| R32 | 3 |  Juan Carlos FerreroClay | 617 | Israel Matos GilClay | 6-2 7-5 | 3 | 85 | 3 | 3 | 60.0% | 84.8% | 54.5% | 0/1 |
| R32 | 96 |  Jan VacekClay | 489 | Guillem BurniolClay | 6-3 3-6 6-4 | 3 | 113 | 2 | 4 | 55.2% | 64.2% | 46.5% | 5/10 |
| R32 | 77 |  Mario AncicClay | 106 |  Harel LevyClay | 6-1 6-1 | 3 | 45 | 7 | 2 | 54.5% | 100.0% | 66.7% | 0/0 |
| R32 | 71 | Ruben Ramirez HidalgoClay | 140 | Alex CalatravaClay | 6-7(7) 7-6(1) 6-4 | 3 | 45 | 7 | 2 | 54.5% | 100.0% | 66.7% | 0/0 |
| R32 | 36 | Ivan LjubicicClay | 240 | Guillermo Garcia-LopezClay | 6-3 6-4 | 3 | 73 | 9 | 2 | 57.6% | 79.4% | 60.0% | 3/4 |
| R32 | 73 | Fernando VerdascoClay | 95 | Albert PortasClay | 6-1 6-4 | 3 | 55 | 6 | 0 | 66.7% | 83.3% | 73.3% | 0/0 |
| R32 | 78 |  Raemon SluiterClay | - | Dennis Van ScheppingenClay | 6-0 6-4 | 3 | 64 | 6 | 1 | 45.2% | 89.3% | 50.0% | 10/10 |
| R32 | 67 | David FerrerClay | 139 |  Giovanni LapenttiClay | 6-4 6-3 | 3 | 78 | 2 | 1 | 59.0% | 69.4% | 68.0% | 4/5 |
| R32 | 58 | Alberto MartinClay | 135 | Nicolas AlmagroClay | 6-2 6-4 | 3 | 85 | 2 | 3 | 59.7% | 63.0% | 54.8% | 6/7 |
| R32 | 101 | Fernando VicenteClay | 88 | Oscar HernandezClay | 7-6(5) 2-6 7-6(5) | 3 | 177 | 4 | 2 | 62.0% | 67.5% | 57.1% | 10/12 |
| R32 | 107 |  Christophe RochusClay | 165 |  Werner EschauerClay | 6-4 6-2 | 3 | 95 | 2 | 4 | 55.7% | 58.8% | 55.6% | 7/10 |
| R32 | 38 | Albert CostaClay | 91 | Galo BlancoClay | 6-3 6-4 | 3 | 69 | 9 | 1 | 69.4% | 88.2% | 66.7% | 0/0 |
| R32 | 103 | Alex CorretjaClay | 55 | David SanchezClay | 5-7 6-2 6-2 | 3 | 125 | 2 | 5 | 51.3% | 80.0% | 47.4% | 5/8 |
| R32 | 123 | Marc LopezClay | 89 | Stefan KoubekClay | 7-5 6-0 | 3 | 81 | 0 | 1 | 57.1% | 71.9% | 45.8% | 5/7 |
| R32 | 110 | Albert MontanesClay | 92 | John van LottumClay | 6-3 6-1 | 3 | 65 | 3 | 0 | 62.5% | 73.3% | 66.7% | 4/4 |
| R32 | 24 | Feliciano LopezClay | 80 |  Igor AndreevClay | 6-4 6-2 | 3 | 77 | 9 | 3 | 49.1% | 85.7% | 55.2% | 1/1 |
| R16 | 3 | Juan Carlos FerreroClay | 96 | Jan VacekClay | 6-3 7-5 | 3 | 91 | 2 | 4 | 60.8% | 77.8% | 44.8% | 7/9 |
| R16 | 77 | Mario AncicClay | 71 | Ruben Ramirez HidalgoClay | 7-5 6-2 | 3 | 88 | 6 | 4 | 43.4% | 82.6% | 56.7% | 0/2 |
| R16 | 73 | Fernando VerdascoClay | 36 | Ivan LjubicicClay | 6-4 6-4 | 3 | 75 | 3 | 2 | 70.2% | 75.0% | 70.6% | 3/3 |
| R16 | 67 | David FerrerClay | 78 | Raemon SluiterClay | 6-2 6-4 | 3 | 70 | 3 | 1 | 72.9% | 67.4% | 62.5% | 5/6 |
| R16 | 58 | Alberto MartinClay | 101 | Fernando VicenteClay | 6-3 5-7 6-4 | 3 | 136 | 0 | 5 | 63.9% | 71.0% | 54.3% | 3/6 |
| R16 | 107 | Christophe RochusClay | 38 | Albert CostaClay | 6-4 6-3 | 3 | 86 | 0 | 2 | 64.4% | 65.8% | 38.1% | 4/7 |
| R16 | 123 | Marc LopezClay | 103 | Alex CorretjaClay | 6-4 6-4 | 3 | 113 | 0 | 2 | 76.2% | 70.8% | 53.3% | 2/3 |
| R16 | 110 | Albert MontanesClay | 24 | Feliciano LopezClay | 4-6 6-2 6-4 | 3 | 105 | 7 | 2 | 59.3% | 66.7% | 72.7% | 4/6 |
| QF | 3 | Juan Carlos FerreroClay | 77 | Mario AncicClay | 6-4 6-4 | 3 | 87 | 4 | 1 | 60.0% | 69.0% | 60.7% | 4/5 |
| QF | 73 | Fernando VerdascoClay | 67 | David FerrerClay | 6-2 6-3 | 3 | 66 | 1 | 2 | 71.4% | 82.9% | 50.0% | 5/6 |
| QF | 58 | Alberto MartinClay | 107 | Christophe RochusClay | 6-1 6-2 | 3 | 63 | 2 | 3 | 64.0% | 54.2% | 59.3% | 8/10 |
| QF | 110 | Albert MontanesClay | 123 | Marc LopezClay | 2-6 6-2 6-0 | 3 | 109 | 5 | 1 | 64.5% | 65.3% | 59.3% | 4/6 |
| SF | 73 | Fernando VerdascoClay | 3 | Juan Carlos FerreroClay | 6-2 6-1 | 3 | 61 | 0 | 3 | 81.3% | 76.9% | 44.4% | 3/3 |
| SF | 110 | Albert MontanesClay | 58 | Alberto MartinClay | 4-6 6-2 6-2 | 3 | 111 | 2 | 6 | 68.9% | 80.4% | 39.1% | 2/4 |
| F | 73 | Fernando VerdascoClay | 110 | Albert MontanesClay | 7-6(5) 6-3 | 3 | 96 | 3 | 3 | 72.4% | 69.1% | 61.9% | 4/6 |
