| R32 | 54 |  Jarkko NieminenClay | 11 |  Mariano PuertaClay | 6-4 7-6(1) | 3 | 104 | 4 | 2 | 62.3% | 72.1% | 61.5% | 3/4 |
| R32 | 83 |  Nicolas AlmagroClay | 132 | Albert PortasClay | 7-6(2) 3-6 6-4 | 3 | 146 | 13 | 3 | 56.9% | 71.4% | 41.5% | 8/12 |
| R32 | 95 |  Florian MayerClay | 71 | Mariano ZabaletaClay | 6-4 4-6 6-1 | 3 | 97 | 9 | 1 | 70.1% | 74.1% | 56.5% | 1/3 |
| R32 | 33 |  Filippo VolandriClay | 186 |  Lukasz KubotClay | 6-3 6-1 | 3 | 71 | 1 | 0 | 78.4% | 77.5% | 54.5% | 2/2 |
| R32 | 9 | Guillermo CoriaClay | 288 |  Gustavo KuertenClay | 6-3 4-0 RET | 3 | 45 | 2 | 1 | 66.7% | 72.7% | 54.5% | 1/2 |
| R32 | 87 | Felix MantillaClay | 1461 | Marcin MatkowskiClay | 6-0 6-7(2) 6-1 | 3 | 115 | 3 | 0 | 73.3% | 60.3% | 47.8% | 6/10 |
| R32 | 81 |  Razvan SabauClay | 80 | Oscar HernandezClay | 2-6 6-1 6-4 | 3 | 110 | 0 | 3 | 73.5% | 74.0% | 50.0% | 1/3 |
| R32 | 50 |  Igor AndreevClay | 90 | Guillermo Garcia-LopezClay | 6-2 6-7(4) 6-2 | 3 | 133 | 2 | 4 | 64.6% | 59.4% | 54.3% | 3/7 |
| R32 | 45 | Jose AcasusoClay | 82 |  Jiri VanekClay | 7-5 4-6 7-5 | 3 | 138 | 9 | 2 | 62.1% | 77.8% | 51.5% | 1/5 |
| R32 | 230 | Adam ChadajClay | 118 | Alessio Di MauroClay | 6-3 5-7 6-1 | 3 | 121 | 1 | 5 | 59.6% | 69.8% | 44.4% | 6/9 |
| R32 | 121 | Potito StaraceClay | 86 |  Stefan KoubekClay | 6-4 6-2 | 3 | 73 | 1 | 2 | 90.0% | 68.5% | 33.3% | 3/4 |
| R32 | 29 | Carlos MoyaClay | 1469 | Mariusz FyrstenbergClay | 6-7(5) 6-3 7-5 | 3 | 147 | 10 | 3 | 68.8% | 74.0% | 51.4% | 6/9 |
| R32 | 49 | Victor HanescuClay | 84 | Albert MontanesClay | 7-6(3) 5-7 6-3 | 3 | 119 | 12 | 0 | 73.7% | 74.3% | 72.0% | 8/9 |
| R32 | 103 | Albert CostaClay | 76 | Philipp KohlschreiberClay | 7-5 6-3 | 3 | 84 | 1 | 2 | 69.5% | 70.7% | 50.0% | 0/2 |
| R32 | 68 | Juan MonacoClay | 234 |  Alan MackinClay | 6-3 6-1 | 3 | 79 | 5 | 0 | 58.5% | 79.2% | 70.6% | 1/2 |
| R32 | 65 |  Gael MonfilsClay | 166 |  Juan Antonio MarinClay | 6-0 6-4 | 3 | 85 | 1 | 3 | 49.1% | 57.7% | 40.7% | 3/6 |
| R16 | 54 | Jarkko NieminenClay | 83 | Nicolas AlmagroClay | 3-6 6-4 7-6(6) | 3 | 118 | 2 | 1 | 65.5% | 73.7% | 50.0% | 2/5 |
| R16 | 95 | Florian MayerClay | 33 | Filippo VolandriClay | 6-3 7-5 | 3 | 71 | 2 | 1 | 56.7% | 70.6% | 50.0% | 0/3 |
| R16 | 9 | Guillermo CoriaClay | 87 | Felix MantillaClay | 3-6 6-3 6-3 | 3 | 109 | 7 | 2 | 53.5% | 78.9% | 69.7% | 2/3 |
| R16 | 50 | Igor AndreevClay | 81 | Razvan SabauClay | 6-3 5-1 RET | 3 | 59 | 3 | 0 | 65.1% | 78.6% | 66.7% | 3/3 |
| R16 | 45 | Jose AcasusoClay | 230 | Adam ChadajClay | 6-3 6-4 | 3 | 85 | 6 | 2 | 56.5% | 66.7% | 53.3% | 2/4 |
| R16 | 121 | Potito StaraceClay | 29 | Carlos MoyaClay | 2-6 7-6(0) 7-5 | 3 | 126 | 1 | 0 | 72.3% | 69.9% | 46.4% | 6/10 |
| R16 | 49 | Victor HanescuClay | 103 | Albert CostaClay | 6-3 6-4 | 3 | 89 | 4 | 0 | 70.9% | 74.4% | 62.5% | 1/2 |
| R16 | 65 | Gael MonfilsClay | 68 | Juan MonacoClay | 6-4 7-6(5) | 3 | 119 | 6 | 2 | 51.3% | 76.9% | 45.9% | 2/5 |
| QF | 95 | Florian MayerClay | 54 | Jarkko NieminenClay | 6-2 6-2 | 3 | 52 | 1 | 1 | 58.7% | 77.8% | 63.2% | 0/0 |
| QF | 9 | Guillermo CoriaClay | 50 | Igor AndreevClay | 6-4 7-6(5) | 3 | 105 | 4 | 2 | 65.8% | 67.3% | 55.6% | 4/6 |
| QF | 121 | Potito StaraceClay | 45 | Jose AcasusoClay | 4-6 6-4 6-4 | 3 | 138 | 3 | 0 | 73.9% | 62.2% | 58.6% | 5/8 |
| QF | 65 | Gael MonfilsClay | 49 | Victor HanescuClay | 6-3 6-3 | 3 | 73 | 1 | 2 | 57.1% | 75.0% | 42.9% | 3/6 |
| SF | 95 | Florian MayerClay | 9 | Guillermo CoriaClay | 6-4 5-7 6-3 | 3 | 135 | 3 | 1 | 66.0% | 58.6% | 55.6% | 8/13 |
| SF | 65 | Gael MonfilsClay | 121 | Potito StaraceClay | 3-6 7-5 6-4 | 3 | 137 | 3 | 5 | 53.5% | 65.2% | 42.5% | 1/7 |
| F | 65 | Gael MonfilsClay | 95 | Florian MayerClay | 7-6(6) 4-6 7-5 | 3 | 127 | 9 | 2 | 58.4% | 74.6% | 52.4% | 4/8 |
