| R32 | 13 |  Marat SafinClay | 130 |  Galo BlancoClay | 7-5 6-2 | 3 | 91 | 6 | 0 | 51.7% | 71.0% | 62.1% | 4/5 |
| R32 | 137 | Marc LopezClay | 89 | Oscar HernandezClay | 7-5 6-2 | 3 | 96 | 0 | 1 | 69.5% | 73.2% | 27.8% | 3/6 |
| R32 | 123 |  Marc RossetClay | 560 |  Filip UrbanClay | 6-4 7-6(6) | 3 | 121 | 7 | 10 | 50.6% | 79.5% | 52.6% | 1/3 |
| R32 | 99 |  Juan MonacoClay | 60 | Alberto MartinClay | 6-7(13) 7-5 6-3 | 3 | 165 | 1 | 3 | 69.3% | 62.5% | 51.3% | 7/12 |
| R32 | 53 | David FerrerClay | 117 | Guillermo Garcia-LopezClay | 6-4 6-3 | 3 | 108 | 1 | 1 | 62.8% | 59.2% | 51.7% | 6/9 |
| R32 | 105 | Jose AcasusoClay | 375 | Michal PrzysieznyClay | 7-5 6-4 | 3 | 79 | 4 | 2 | 60.0% | 76.9% | 61.5% | 0/1 |
| R32 | 163 |  Jiri VanekClay | 120 | Bohdan UlihrachClay | 2-6 6-2 7-6(5) | 3 | 136 | 8 | 4 | 74.0% | 66.2% | 37.0% | 8/12 |
| R32 | 96 |  Stefan KoubekClay | 91 |  Paul-Henri MathieuClay | 3-6 6-1 6-3 | 3 | 104 | 5 | 0 | 73.8% | 68.8% | 82.4% | 2/4 |
| R32 | 71 | Rafael NadalClay | 88 |  Victor HanescuClay | 6-4 6-4 | 3 | 81 | 3 | 1 | 80.9% | 89.5% | 44.4% | 1/2 |
| R32 | 272 | Arnaud Di PasqualeClay | 100 | Alex CalatravaClay | 6-4 3-6 6-4 | 3 | 133 | 3 | 4 | 80.0% | 63.9% | 50.0% | 5/10 |
| R32 | 154 | Franco SquillariClay | 133 | Tomas ZibClay | 6-4 6-2 | 3 | 78 | 4 | 5 | 58.3% | 77.1% | 60.0% | 5/5 |
| R32 | 327 | Lukasz KubotClay | 55 | Igor AndreevClay | 6-4 6-2 | 3 | 81 | 2 | 3 | 60.0% | 76.7% | 60.0% | 1/2 |
| R32 | 110 | Felix MantillaClay | 84 | Albert MontanesClay | 6-0 6-2 | 3 | 44 | 4 | 1 | 51.4% | 84.2% | 61.1% | 0/1 |
| R32 | 145 | Albert PortasClay | 158 | Martin Vassallo ArguelloClay | 6-1 6-2 | 3 | 72 | 1 | 1 | 67.3% | 74.3% | 58.8% | 1/1 |
| R32 | 116 | Olivier MutisClay | 136 | Ruben Ramirez HidalgoClay | 6-4 6-3 | 3 | 68 | 2 | 2 | 40.7% | 68.2% | 59.4% | 2/4 |
| R32 | 114 |  Adrian GarciaClay | 56 | Nikolay DavydenkoClay | 3-6 7-6(5) 6-4 | 3 | 140 | 1 | 1 | 58.8% | 63.3% | 61.9% | 7/10 |
| R16 | 137 | Marc LopezClay | 13 | Marat SafinClay | 6-3 6-2 | 3 | 75 | 0 | 0 | 47.9% | 78.3% | 68.0% | 1/1 |
| R16 | 99 | Juan MonacoClay | 123 | Marc RossetClay | 6-4 6-3 | 3 | 82 | 2 | 2 | 82.6% | 61.4% | 50.0% | 7/9 |
| R16 | 105 | Jose AcasusoClay | 53 | David FerrerClay | 6-4 7-6(4) | 3 | 102 | 3 | 3 | 60.5% | 69.6% | 60.0% | 0/1 |
| R16 | 163 | Jiri VanekClay | 96 | Stefan KoubekClay | 6-4 6-4 | 3 | 81 | 1 | 0 | 65.6% | 75.0% | 76.2% | 2/2 |
| R16 | 71 | Rafael NadalClay | 272 | Arnaud Di PasqualeClay | 6-2 6-4 | 3 | 79 | 1 | 0 | 60.8% | 77.4% | 50.0% | 0/1 |
| R16 | 154 | Franco SquillariClay | 327 | Lukasz KubotClay | 6-2 6-3 | 3 | 75 | 3 | 0 | 64.0% | 75.0% | 61.1% | 2/2 |
| R16 | 110 | Felix MantillaClay | 145 | Albert PortasClay | 5-7 7-5 7-5 | 3 | 156 | 8 | 2 | 47.8% | 68.8% | 44.3% | 16/22 |
| R16 | 114 | Adrian GarciaClay | 116 | Olivier MutisClay | 6-2 7-6(9) | 3 | 78 | 7 | 2 | 67.6% | 67.4% | 40.9% | 6/10 |
| QF | 99 | Juan MonacoClay | 137 | Marc LopezClay | 6-3 2-6 7-6(6) | 3 | 142 | 2 | 1 | 85.6% | 60.2% | 42.9% | 2/7 |
| QF | 105 | Jose AcasusoClay | 163 | Jiri VanekClay | 3-6 6-3 6-2 | 3 | 99 | 1 | 1 | 47.9% | 85.3% | 62.2% | 0/1 |
| QF | 71 | Rafael NadalClay | 154 | Franco SquillariClay | 6-3 6-4 | 3 | 158 | 1 | 0 | 86.4% | 64.7% | 62.5% | 4/6 |
| QF | 110 | Felix MantillaClay | 114 | Adrian GarciaClay | 6-3 6-3 | 3 | 81 | 0 | 2 | 67.2% | 70.7% | 60.0% | 6/7 |
| SF | 105 | Jose AcasusoClay | 99 | Juan MonacoClay | 6-4 6-2 | 3 | 78 | 2 | 2 | 50.8% | 66.7% | 58.6% | 1/2 |
| SF | 71 | Rafael NadalClay | 110 | Felix MantillaClay | 7-5 6-1 | 3 | 94 | 2 | 2 | 72.6% | 68.9% | 47.1% | 3/5 |
| F | 71 | Rafael NadalClay | 105 | Jose AcasusoClay | 6-3 6-4 | 3 | 96 | 4 | 1 | 78.9% | 71.7% | 37.5% | 11/12 |
