| R32 | 5 |  David FerrerClay | 112 | Ivan NavarroClay | 6-3 6-4 | 3 | 93 | 2 | 1 | 74.2% | 71.7% | 56.3% | 2/3 |
| R32 | 147 | Pablo AndujarClay | 70 |  Kristof VliegenClay | 6-4 6-1 | 3 | 69 | 1 | 0 | 82.4% | 78.6% | 33.3% | 1/2 |
| R32 | 75 |  Mischa ZverevClay | 106 |  Luis HornaClay | 6-3 6-7(5) 6-4 | 3 | 132 | 9 | 1 | 72.2% | 76.9% | 64.0% | 2/2 |
| R32 | 31 | Fernando VerdascoClay | 98 |  Nicolas LapenttiClay | 5-7 6-3 6-4 | 3 | 159 | 4 | 2 | 81.4% | 68.5% | 47.6% | 8/9 |
| R32 | 18 | Tommy RobredoClay | 59 | Albert MontanesClay | 6-3 7-5 | 3 | 102 | 2 | 0 | 71.2% | 70.2% | 52.6% | 1/3 |
| R32 | 80 | Santiago VenturaClay | 270 | David MarreroClay | 7-6(3) 7-6(6) | 3 | 152 | 7 | 0 | 49.4% | 77.3% | 57.8% | 2/3 |
| R32 | 63 |  Gael MonfilsClay | 135 |  Maximo GonzalezClay | 6-3 6-4 | 3 | 89 | 5 | 1 | 59.2% | 72.4% | 65.0% | 2/4 |
| R32 | 39 |  Potito StaraceClay | 64 | Simone BolelliClay | 6-3 6-1 | 3 | 65 | 1 | 1 | 81.6% | 72.5% | 66.7% | 2/2 |
| R32 | 113 |  Evgeny KorolevClay | 26 |  Igor AndreevClay | 6-4 4-6 7-6(4) | 3 | 148 | 2 | 1 | 67.6% | 74.6% | 58.8% | 5/6 |
| R32 | 131 | Daniel Gimeno-TraverClay | 126 |  Sergiy StakhovskyClay | 6-4 6-4 | 3 | 75 | 2 | 0 | 69.6% | 90.6% | 78.6% | 0/0 |
| R32 | 62 |  Robin HaaseClay | 128 | Yuri SchukinClay | 6-4 4-1 RET | 3 | 65 | 9 | 0 | 72.7% | 75.0% | 50.0% | 4/6 |
| R32 | 86 | Marat SafinClay | 19 | Juan Carlos FerreroClay | 6-3 5-7 6-4 | 3 | 129 | 8 | 3 | 61.5% | 80.4% | 51.4% | 4/6 |
| R32 | 27 | Nicolas AlmagroClay | 268 | Miguel Angel Lopez JaenClay | 7-5 6-3 | 3 | 100 | 13 | 6 | 50.5% | 80.4% | 44.4% | 6/7 |
| R32 | 124 | Eduardo SchwankClay | 141 | Christophe RochusClay | 6-2 2-0 RET | 3 | 50 | 4 | 1 | 69.8% | 73.3% | 38.5% | 1/1 |
| R32 | 65 | Guillermo Garcia-LopezClay | 48 | Steve DarcisClay | 6-4 RET | 3 | 43 | 0 | 2 | 61.3% | 52.6% | 66.7% | 3/4 |
| R32 | 17 | Juan MonacoClay | 122 |  Werner EschauerClay | 6-7(5) 6-4 6-4 | 3 | 166 | 3 | 3 | 61.1% | 62.3% | 50.0% | 5/11 |
| R16 | 5 | David FerrerClay | 147 | Pablo AndujarClay | 6-3 6-4 | 3 | 83 | 2 | 0 | 65.5% | 72.2% | 36.8% | 1/3 |
| R16 | 31 | Fernando VerdascoClay | 75 | Mischa ZverevClay | 6-4 6-2 | 3 | 97 | 1 | 2 | 87.0% | 72.5% | 50.0% | 1/3 |
| R16 | 18 | Tommy RobredoClay | 80 | Santiago VenturaClay | 6-7(7) 6-3 6-4 | 3 | 157 | 2 | 2 | 70.9% | 78.1% | 60.0% | 1/1 |
| R16 | 39 | Potito StaraceClay | 63 | Gael MonfilsClay | 7-5 6-1 | 3 | 92 | 0 | 0 | 83.6% | 62.5% | 54.5% | 8/10 |
| R16 | 113 | Evgeny KorolevClay | 131 | Daniel Gimeno-TraverClay | 6-7(8) 7-6(2) 6-3 | 3 | 161 | 4 | 3 | 62.0% | 72.0% | 52.2% | 4/6 |
| R16 | 62 | Robin HaaseClay | 86 | Marat SafinClay | 2-6 7-6(9) 6-4 | 3 | 147 | 2 | 3 | 60.2% | 66.1% | 56.4% | 2/6 |
| R16 | 27 | Nicolas AlmagroClay | 124 | Eduardo SchwankClay | 6-3 6-4 | 3 | 79 | 6 | 0 | 73.2% | 75.6% | 66.7% | 2/3 |
| R16 | 17 | Juan MonacoClay | 65 | Guillermo Garcia-LopezClay | 6-4 6-4 | 3 | 90 | 1 | 0 | 79.3% | 69.6% | 66.7% | 1/2 |
| QF | 5 | David FerrerClay | 31 | Fernando VerdascoClay | 6-3 1-6 7-5 | 3 | 129 | 0 | 2 | 67.5% | 60.7% | 44.4% | 3/8 |
| QF | 18 | Tommy RobredoClay | 39 | Potito StaraceClay | 6-3 3-0 RET | 3 | 63 | 1 | 0 | 80.9% | 73.7% | 55.6% | 4/4 |
| QF | 113 | Evgeny KorolevClay | 62 | Robin HaaseClay | 7-5 6-4 | 3 | 113 | 6 | 2 | 67.4% | 60.0% | 44.8% | 8/12 |
| QF | 27 | Nicolas AlmagroClay | 17 | Juan MonacoClay | 6-3 6-2 | 3 | 74 | 2 | 3 | 53.0% | 71.4% | 58.1% | 5/6 |
| SF | 5 | David FerrerClay | 18 | Tommy RobredoClay | 2-6 6-2 6-3 | 3 | 137 | 0 | 1 | 67.8% | 62.7% | 53.6% | 8/11 |
| SF | 27 | Nicolas AlmagroClay | 113 | Evgeny KorolevClay | 6-1 6-4 | 3 | 60 | 10 | 3 | 65.5% | 75.0% | 63.2% | 1/1 |
| F | 5 | David FerrerClay | 27 | Nicolas AlmagroClay | 4-6 6-2 7-6(2) | 3 | 125 | 0 | 4 | 64.1% | 72.9% | 48.5% | 2/5 |
