | Kevin KimClay | 6-2 6-0 | 3 | 80 | 2 | 0 | 71.9% | 91.3% | 77.8% | 0/0 |
| R16 | 110 | Leonardo MayerClay | 48 | Carlos MoyaClay | 6-4 7-5 | 3 | 101 | 3 | 0 | 67.2% | 77.8% | 63.6% | 4/4 |
| R16 | 10 | Gael MonfilsClay | 68 | Thomaz BellucciClay | 7-6(4) 6-7(5) 6-1 | 3 | 144 | 6 | 2 | 63.9% | 80.6% | 60.0% | 2/3 |
| QF | 64 | Martin Vassallo ArguelloClay | 116 | Daniel KoellererClay | 6-3 7-6(6) | 3 | 119 | 7 | 0 | 69.0% | 79.6% | 45.5% | 1/2 |
| QF | 21 | Nicolas AlmagroClay | 89 | Daniel Gimeno-TraverClay | 6-2 7-6(2) | 3 | 74 | 14 | 2 | 73.1% | 92.1% | 57.1% | 0/0 |
| QF | 43 | Jose AcasusoClay | 15 | Tommy RobredoClay | 7-5 6-2 | 3 | 87 | 5 | 1 | 68.9% | 78.6% | 63.2% | 1/1 |
| QF | 10 | Gael MonfilsClay | 110 | Leonardo MayerClay | 6-3 6-7(4) 4-1 RET | 3 | 126 | 8 | 4 | 62.2% | 75.0% | 64.7% | 3/3 |
| SF | 21 | Nicolas AlmagroClay | 64 | Martin Vassallo ArguelloClay | 6-4 6-4 | 3 | 100 | 6 | 4 | 49.3% | 69.4% | 56.8% | 4/5 |
| SF | 10 | Gael MonfilsClay | 43 | Jose AcasusoClay | 6-3 6-4 | 3 | 85 | 11 | 2 | 64.4% | 89.5% | 52.4% | 4/4 |
| F | 21 | Nicolas AlmagroClay | 10 | Gael MonfilsClay | 6-4 6-4 | 3 | 77 | 5 | 2 | 56.9% | 79.3% | 68.2% | 0/1 |
