| R32 | 32 |  Andrea GaudenziClay | 79 |  Juan Antonio MarinClay | 6-2 7-6(4) | 3 | 88 | 1 | 4 | 66.7% | 73.8% | 61.9% | 1/2 |
| R32 | 116 |  Jacobo DiazClay | 105 | Albert PortasClay | 6-2 6-2 | 3 | 54 | 4 | 2 | 75.0% | 83.3% | 50.0% | 2/2 |
| R32 | 590 |  Mariano HoodClay | 76 |  Andrei PavelClay | 6-1 6-2 | 3 | 61 | 4 | 0 | 64.3% | 75.0% | 60.0% | 4/4 |
| R32 | 58 | Carlos CostaClay | 100 | Alex CalatravaClay | 6-4 6-2 | 3 | 77 | 4 | 0 | 43.1% | 64.0% | 78.8% | 4/4 |
| R32 | 42 |  Dominik HrbatyClay | 267 | Davide ScalaClay | 6-3 6-4 | 3 | 72 | 6 | 5 | 35.7% | 80.0% | 58.3% | 1/2 |
| R32 | 67 |  Jiri NovakClay | 92 | Sergi BrugueraClay | 7-5 5-7 7-5 | 3 | 142 | 6 | 4 | 57.6% | 64.7% | 56.0% | 6/11 |
| R32 | 214 |  Luis Adrian MorejonClay | 687 | Omar CamporeseClay | 6-4 6-4 | 3 | 88 | 4 | 4 | 58.2% | 81.3% | 47.8% | 2/4 |
| R32 | 144 | Juan Albert Viloca-PuigClay | 48 | Julian AlonsoClay | 4-6 6-4 7-6(5) | 3 | 138 | 6 | 5 | 58.7% | 77.0% | 51.2% | 3/6 |
| R32 | 71 | Fernando VicenteClay | 43 |  Fernando MeligeniClay | 0-6 6-4 6-2 | 3 | 96 | 1 | 1 | 70.9% | 71.4% | 34.8% | 4/7 |
| R32 | 96 | Mariano ZabaletaClay | 171 | Renzo FurlanClay | 6-3 6-3 | 3 | 74 | 2 | 2 | 45.3% | 75.0% | 62.1% | 1/2 |
| R32 | 73 | Mariano PuertaClay | 88 | Lucas Arnold KerClay | 6-4 4-6 6-3 | 3 | 153 | 2 | 0 | 55.7% | 64.8% | 58.1% | 10/12 |
| R32 | 91 | Galo BlancoClay | 34 |  Magnus NormanClay | 6-3 6-0 | 3 | 61 | 3 | 4 | 41.5% | 76.5% | 62.5% | 2/3 |
| R32 | 50 | Davide SanguinettiClay | 139 | Marzio MartelliClay | 6-1 3-6 6-4 | 3 | 113 | 5 | 1 | 53.5% | 65.2% | 57.5% | 4/7 |
| R32 | 157 | Vincenzo SantopadreClay | 74 |  Marat SafinClay | 6-2 6-0 | 3 | 49 | 5 | 1 | 61.1% | 86.4% | 64.3% | 0/0 |
| R32 | 98 | Javier SanchezClay | 415 | Pietro AngeliniClay | 6-4 6-2 | 3 | 66 | 9 | 3 | 67.3% | 75.7% | 55.6% | 3/4 |
| R32 | 30 |  Richard FrombergClay | 81 | Dinu PescariuClay | 6-4 6-0 | 3 | 53 | 6 | 2 | 63.0% | 79.3% | 47.1% | 1/2 |
| R16 | 32 | Andrea GaudenziClay | 116 | Jacobo DiazClay | 6-2 6-2 | 3 | 62 | 2 | 1 | 54.8% | 82.6% | 73.7% | 0/0 |
| R16 | 58 | Carlos CostaClay | 590 | Mariano HoodClay | 6-4 7-5 | 3 | 83 | 11 | 3 | 56.9% | 78.8% | 52.0% | 1/3 |
| R16 | 42 | Dominik HrbatyClay | 67 | Jiri NovakClay | 7-6(2) 7-6(3) | 3 | 88 | 5 | 6 | 61.4% | 75.9% | 52.9% | 3/5 |
| R16 | 144 | Juan Albert Viloca-PuigClay | 214 | Luis Adrian MorejonClay | 6-3 6-3 | 3 | 89 | 2 | 1 | 52.4% | 78.8% | 63.3% | 7/7 |
| R16 | 96 | Mariano ZabaletaClay | 71 | Fernando VicenteClay | 5-7 7-6(10) 6-4 | 3 | 167 | 5 | 7 | 54.2% | 71.9% | 50.0% | 7/11 |
| R16 | 73 | Mariano PuertaClay | 91 | Galo BlancoClay | 4-6 6-3 6-1 | 3 | 113 | 3 | 5 | 63.7% | 70.6% | 58.6% | 1/2 |
| R16 | 157 | Vincenzo SantopadreClay | 50 | Davide SanguinettiClay | 7-6(4) 6-2 | 3 | 82 | 6 | 2 | 42.6% | 80.8% | 62.9% | 2/3 |
| R16 | 30 | Richard FrombergClay | 98 | Javier SanchezClay | 6-2 6-3 | 3 | 61 | 8 | 5 | 56.4% | 87.1% | 50.0% | 4/4 |
| QF | 58 | Carlos CostaClay | 32 | Andrea GaudenziClay | 7-5 6-1 | 3 | 81 | 1 | 2 | 50.0% | 65.7% | 65.7% | 10/11 |
| QF | 42 | Dominik HrbatyClay | 144 | Juan Albert Viloca-PuigClay | 2-6 6-4 6-0 | 3 | 104 | 2 | 2 | 52.2% | 75.0% | 38.6% | 9/11 |
| QF | 73 | Mariano PuertaClay | 96 | Mariano ZabaletaClay | 4-6 6-3 4-0 RET | 3 | 104 | 5 | 1 | 68.8% | 72.7% | 65.0% | 2/4 |
| QF | 30 | Richard FrombergClay | 157 | Vincenzo SantopadreClay | 6-4 7-5 | 3 | 94 | 10 | 5 | 59.0% | 83.3% | 56.0% | 3/4 |
| SF | 42 | Dominik HrbatyClay | 58 | Carlos CostaClay | 6-0 4-6 7-6(6) | 3 | 137 | 5 | 7 | 53.5% | 65.6% | 50.9% | 13/17 |
| SF | 73 | Mariano PuertaClay | 30 | Richard FrombergClay | 6-2 3-6 6-3 | 3 | 98 | 1 | 1 | 65.7% | 70.5% | 56.5% | 1/4 |
| F | 42 | Dominik HrbatyClay | 73 | Mariano PuertaClay | 6-2 7-5 | 3 | 76 | 5 | 2 | 51.9% | 75.0% | 57.7% | 4/6 |
