| R32 | 4 |  Nikolay DavydenkoClay | 103 |  Andrei PavelClay | 6-3 6-4 | 3 | 80 | 2 | 1 | 65.3% | 87.5% | 41.2% | 1/2 |
| R32 | 87 |  Martin Vassallo ArguelloClay | 256 | Maximo GonzalezClay | 2-6 6-3 6-2 | 3 | 86 | 5 | 2 | 75.0% | 68.6% | 70.6% | 1/4 |
| R32 | 51 |  Albert MontanesClay | 83 | Diego HartfieldClay | 6-1 6-3 | 3 | 83 | 1 | 2 | 48.4% | 76.7% | 59.4% | 3/3 |
| R32 | 85 | Mariano ZabaletaClay | 31 | Nicolas AlmagroClay | 6-3 7-5 | 3 | 109 | 0 | 2 | 63.0% | 58.7% | 51.9% | 7/10 |
| R32 | 67 | Sergio RoitmanClay | 20 | Juan Ignacio ChelaClay | 6-1 6-2 | 3 | 70 | 1 | 0 | 69.2% | 68.9% | 35.0% | 11/12 |
| R32 | 72 | Jose AcasusoClay | 53 |  Werner EschauerClay | 6-2 6-3 | 3 | 74 | 2 | 2 | 66.0% | 74.2% | 31.3% | 0/2 |
| R32 | 111 |  Olivier PatienceClay | 404 |  Dawid OlejniczakClay | 7-6(0) 6-4 | 3 | 83 | 3 | 7 | 56.2% | 75.6% | 59.4% | 3/4 |
| R32 | 35 |  Florian MayerClay | 110 | Juan Pablo BrzezickiClay | 6-3 6-3 | 3 | 86 | 1 | 1 | 60.4% | 79.3% | 63.2% | 0/1 |
| R32 | 120 |  Boris PashanskiClay | 32 |  Potito StaraceClay | 6-7(4) 6-2 3-1 RET | 3 | 94 | 5 | 1 | 67.7% | 85.7% | 65.0% | 1/2 |
| R32 | 49 | Gilles SimonClay | 141 | Viktor TroickiClay | 6-0 7-6(6) | 3 | 84 | 3 | 0 | 51.7% | 76.7% | 46.4% | 2/4 |
| R32 | 46 | Igor AndreevClay | 69 |  Nicolas LapenttiClay | 6-0 6-4 | 3 | 71 | 2 | 2 | 75.4% | 69.8% | 64.3% | 4/4 |
| R32 | 207 | Michal PrzysieznyClay | 28 | Filippo VolandriClay | 6-4 2-6 7-5 | 3 | 132 | 2 | 2 | 57.8% | 67.8% | 34.9% | 6/11 |
| R32 | 68 | Stefan KoubekClay | 37 | Agustin CalleriClay | 0-6 7-6(3) 7-5 | 3 | 131 | 5 | 2 | 57.0% | 67.9% | 47.5% | 4/10 |
| R32 | 75 |  Kristof VliegenClay | 89 |  Luis HornaClay | 6-2 6-7(8) 6-3 | 3 | 144 | 2 | 2 | 52.6% | 76.5% | 52.2% | 2/4 |
| R32 | 150 | Steve DarcisClay | 64 |  Nicolas MassuClay | 6-7(8) 7-6(0) 6-4 | 3 | 193 | 5 | 5 | 61.9% | 75.4% | 52.5% | 5/8 |
| R32 | 7 | Tommy RobredoClay | 134 | Lukasz KubotClay | 6-4 5-7 7-5 | 3 | 125 | 4 | 3 | 73.3% | 64.9% | 33.3% | 5/10 |
| R16 | 87 | Martin Vassallo ArguelloClay | 4 | Nikolay DavydenkoClay | 2-6 6-3 2-1 RET | 3 | 115 | 3 | 1 | 69.5% | 73.2% | 44.4% | 1/3 |
| R16 | 51 | Albert MontanesClay | 85 | Mariano ZabaletaClay | 4-6 6-3 7-5 | 3 | 122 | 3 | 5 | 57.6% | 73.5% | 50.0% | 0/4 |
| R16 | 72 | Jose AcasusoClay | 67 | Sergio RoitmanClay | 6-4 6-4 | 3 | 76 | 5 | 0 | 55.6% | 73.3% | 70.8% | 1/2 |
| R16 | 35 | Florian MayerClay | 111 | Olivier PatienceClay | 6-1 6-1 | 3 | 47 | 4 | 0 | 68.6% | 91.7% | 54.5% | 0/0 |
| R16 | 49 | Gilles SimonClay | 120 | Boris PashanskiClay | 6-4 4-6 6-3 | 3 | 151 | 3 | 1 | 41.0% | 60.5% | 54.8% | 7/11 |
| R16 | 46 | Igor AndreevClay | 207 | Michal PrzysieznyClay | 7-5 6-4 | 3 | 91 | 7 | 0 | 74.2% | 67.3% | 82.4% | 4/5 |
| R16 | 68 | Stefan KoubekClay | 75 | Kristof VliegenClay | 6-2 3-6 6-4 | 3 | 121 | 4 | 4 | 56.6% | 66.1% | 51.2% | 9/13 |
| R16 | 7 | Tommy RobredoClay | 150 | Steve DarcisClay | 1-6 6-0 7-5 | 3 | 97 | 3 | 2 | 73.0% | 61.1% | 45.0% | 4/8 |
| QF | 51 | Albert MontanesClay | 87 | Martin Vassallo ArguelloClay | 2-6 6-4 6-2 | 3 | 138 | 4 | 2 | 69.6% | 64.6% | 61.9% | 1/5 |
| QF | 72 | Jose AcasusoClay | 35 | Florian MayerClay | 7-6(4) 6-3 | 3 | 105 | 2 | 2 | 47.6% | 83.3% | 51.5% | 1/4 |
| QF | 49 | Gilles SimonClay | 46 | Igor AndreevClay | 6-4 7-5 | 3 | 100 | 3 | 2 | 44.6% | 79.3% | 63.9% | 4/5 |
| QF | 7 | Tommy RobredoClay | 68 | Stefan KoubekClay | 5-7 6-4 6-1 | 3 | 143 | 1 | 3 | 67.7% | 64.6% | 51.6% | 2/5 |
| SF | 72 | Jose AcasusoClay | 51 | Albert MontanesClay | 6-1 6-2 | 3 | 62 | 5 | 3 | 51.0% | 84.0% | 62.5% | 5/5 |
| SF | 7 | Tommy RobredoClay | 49 | Gilles SimonClay | 6-3 7-6(4) | 3 | 117 | 2 | 1 | 70.8% | 52.9% | 57.1% | 2/6 |
| F | 7 | Tommy RobredoClay | 72 | Jose AcasusoClay | 7-5 6-0 | 3 | 112 | 1 | 0 | 70.9% | 64.1% | 68.8% | 3/5 |
