| R32 | 85 |  Jan HernychClay | 6 |  Nikolay DavydenkoClay | 7-5 7-5 | 3 | 109 | 0 | 3 | 59.7% | 65.2% | 41.9% | 3/7 |
| R32 | 94 |  Guillermo Garcia-LopezClay | 43 | Feliciano LopezClay | 6-3 6-3 | 3 | 76 | 3 | 7 | 59.2% | 64.3% | 31.0% | 6/11 |
| R32 | 80 |  Potito StaraceClay | 74 | Lukas DlouhyClay | 6-3 6-3 | 3 | 52 | 2 | 0 | 87.0% | 72.5% | 66.7% | 0/1 |
| R32 | 34 | Fernando VerdascoClay | 60 | Alberto MartinClay | 6-3 6-4 | 3 | 89 | 3 | 1 | 66.7% | 68.2% | 50.0% | 5/7 |
| R32 | 127 |  Thierry AscioneClay | 10 | David FerrerClay | 7-6(1) RET | 3 | 46 | 0 | 1 | 61.9% | 65.4% | 43.8% | 4/6 |
| R32 | 54 | Andreas SeppiClay | 92 | Ruben Ramirez HidalgoClay | 6-2 6-2 | 3 | 46 | 0 | 1 | 61.9% | 65.4% | 43.8% | 4/6 |
| R32 | 86 | Gilles SimonClay | 69 | Robin VikClay | 6-3 6-2 | 3 | 65 | 3 | 0 | 50.0% | 79.2% | 58.3% | 0/2 |
| R32 | 52 | Davide SanguinettiClay | 131 |  Teymuraz GabashviliClay | 6-7(4) 6-4 6-3 | 3 | 129 | 3 | 1 | 38.9% | 73.8% | 51.5% | 7/11 |
| R32 | 33 | Filippo VolandriClay | 109 | Albert PortasClay | 6-0 6-1 | 3 | 45 | 0 | 0 | 70.3% | 84.6% | 72.7% | 1/1 |
| R32 | 88 | Tomas ZibClay | 87 |  Andrei PavelClay | 7-5 6-3 | 3 | 93 | 3 | 1 | 65.8% | 66.7% | 52.0% | 4/6 |
| R32 | 71 |  Bjorn PhauClay | 223 | Gorka FraileClay | 7-6(1) 6-7(4) 6-2 | 3 | 135 | 5 | 2 | 51.7% | 76.7% | 50.0% | 5/8 |
| R32 | 77 | Nicolas AlmagroClay | 15 | Juan Carlos FerreroClay | 6-7(3) 6-4 6-4 | 3 | 160 | 5 | 5 | 62.7% | 72.5% | 53.7% | 7/8 |
| R32 | 50 | Marat SafinClay | 28 | Igor AndreevClay | 7-6(6) 6-4 | 3 | 111 | 3 | 3 | 64.9% | 72.9% | 65.4% | 4/6 |
| R32 | 58 |  Boris PashanskiClay | 214 | Albert CostaClay | 3-6 6-3 6-4 | 3 | 116 | 0 | 1 | 57.1% | 71.9% | 45.8% | 5/7 |
| R32 | 70 | Florian MayerClay | 505 | Guillem BurniolClay | 6-0 6-3 | 3 | 51 | 5 | 2 | 73.5% | 72.2% | 53.8% | 7/8 |
| R32 | 9 |  Gaston GaudioClay | 95 |  Raemon SluiterClay | 7-6(6) 7-6(3) | 3 | 114 | 4 | 6 | 69.4% | 75.0% | 33.3% | 5/7 |
| R16 | 94 | Guillermo Garcia-LopezClay | 85 | Jan HernychClay | 6-2 6-4 | 3 | 67 | 2 | 4 | 58.0% | 57.4% | 50.0% | 9/13 |
| R16 | 34 | Fernando VerdascoClay | 80 | Potito StaraceClay | 6-3 7-6(4) | 3 | 93 | 1 | 3 | 78.3% | 70.8% | 55.6% | 6/7 |
| R16 | 54 | Andreas SeppiClay | 127 | Thierry AscioneClay | 1-6 6-1 6-2 | 3 | 91 | 7 | 3 | 64.9% | 70.0% | 51.9% | 6/8 |
| R16 | 86 | Gilles SimonClay | 52 | Davide SanguinettiClay | 3-6 7-5 6-3 | 3 | 114 | 4 | 1 | 55.6% | 71.1% | 55.6% | 4/8 |
| R16 | 33 | Filippo VolandriClay | 88 | Tomas ZibClay | 6-4 6-4 | 3 | 71 | 1 | 1 | 65.4% | 82.4% | 77.8% | 2/2 |
| R16 | 77 | Nicolas AlmagroClay | 71 | Bjorn PhauClay | 6-2 6-1 | 3 | 68 | 2 | 1 | 67.9% | 80.6% | 47.1% | 6/6 |
| R16 | 50 | Marat SafinClay | 58 | Boris PashanskiClay | 6-2 6-2 | 3 | 55 | 2 | 1 | 59.5% | 88.0% | 64.7% | 1/1 |
| R16 | 9 | Gaston GaudioClay | 70 | Florian MayerClay | 6-4 6-2 | 3 | 68 | 4 | 1 | 71.4% | 68.6% | 64.3% | 0/2 |
| QF | 34 | Fernando VerdascoClay | 94 | Guillermo Garcia-LopezClay | 6-7(2) 6-4 6-3 | 3 | 157 | 2 | 1 | 74.7% | 67.6% | 79.2% | 6/8 |
| QF | 86 | Gilles SimonClay | 54 | Andreas SeppiClay | 7-6(2) 7-6(4) | 3 | 106 | 2 | 2 | 51.8% | 77.3% | 63.4% | 4/5 |
| QF | 77 | Nicolas AlmagroClay | 33 | Filippo VolandriClay | 6-4 6-1 | 3 | 71 | 3 | 1 | 71.2% | 67.3% | 57.1% | 4/4 |
| QF | 50 | Marat SafinClay | 9 | Gaston GaudioClay | 6-4 6-4 | 3 | 81 | 4 | 0 | 67.2% | 78.0% | 65.0% | 4/4 |
| SF | 86 | Gilles SimonClay | 34 | Fernando VerdascoClay | 6-2 7-6(5) | 3 | 99 | 5 | 1 | 63.1% | 73.2% | 50.0% | 2/4 |
| SF | 77 | Nicolas AlmagroClay | 50 | Marat SafinClay | 6-2 2-6 6-4 | 3 | 134 | 3 | 1 | 62.2% | 66.1% | 50.0% | 8/11 |
| F | 77 | Nicolas AlmagroClay | 86 | Gilles SimonClay | 6-2 6-3 | 3 | 79 | 7 | 0 | 65.2% | 74.4% | 52.2% | 6/6 |
