| 2022-09-18 | Davis Cup Finals RR: GER vs AUS | Hard | RR | 81 |  Thanasi Kokkinakis | 52 |  Oscar Otte | 7-6(6) 6-1 | H2H | 3 | - | - | - | - | - | - | - |
| 2022-11-27 | Davis Cup Finals F: CAN vs AUS | Hard | RR | 18 |  Denis Shapovalov | 94 | Thanasi Kokkinakis | 6-2 6-4 | H2H | 3 | - | - | - | - | - | - | - |
| 2022-11-25 | Davis Cup Finals SF: AUS vs CRO | Hard | RR | 26 |  Borna Coric | 95 | Thanasi Kokkinakis | 6-4 6-3 | H2H | 3 | - | - | - | - | - | - | - |
| 2022-10-03 | Tokyo | Hard | R32 | 28 | Borna Coric (9) | 91 | Thanasi Kokkinakis | 6-4 7-6(4) | H2H | 3 | 122 | 5 | 3 | 70.3% | 82.2% | 63.2% | 1/1 |
| 2022-08-29 | US Open | Hard | R128 | 25 | Nick Kyrgios (23) | 70 | Thanasi Kokkinakis | 6-3 6-4 7-6(4) | H2H | 5 | 121 | 13 | 3 | 71.1% | 86.4% | 79.2% | 0/0 |
| 2022-08-22 | Winston-Salem | Hard | R64 | 84 | James Duckworth | 70 | Thanasi Kokkinakis | 4-6 6-3 7-6(5) | H2H | 3 | 135 | 13 | 5 | 53.7% | 82.4% | 59.1% | 3/4 |
| 2022-08-15 | Cincinnati Masters | Hard | R64 | 12 |  Jannik Sinner (10) | 75 | Thanasi Kokkinakis (Q) | 6-7(9) 6-4 7-6(6) | H2H | 3 | 194 | 6 | 3 | 53.6% | 76.7% | 63.5% | 5/6 |
| 2022-08-01 | Los Cabos | Hard | R16 | 92 |  Steve Johnson | 75 | Thanasi Kokkinakis (7) | 6-7(3) 6-4 6-4 | H2H | 3 | 167 | 12 | 5 | 49.0% | 74.5% | 64.2% | 6/7 |
| 2022-08-01 | Los Cabos | Hard | R32 | 75 | Thanasi Kokkinakis (7) | 125 |  Fernando Verdasco | 6-3 6-7(5) 6-2 | H2H | 3 | 170 | 15 | 2 | 66.3% | 72.5% | 54.3% | 5/6 |
| 2022-07-25 | Atlanta | Hard | R32 | 736 | Andres Martin (WC) | 69 | Thanasi Kokkinakis | 6-3 6-2 | H2H | 3 | 72 | 2 | 1 | 65.4% | 82.4% | 61.1% | 2/2 |
