| 2022-11-23 | Davis Cup Finals QF: CRO vs ESP | Hard | RR | 17 |  Marin Cilic | 13 |  Pablo Carreno Busta | 5-7 6-3 7-6(5) | H2H | 3 | - | - | - | - | - | - | - |
| 2022-11-25 | Davis Cup Finals SF: AUS vs CRO | Hard | RR | 24 |  Alex de Minaur | 17 | Marin Cilic | 6-2 6-2 | H2H | 3 | - | - | - | - | - | - | - |
| 2022-10-31 | Paris Masters | Hard | R64 | 23 |  Lorenzo Musetti | 17 | Marin Cilic (15) | 6-4 6-4 | H2H | 3 | 82 | 7 | 1 | 73.7% | 81.0% | 53.3% | 2/2 |
| 2022-10-24 | Basel | Hard | R32 | 51 |  Arthur Rinderknech (Q) | 16 | Marin Cilic (4) | 6-4 3-6 7-6(5) | H2H | 3 | 146 | 11 | 1 | 77.9% | 74.6% | 63.2% | 0/2 |
| 2022-10-03 | Astana | Hard | R16 | 18 |  Karen Khachanov | 14 | Marin Cilic (9) | 2-6 6-3 6-3 | H2H | 3 | 144 | 5 | 3 | 63.5% | 66.7% | 42.1% | 12/15 |
| 2022-10-03 | Astana | Hard | R32 | 14 | Marin Cilic (9) | 55 |  Oscar Otte | 5-7 7-6(4) 6-2 | H2H | 3 | 152 | 7 | 0 | 66.7% | 80.0% | 56.7% | 0/2 |
| 2022-09-26 | Tel Aviv | Hard | F | 7 |  Novak Djokovic (1) | 16 | Marin Cilic (2) | 6-3 6-4 | H2H | 3 | 94 | 7 | 4 | 63.2% | 88.9% | 47.6% | 1/1 |
| 2022-09-26 | Tel Aviv | Hard | SF | 16 | Marin Cilic (2) | 68 | Constant Lestienne | 7-5 6-3 | H2H | 3 | 106 | 14 | 2 | 60.0% | 86.1% | 45.8% | 1/2 |
| 2022-09-26 | Tel Aviv | Hard | R16 | 16 | Marin Cilic (2) | 173 |  Dominic Thiem (WC) | 6-7(6) 6-2 6-4 | H2H | 3 | 163 | 15 | 3 | 60.2% | 79.2% | 57.1% | 1/2 |
| 2022-08-29 | US Open | Hard | R32 | 17 | Marin Cilic (15) | 23 |  Daniel Evans (20) | 7-6(11) 6-7(3) 6-2 7-5 | H2H | 5 | 239 | 26 | 9 | 56.1% | 82.1% | 54.1% | 7/9 |
