| R16 | 10 |  Jannik SinnerClay | 59 |  Jaume MunarClay | 6-4 6-4 | 3 | 116 | 1 | 4 | 52.9% | 72.2% | 50.0% | 6/8 |
| R32 | 136 | Franco AgamenoneClay | 77 |  Laslo DjereClay | 7-6(8) 2-6 7-5 | 3 | 177 | 2 | 2 | 66.1% | 62.2% | 50.0% | 10/16 |
| R32 | 151 | Marco CecchinatoClay | 538 |  Mili PoljicakClay | 6-1 5-7 6-2 | 3 | 175 | 1 | 2 | 71.5% | 56.8% | 62.9% | 10/13 |
| R32 | 31 | Lorenzo MusettiClay | 283 | SLOAljaz BedeneClay | 6-2 3-6 6-1 | 3 | 115 | 2 | 1 | 60.3% | 63.4% | 63.0% | 1/4 |
| R32 | 99 |  Daniel Elahi GalanClay | 54 | Fabio FogniniClay | 6-3 5-7 6-3 | 3 | 163 | 2 | 2 | 58.0% | 63.1% | 48.9% | 11/16 |
| R32 | 168 | Giulio ZeppieriClay | 90 |  Pedro CachinClay | 3-6 6-1 6-4 | 3 | 114 | 5 | 1 | 73.5% | 84.0% | 50.0% | 1/2 |
| R32 | 82 | Bernabe Zapata MirallesClay | 815 | Dino PrizmicClay | 6-4 3-0 RET | 3 | 96 | 0 | 2 | 72.3% | 58.8% | 38.5% | 2/5 |
| R32 | 116 |  Corentin MoutetClay | 65 |  Daniel AltmaierClay | 6-4 6-2 | 3 | 105 | 0 | 3 | 70.8% | 65.2% | 31.6% | 6/9 |
| R32 | 120 | Facundo BagnisClay | 72 | Tomas Martin EtcheverryClay | 7-5 6-3 | 3 | 117 | 1 | 2 | 49.2% | 82.8% | 63.3% | 1/2 |
| R32 | 117 |  Norbert GombosClay | 123 | Federico DelbonisClay | 6-4 5-7 6-4 | 3 | 137 | 5 | 3 | 54.2% | 82.2% | 57.9% | 0/2 |
| R16 | 86 | Roberto Carballes BaenaClay | 38 | Alex MolcanClay | 3-6 6-2 6-3 | 3 | 159 | 0 | 3 | 56.0% | 70.2% | 51.4% | 5/8 |
| R16 | 136 | Franco AgamenoneClay | 32 | Sebastian BaezClay | 3-6 6-1 7-5 | 3 | 145 | 1 | 4 | 64.9% | 63.9% | 54.5% | 8/11 |
| R16 | 151 | Marco CecchinatoClay | 31 | Lorenzo MusettiClay | 6-4 6-3 | 3 | 75 | 0 | 1 | 73.6% | 69.2% | 71.4% | 1/3 |
| R16 | 168 | Giulio ZeppieriClay | 99 | Daniel Elahi GalanClay | 6-4 3-6 6-1 | 3 | 129 | 4 | 4 | 60.8% | 77.8% | 58.6% | 1/2 |
| R16 | 82 | Bernabe Zapata MirallesClay | 27 |  Holger RuneClay | 3-6 6-3 6-2 | 3 | 112 | 2 | 1 | 60.5% | 63.5% | 58.8% | 8/10 |
| R16 | 120 | Facundo BagnisClay | 116 | Corentin MoutetClay | 6-3 6-1 | 3 | 81 | 0 | 0 | 71.2% | 64.9% | 53.3% | 7/9 |
| R16 | 5 | Carlos AlcarazClay | 117 | Norbert GombosClay | 6-2 6-3 | 3 | 97 | 2 | 1 | 62.3% | 71.1% | 60.9% | 7/7 |
| QF | 10 | Jannik SinnerClay | 86 | Roberto Carballes BaenaClay | 6-4 7-6(5) | 3 | 138 | 6 | 2 | 51.5% | 82.9% | 60.6% | 0/1 |
| QF | 136 | Franco AgamenoneClay | 151 | Marco CecchinatoClay | 6-2 6-1 | 3 | 77 | 1 | 1 | 72.5% | 79.3% | 72.7% | 2/2 |
| QF | 168 | Giulio ZeppieriClay | 82 | Bernabe Zapata MirallesClay | 7-5 6-4 | 3 | 101 | 6 | 0 | 57.7% | 73.2% | 60.0% | 5/6 |
| QF | 5 | Carlos AlcarazClay | 120 | Facundo BagnisClay | 6-0 6-4 | 3 | 84 | 2 | 3 | 61.5% | 81.3% | 45.0% | 1/1 |
| SF | 10 | Jannik SinnerClay | 136 | Franco AgamenoneClay | 6-1 6-3 | 3 | 86 | 0 | 1 | 62.8% | 77.8% | 56.3% | 2/3 |
| SF | 5 | Carlos AlcarazClay | 168 | Giulio ZeppieriClay | 7-5 4-6 6-3 | 3 | 175 | 3 | 5 | 58.7% | 67.2% | 51.2% | 9/13 |
| F | 10 | Jannik SinnerClay | 5 | Carlos AlcarazClay | 6-7(5) 6-1 6-1 | 3 | 145 | 6 | 4 | 57.6% | 77.4% | 61.5% | 9/9 |
| R32 | 59 | Jaume MunarClay | 108 |  Mikael YmerClay | 4-6 6-1 6-4 | 3 | 156 | 1 | 1 | 59.5% | 76.6% | 37.5% | 4/8 |
| R32 | 86 | Roberto Carballes BaenaClay | 110 |  Henri LaaksonenClay | 6-4 7-5 | 3 | 121 | 4 | 1 | 65.3% | 71.4% | 50.0% | 7/9 |
| R32 | 38 | Alex MolcanClay | 276 | Duje AjdukovicClay | 6-2 7-6(2) | 3 | 107 | 1 | 1 | 61.9% | 64.1% | 45.8% | 7/11 |
