| R32 | 2 |  Juan Carlos FerreroClay | 623 |  Bartlomiej DabrowskiClay | 6-3 6-1 | 3 | 65 | 0 | 2 | 47.7% | 85.7% | 65.2% | 0/0 |
| R32 | 283 |  Frantisek CermakClay | 1360 | Filip UrbanClay | 6-4 6-2 | 3 | 70 | 3 | 2 | 67.2% | 69.2% | 47.4% | 4/6 |
| R32 | 92 |  Luis HornaClay | 158 |  Attila SavoltClay | 6-1 6-1 | 3 | 42 | 5 | 0 | 64.7% | 81.8% | 91.7% | 3/3 |
| R32 | 56 |  Dominik HrbatyClay | 430 | Mariusz FyrstenbergClay | 7-5 6-3 | 3 | 75 | 3 | 2 | 59.7% | 72.5% | 44.4% | 3/6 |
| R32 | 7 |  Guillermo CoriaClay | 91 |  Victor HanescuClay | 6-3 6-4 | 3 | 79 | 3 | 2 | 62.2% | 89.3% | 58.8% | 3/4 |
| R32 | 96 |  Christophe RochusClay | 116 | Federico BrowneClay | 6-3 6-3 | 3 | 79 | 3 | 2 | 62.2% | 89.3% | 58.8% | 3/4 |
| R32 | 453 |  Marc-Kevin GoellnerClay | 152 |  Michel KratochvilClay | 6-4 4-6 6-3 | 3 | 136 | 16 | 6 | 50.9% | 83.1% | 38.6% | 11/14 |
| R32 | 71 |  Olivier MutisClay | 138 | Adrian VoineaClay | 6-2 6-4 | 3 | 56 | 0 | 0 | 43.2% | 78.9% | 84.0% | 0/0 |
| R32 | 60 | David SanchezClay | 77 |  Magnus NormanClay | 6-4 6-2 | 3 | 79 | 2 | 2 | 61.4% | 71.4% | 68.2% | 2/3 |
| R32 | 106 | Andreas VinciguerraClay | 129 |  Giorgio GalimbertiClay | 6-3 6-2 | 3 | 48 | 4 | 1 | 60.4% | 89.7% | 63.2% | 0/0 |
| R32 | 72 | David FerrerClay | 166 | Bohdan UlihrachClay | 7-6(2) 6-2 | 3 | 80 | 1 | 2 | 76.1% | 70.4% | 52.9% | 1/2 |
| R32 | 19 | David NalbandianClay | 132 | Marc RossetClay | 6-2 6-4 | 3 | 86 | 2 | 2 | 52.9% | 92.6% | 50.0% | 0/0 |
| R32 | 98 | Mariano PuertaClay | 47 | Filippo VolandriClay | 6-4 6-0 | 3 | 48 | 1 | 3 | 70.7% | 93.1% | 50.0% | 0/0 |
| R32 | 84 | Ruben Ramirez HidalgoClay | 173 |  Julian KnowleClay | 7-5 3-6 6-1 | 3 | 121 | 9 | 3 | 60.0% | 66.7% | 58.8% | 3/7 |
| R32 | 115 | Galo BlancoClay | 726 | Marcin MatkowskiClay | 6-0 6-1 | 3 | 44 | 1 | 0 | 75.8% | 80.0% | 62.5% | 1/1 |
| R32 | 83 | Albert PortasClay | 4 | Carlos MoyaClay | 7-6(4) 6-7(6) 7-5 | 3 | 151 | 3 | 2 | 63.1% | 66.3% | 65.4% | 8/10 |
| R16 | 2 | Juan Carlos FerreroClay | 283 | Frantisek CermakClay | 4-6 7-5 6-2 | 3 | 116 | 3 | 3 | 69.3% | 70.5% | 51.9% | 6/9 |
| R16 | 92 | Luis HornaClay | 56 | Dominik HrbatyClay | 6-3 6-1 | 3 | 116 | 3 | 3 | 69.3% | 70.5% | 51.9% | 6/9 |
| R16 | 7 | Guillermo CoriaClay | 96 | Christophe RochusClay | 6-1 6-0 | 3 | 55 | 2 | 0 | 65.7% | 78.3% | 66.7% | 2/2 |
| R16 | 71 | Olivier MutisClay | 453 | Marc-Kevin GoellnerClay | 6-4 6-2 | 3 | 69 | 2 | 0 | 57.1% | 67.9% | 71.4% | 3/4 |
| R16 | 106 | Andreas VinciguerraClay | 60 | David SanchezClay | 6-3 6-4 | 3 | 80 | 2 | 4 | 60.0% | 64.4% | 46.7% | 8/10 |
| R16 | 72 | David FerrerClay | 19 | David NalbandianClay | 6-4 4-6 6-3 | 3 | 127 | 2 | 0 | 62.9% | 64.3% | 45.5% | 3/8 |
| R16 | 84 | Ruben Ramirez HidalgoClay | 98 | Mariano PuertaClay | 6-3 6-3 | 3 | 63 | 11 | 0 | 50.0% | 84.6% | 61.5% | 0/0 |
| R16 | 115 | Galo BlancoClay | 83 | Albert PortasClay | 3-6 6-1 6-4 | 3 | 131 | 3 | 3 | 57.5% | 68.0% | 48.6% | 3/6 |
| QF | 92 | Luis HornaClay | 2 | Juan Carlos FerreroClay | 6-1 7-6(1) | 3 | 88 | 7 | 5 | 42.3% | 80.0% | 58.5% | 0/0 |
| QF | 7 | Guillermo CoriaClay | 71 | Olivier MutisClay | 6-3 6-4 | 3 | 78 | 6 | 5 | 56.5% | 69.2% | 56.7% | 3/4 |
| QF | 72 | David FerrerClay | 106 | Andreas VinciguerraClay | 6-1 6-2 | 3 | 71 | 1 | 4 | 63.6% | 71.4% | 50.0% | 6/6 |
| QF | 84 | Ruben Ramirez HidalgoClay | 115 | Galo BlancoClay | 6-7(7) 6-4 6-0 | 3 | 120 | 5 | 4 | 66.3% | 75.5% | 70.4% | 1/2 |
| SF | 7 | Guillermo CoriaClay | 92 | Luis HornaClay | 6-2 6-2 | 3 | 57 | 2 | 1 | 74.4% | 79.3% | 70.0% | 0/1 |
| SF | 72 | David FerrerClay | 84 | Ruben Ramirez HidalgoClay | 6-7(2) 6-3 6-4 | 3 | 118 | 0 | 6 | 58.6% | 67.2% | 48.8% | 4/9 |
| F | 7 | Guillermo CoriaClay | 72 | David FerrerClay | 7-5 6-1 | 3 | 75 | 3 | 0 | 63.6% | 75.0% | 62.5% | 1/3 |
