| 2025-11-03 | Athens | Hard | R32 | 72 |  Marcos Giron | 95 |  Pedro Martinez | 6-4 6-1 | H2H | 3 | 85 | 10 | 1 | 58.3% | 82.1% | 65.0% | 0/0 |
| 2025-10-13 | Brussels | Hard | R32 | 111 | Eliot Spizzirri | 89 | Pedro Martinez | 6-4 6-1 | H2H | 3 | 77 | 5 | 2 | 59.6% | 96.4% | 52.6% | 0/0 |
| 2025-10-01 | Shanghai | Hard | R128 | 80 |  Arthur Cazaux | 70 | Pedro Martinez | 6-3 3-6 7-5 | H2H | 3 | 181 | 23 | 1 | 64.1% | 86.0% | 50.0% | 2/4 |
| 2025-09-12 | Davis Cup QLS R2: ESP vs DEN | Clay | RR | 67 | Pedro Martinez | 11 |  Holger Rune | 6-1 4-6 7-6 | H2H | 3 | 196 | 0 | 3 | 65.2% | 72.4% | 58.1% | 2/5 |
| 2025-08-24 | US Open | Hard | R128 | 435 |  Leandro Riedi | 66 | Pedro Martinez | 6-4 6-2 6-3 | H2H | 5 | 130 | 15 | 4 | 66.3% | 80.0% | 53.6% | 8/8 |
| 2025-08-18 | Winston-Salem | Hard | R32 | 39 | Giovanni Mpetshi Perricard (9) | 64 | Pedro Martinez | 2-6 6-3 7-6(3) | H2H | 3 | 111 | 2 | 4 | 62.0% | 75.0% | 70.4% | 0/2 |
| 2025-08-18 | Winston-Salem | Hard | R64 | 64 | Pedro Martinez | 68 |  David Goffin | 6-3 6-3 | H2H | 3 | 93 | 2 | 2 | 59.7% | 70.3% | 48.0% | 8/10 |
| 2025-08-07 | Cincinnati Masters | Hard | R64 | 15 | Tommy Paul (13) | 68 | Pedro Martinez | 6-2 6-2 | H2H | 3 | 91 | 8 | 2 | 58.9% | 75.8% | 56.5% | 6/6 |
| 2025-08-07 | Cincinnati Masters | Hard | R128 | 68 | Pedro Martinez | 100 |  Nicolas Jarry | 1-6 6-4 6-3 | H2H | 3 | 152 | 3 | 6 | 59.6% | 60.7% | 55.3% | 7/10 |
| 2025-07-27 | Canada Masters | Hard | R128 | 99 |  Aleksandar Vukic | 68 | Pedro Martinez | 7-5 6-3 | H2H | 3 | 111 | 8 | 2 | 53.0% | 77.1% | 41.9% | 2/5 |
