| R16 | 45 |  Dusan LajovicClay | 121 |  Bernabe Zapata MirallesClay | 7-5 6-4 | 3 | 110 | 1 | 2 | 50.7% | 75.0% | 51.4% | 5/7 |
| R32 | 121 | Bernabe Zapata MirallesClay | 94 |  Pablo CuevasClay | 4-6 6-2 6-4 | 3 | 126 | 2 | 0 | 65.5% | 68.4% | 53.3% | 5/8 |
| R32 | 152 |  Daniel AltmaierClay | 88 |  Corentin MoutetClay | 5-7 6-1 RET | 3 | 125 | 0 | 1 | 58.5% | 73.7% | 44.4% | 6/8 |
| R32 | 75 |  Gianluca MagerClay | 97 | Pedro MartinezClay | 0-6 6-3 6-3 | 3 | 115 | 3 | 5 | 59.1% | 71.8% | 44.4% | 6/10 |
| R32 | 177 | Alessandro GiannessiClay | 86 |  Jiri VeselyClay | 7-6(4) 7-5 | 3 | 119 | 6 | 5 | 65.1% | 75.0% | 46.7% | 3/5 |
| R32 | 127 |  Damir DzumhurClay | 185 |  Filip HoranskyClay | 6-4 6-3 | 3 | 76 | 0 | 0 | 70.0% | 71.4% | 66.7% | 0/1 |
| R32 | 82 | Marco CecchinatoClay | 58 | SLOAljaz BedeneClay | 6-1 6-4 | 3 | 65 | 5 | 0 | 75.5% | 75.7% | 75.0% | 0/0 |
| R32 | 73 | Carlos AlcarazClay | 103 | Lucas PouilleClay | 3-6 6-2 6-2 | 3 | 126 | 0 | 0 | 65.8% | 70.8% | 44.0% | 2/5 |
| R32 | 117 | Andrej MartinClay | 215 |  Renzo OlivoClay | 1-6 6-2 7-6(1) | 3 | 156 | 0 | 5 | 75.7% | 57.1% | 40.7% | 14/20 |
| R32 | 92 |  Radu AlbotClay | 204 |  Holger RuneClay | 1-6 6-3 6-2 | 3 | 123 | 5 | 8 | 64.4% | 66.0% | 50.0% | 1/4 |
| R32 | 91 | Stefano TravagliaClay | 67 | Jaume MunarClay | 6-3 7-6(1) | 3 | 112 | 3 | 1 | 55.4% | 73.2% | 51.5% | 5/7 |
| R32 | 108 | Carlos TabernerClay | 288 |  Nino SerdarusicClay | 6-2 6-2 | 3 | 78 | 3 | 1 | 67.3% | 75.8% | 56.3% | 0/0 |
| R32 | 275 | Duje AjdukovicClay | 210 | Andrea CollariniClay | 6-3 6-2 | 3 | 72 | 3 | 0 | 58.7% | 66.7% | 52.6% | 0/2 |
| R16 | 152 | Daniel AltmaierClay | 75 | Gianluca MagerClay | 4-6 6-1 7-5 | 3 | 108 | 9 | 2 | 62.9% | 81.8% | 61.5% | 1/3 |
| R16 | 59 | Richard GasquetClay | 177 | Alessandro GiannessiClay | 7-6(4) 6-4 | 3 | 111 | 3 | 3 | 58.1% | 86.1% | 69.2% | 0/0 |
| R16 | 127 | Damir DzumhurClay | 82 | Marco CecchinatoClay | 6-3 6-1 | 3 | 67 | 1 | 1 | 83.7% | 75.6% | 37.5% | 0/0 |
| R16 | 73 | Carlos AlcarazClay | 117 | Andrej MartinClay | 6-3 6-1 | 3 | 75 | 1 | 2 | 73.1% | 65.8% | 50.0% | 3/5 |
| R16 | 34 | Filip KrajinovicClay | 92 | Radu AlbotClay | 6-4 6-2 | 3 | 87 | 2 | 3 | 58.2% | 75.0% | 60.9% | 3/4 |
| R16 | 91 | Stefano TravagliaClay | 108 | Carlos TabernerClay | 6-4 6-3 | 3 | 101 | 8 | 2 | 61.0% | 69.4% | 56.5% | 2/4 |
| R16 | 43 | Albert Ramos-VinolasClay | 275 | Duje AjdukovicClay | 7-5 6-4 | 3 | 113 | 2 | 2 | 65.2% | 68.9% | 54.2% | 4/6 |
| QF | 152 | Daniel AltmaierClay | 45 | Dusan LajovicClay | 6-2 6-4 | 3 | 91 | 4 | 2 | 51.8% | 93.1% | 40.7% | 4/5 |
| QF | 59 | Richard GasquetClay | 127 | Damir DzumhurClay | 6-3 7-6(7) | 3 | 110 | 3 | 2 | 65.3% | 73.5% | 50.0% | 2/4 |
| QF | 73 | Carlos AlcarazClay | 34 | Filip KrajinovicClay | 7-6(3) 2-6 6-1 | 3 | 138 | 0 | 2 | 70.8% | 69.8% | 38.5% | 5/9 |
| QF | 43 | Albert Ramos-VinolasClay | 91 | Stefano TravagliaClay | 6-2 6-1 | 3 | 67 | 1 | 5 | 69.2% | 72.2% | 56.3% | 1/2 |
| SF | 59 | Richard GasquetClay | 152 | Daniel AltmaierClay | 7-6(2) 3-6 6-3 | 3 | 191 | 6 | 3 | 58.9% | 69.9% | 45.1% | 7/10 |
| SF | 73 | Carlos AlcarazClay | 43 | Albert Ramos-VinolasClay | 6-2 7-6(3) | 3 | 119 | 1 | 2 | 71.4% | 64.0% | 50.0% | 5/8 |
| F | 73 | Carlos AlcarazClay | 59 | Richard GasquetClay | 6-2 6-2 | 3 | 76 | 0 | 2 | 55.1% | 77.8% | 59.1% | 3/3 |
