| R32 | 4 |  Andy MurrayHard | 77 |  Daniel Gimeno-TraverHard | 6-3 6-1 | 3 | 60 | 3 | 2 | 57.8% | 84.6% | 47.4% | 1/2 |
| R32 | 64 |  Leonardo MayerHard | 35 |  Igor AndreevHard | 6-3 6-3 | 3 | 63 | 3 | 0 | 69.6% | 84.4% | 64.3% | 0/1 |
| R32 | 34 | Albert MontanesHard | 315 | Roberto Bautista AgutHard | 6-1 3-6 6-4 | 3 | 115 | 4 | 3 | 53.8% | 65.1% | 59.5% | 3/6 |
| R32 | 18 | David FerrerHard | 27 | Nicolas AlmagroHard | 7-5 6-7(3) 6-2 | 3 | 137 | 1 | 3 | 54.3% | 76.0% | 47.6% | 0/3 |
| R32 | 8 | Fernando VerdascoHard | 75 | Oscar HernandezHard | 6-1 0-1 RET | 3 | 30 | 2 | 0 | 52.6% | 100.0% | 66.7% | 0/0 |
| R32 | 39 |  Janko TipsarevicHard | 36 |  Victor HanescuHard | 6-4 6-3 | 3 | 85 | 5 | 2 | 55.0% | 72.7% | 55.6% | 1/2 |
| R32 | 46 | Feliciano LopezHard | 119 | Alberto MartinHard | 7-5 6-3 | 3 | 80 | 12 | 3 | 66.7% | 89.5% | 47.4% | 2/2 |
| R32 | 15 | Tommy RobredoHard | 88 |  Christophe RochusHard | 6-0 5-7 6-3 | 3 | 130 | 16 | 1 | 63.0% | 71.4% | 43.2% | 10/13 |
| R32 | 12 |  Gilles SimonHard | 81 | Igor KunitsynHard | 6-3 6-2 | 3 | 54 | 4 | 0 | 70.0% | 85.7% | 60.0% | 3/3 |
| R32 | 19 |  Tomas BerdychHard | 32 | Paul-Henri MathieuHard | 6-3 6-4 | 3 | 80 | 8 | 2 | 67.2% | 87.8% | 45.0% | 4/4 |
| R32 | 50 |  Pablo CuevasHard | 22 | Juan Carlos FerreroHard | 2-6 7-6(4) 6-3 | 3 | 127 | 10 | 3 | 55.3% | 73.7% | 52.2% | 7/11 |
| R32 | 23 | Mikhail YouzhnyHard | 9 | Jo-Wilfried TsongaHard | 6-7(3) 6-0 3-0 RET | 3 | 89 | 5 | 2 | 51.7% | 80.6% | 65.5% | 2/3 |
| R32 | 16 | Gael MonfilsHard | 82 | Marcel GranollersHard | 6-4 6-2 | 3 | 71 | 2 | 1 | 53.5% | 68.4% | 45.5% | 8/10 |
| R32 | 47 | Guillermo Garcia-LopezHard | 56 |  Simon GreulHard | 7-5 6-2 | 3 | 86 | 4 | 4 | 68.3% | 68.3% | 52.6% | 7/9 |
| R32 | 30 | Juan MonacoHard | 72 | Martin Vassallo ArguelloHard | 6-3 6-2 | 3 | 75 | 3 | 0 | 61.2% | 66.7% | 68.4% | 2/3 |
| R32 | 7 | Nikolay DavydenkoHard | 98 |  Alejandro FallaHard | 6-2 6-1 | 3 | 62 | 5 | 0 | 70.3% | 80.8% | 63.6% | 0/1 |
| R16 | 4 | Andy MurrayHard | 64 | Leonardo MayerHard | 6-4 3-6 6-3 | 3 | 142 | 8 | 3 | 55.9% | 78.8% | 43.9% | 3/5 |
| R16 | 34 | Albert MontanesHard | 18 | David FerrerHard | W/O | 3 | - | 8 | 3 | 55.9% | 78.8% | 43.9% | 3/5 |
| R16 | 8 | Fernando VerdascoHard | 39 | Janko TipsarevicHard | 6-3 6-3 | 3 | 83 | 7 | 2 | 65.6% | 77.5% | 42.9% | 5/6 |
| R16 | 15 | Tommy RobredoHard | 46 | Feliciano LopezHard | 4-6 6-3 6-4 | 3 | 102 | 7 | 1 | 60.0% | 77.1% | 65.6% | 4/6 |
| R16 | 12 | Gilles SimonHard | 19 | Tomas BerdychHard | 6-4 4-6 6-3 | 3 | 139 | 11 | 1 | 58.8% | 73.1% | 48.9% | 11/13 |
| R16 | 23 | Mikhail YouzhnyHard | 50 | Pablo CuevasHard | 6-2 2-6 6-1 | 3 | 95 | 1 | 2 | 60.9% | 84.6% | 48.0% | 2/4 |
| R16 | 47 | Guillermo Garcia-LopezHard | 16 | Gael MonfilsHard | 6-2 7-5 | 3 | 97 | 1 | 4 | 62.9% | 79.5% | 52.2% | 1/1 |
| R16 | 7 | Nikolay DavydenkoHard | 30 | Juan MonacoHard | 6-3 7-5 | 3 | 102 | 0 | 4 | 57.4% | 69.2% | 51.7% | 3/5 |
| QF | 4 | Andy MurrayHard | 34 | Albert MontanesHard | 6-4 6-2 | 3 | 74 | 3 | 1 | 59.6% | 77.4% | 52.4% | 1/2 |
| QF | 8 | Fernando VerdascoHard | 15 | Tommy RobredoHard | 6-3 6-2 | 3 | 76 | 5 | 1 | 63.6% | 71.4% | 70.0% | 2/2 |
| QF | 23 | Mikhail YouzhnyHard | 12 | Gilles SimonHard | 6-4 6-4 | 3 | 97 | 4 | 0 | 71.4% | 65.5% | 68.2% | 11/11 |
| QF | 7 | Nikolay DavydenkoHard | 47 | Guillermo Garcia-LopezHard | 6-4 7-6(3) | 3 | 117 | 9 | 2 | 48.4% | 83.3% | 62.5% | 2/4 |
| SF | 4 | Andy MurrayHard | 8 | Fernando VerdascoHard | 6-3 2-6 6-3 | 3 | 122 | 5 | 4 | 48.3% | 69.0% | 57.8% | 6/8 |
| SF | 23 | Mikhail YouzhnyHard | 7 | Nikolay DavydenkoHard | 3-6 6-4 6-3 | 3 | 144 | 2 | 0 | 64.4% | 66.1% | 41.9% | 6/10 |
| F | 4 | Andy MurrayHard | 23 | Mikhail YouzhnyHard | 6-3 6-2 | 3 | 68 | 8 | 1 | 59.2% | 89.7% | 45.0% | 2/3 |
