| R32 | 6 |  Nikolay DavydenkoClay | 68 |  Christophe RochusClay | 6-1 6-2 | 3 | 54 | 6 | 2 | 63.4% | 84.6% | 66.7% | 0/0 |
| R32 | 72 |  Juan MonacoClay | 73 |  Jurgen MelzerClay | 2-6 7-6(2) 6-4 | 3 | 138 | 1 | 3 | 76.4% | 63.2% | 33.3% | 2/9 |
| R32 | 112 | Carlos BerlocqClay | 61 |  Philipp KohlschreiberClay | 6-0 6-2 | 3 | 60 | 5 | 0 | 72.3% | 79.4% | 38.5% | 1/1 |
| R32 | 85 |  Lukas DlouhyClay | 56 |  Ruben Ramirez HidalgoClay | 6-4 6-2 | 3 | 63 | 4 | 1 | 53.7% | 79.3% | 60.0% | 1/1 |
| R32 | 20 | Gaston GaudioClay | 77 |  Boris PashanskiClay | 6-1 6-7(4) 6-4 | 3 | 141 | 6 | 4 | 73.4% | 66.7% | 64.0% | 5/8 |
| R32 | 87 | Oliver MarachClay | 102 | Alexander WaskeClay | 6-4 7-6(6) | 3 | 100 | 5 | 2 | 49.3% | 80.6% | 56.8% | 2/3 |
| R32 | 80 | Guillermo Garcia-LopezClay | 365 | Mariano ZabaletaClay | 7-6(4) 7-5 | 3 | 131 | 1 | 3 | 68.0% | 66.7% | 62.5% | 1/4 |
| R32 | 58 |  Filippo VolandriClay | 211 | Daniel Gimeno-TraverClay | 6-4 6-1 | 3 | 60 | 0 | 1 | 76.1% | 77.1% | 63.6% | 1/2 |
| R32 | 39 | Agustin CalleriClay | 206 |  Hugo ArmandoClay | 6-4 2-6 7-6(4) | 3 | 132 | 8 | 4 | 59.8% | 74.1% | 48.7% | 6/9 |
| R32 | 94 |  Raemon SluiterClay | 911 |  Grzegorz PanfilClay | 6-1 6-3 | 3 | 65 | 9 | 3 | 44.7% | 85.7% | 61.5% | 2/2 |
| R32 | 100 | Jiri VanekClay | 97 | Alessio Di MauroClay | 7-6(3) 6-0 | 3 | 96 | 0 | 3 | 78.2% | 69.8% | 33.3% | 0/2 |
| R32 | 364 | Michal PrzysieznyClay | 33 | Guillermo CoriaClay | 5-6 RET | 3 | 66 | 0 | 2 | 55.8% | 50.0% | 36.8% | 7/11 |
| R32 | 34 | Juan Ignacio ChelaClay | 283 |  Adrian GarciaClay | 6-3 6-2 | 3 | 78 | 5 | 0 | 66.7% | 77.3% | 54.5% | 2/2 |
| R32 | 111 | Martin Vassallo ArguelloClay | 90 |  Marcos DanielClay | 6-4 2-0 RET | 3 | 80 | 2 | 0 | 65.4% | 88.2% | 55.6% | 0/1 |
| R32 | 60 | Florian MayerClay | 138 | Lukasz KubotClay | 6-1 6-2 | 3 | 52 | 8 | 1 | 63.4% | 88.5% | 60.0% | 0/0 |
| R32 | 7 | Tommy RobredoClay | 140 | Ivo MinarClay | 7-6(5) 3-6 6-4 | 3 | 143 | 1 | 1 | 71.7% | 60.6% | 42.9% | 3/8 |
| R16 | 6 | Nikolay DavydenkoClay | 72 | Juan MonacoClay | 7-5 6-7(7) 6-1 | 3 | 165 | 4 | 2 | 71.2% | 74.3% | 46.7% | 4/6 |
| R16 | 112 | Carlos BerlocqClay | 85 | Lukas DlouhyClay | 5-7 7-5 6-0 | 3 | 121 | 0 | 0 | 85.3% | 59.3% | 64.3% | 1/4 |
| R16 | 87 | Oliver MarachClay | 20 | Gaston GaudioClay | 5-7 6-4 7-6(4) | 3 | 161 | 11 | 3 | 55.0% | 68.9% | 50.0% | 4/8 |
| R16 | 58 | Filippo VolandriClay | 80 | Guillermo Garcia-LopezClay | 6-3 3-6 6-4 | 3 | 117 | 0 | 3 | 83.8% | 61.4% | 43.8% | 6/9 |
| R16 | 39 | Agustin CalleriClay | 94 | Raemon SluiterClay | 6-4 6-4 | 3 | 75 | 9 | 2 | 54.7% | 82.9% | 51.7% | 5/5 |
| R16 | 364 | Michal PrzysieznyClay | 100 | Jiri VanekClay | 6-3 6-1 | 3 | 66 | 1 | 1 | 65.3% | 65.6% | 70.6% | 0/1 |
| R16 | 34 | Juan Ignacio ChelaClay | 111 | Martin Vassallo ArguelloClay | 6-2 6-1 | 3 | 75 | 1 | 0 | 51.4% | 78.9% | 77.8% | 1/1 |
| R16 | 60 | Florian MayerClay | 7 | Tommy RobredoClay | 6-2 6-4 | 3 | 70 | 4 | 1 | 60.3% | 77.1% | 43.5% | 5/7 |
| QF | 6 | Nikolay DavydenkoClay | 112 | Carlos BerlocqClay | 6-0 6-4 | 3 | 77 | 2 | 1 | 78.6% | 78.8% | 66.7% | 0/0 |
| QF | 58 | Filippo VolandriClay | 87 | Oliver MarachClay | 6-2 6-3 | 3 | 88 | 0 | 0 | 81.0% | 55.3% | 54.5% | 6/9 |
| QF | 39 | Agustin CalleriClay | 364 | Michal PrzysieznyClay | 6-4 6-2 | 3 | 89 | 5 | 2 | 62.0% | 83.9% | 57.9% | 1/1 |
| QF | 60 | Florian MayerClay | 34 | Juan Ignacio ChelaClay | 6-4 6-0 | 3 | 61 | 4 | 1 | 72.1% | 74.2% | 75.0% | 0/0 |
| SF | 6 | Nikolay DavydenkoClay | 58 | Filippo VolandriClay | 6-2 6-4 | 3 | 73 | 1 | 1 | 70.0% | 71.4% | 27.8% | 5/8 |
| SF | 60 | Florian MayerClay | 39 | Agustin CalleriClay | 6-2 4-3 RET | 3 | 56 | 2 | 1 | 66.7% | 90.9% | 81.8% | 0/0 |
| F | 6 | Nikolay DavydenkoClay | 60 | Florian MayerClay | 7-6(6) 5-7 6-4 | 3 | 154 | 2 | 1 | 62.3% | 56.1% | 62.5% | 6/11 |
