| R32 | 78 |  Ernests GulbisClay | 930 |  Gorka FraileClay | 6-1 6-3 | 3 | 64 | 14 | 5 | 61.5% | 90.6% | 35.0% | 2/2 |
| R32 | 130 |  Wayne OdesnikClay | 74 |  Edouard Roger-VasselinClay | 6-7(4) 6-2 7-5 | 3 | 173 | 6 | 5 | 60.0% | 68.2% | 61.4% | 7/9 |
| R32 | 71 | SLOBlaz KavcicClay | 131 |  Antonio VeicClay | 6-2 6-2 | 3 | 75 | 0 | 1 | 65.0% | 73.1% | 71.4% | 0/1 |
| R32 | 120 |  Daniel BrandsClay | 386 |  Walter TrusendiClay | 6-1 7-6(8) | 3 | 107 | 3 | 3 | 58.2% | 71.8% | 46.4% | 2/4 |
| R32 | 137 |  Andrey KuznetsovClay | 136 | Daniel Munoz de la NavaClay | 6-3 5-7 7-6(5) | 3 | 177 | 7 | 8 | 64.0% | 71.8% | 42.5% | 2/6 |
| R32 | 547 | Mate PavicClay | 37 | Juan Carlos FerreroClay | 6-2 6-2 | 3 | 61 | 5 | 3 | 61.8% | 73.5% | 57.1% | 4/4 |
| R32 | 95 | Potito StaraceClay | 427 |  Ivo KlecClay | 6-3 7-6(6) | 3 | 102 | 3 | 1 | 74.6% | 72.3% | 81.3% | 1/2 |
| R32 | 108 | Matthias BachingerClay | 143 |  Joao SousaClay | 6-7(5) 6-1 7-6(6) | 3 | 162 | 11 | 4 | 47.7% | 76.9% | 43.9% | 10/14 |
| R32 | 60 | Martin KlizanClay | 111 | SLOAljaz BedeneClay | 6-2 6-2 | 3 | 77 | 2 | 3 | 48.9% | 78.3% | 58.3% | 1/2 |
| R32 | 38 |  Carlos BerlocqClay | 97 | Ivan DodigClay | 6-4 6-0 | 3 | 85 | 1 | 1 | 76.9% | 83.3% | 77.8% | 0/0 |
| R32 | 250 | Marco TrungellitiClay | 88 | Paolo LorenziClay | 7-5 6-4 | 3 | 127 | 1 | 5 | 57.1% | 61.4% | 54.5% | 5/8 |
| R32 | 63 | Fabio FogniniClay | 117 | Karol BeckClay | 6-3 6-1 | 3 | 61 | 1 | 2 | 65.0% | 84.6% | 71.4% | 0/0 |
| R16 | 16 | Fernando VerdascoClay | 78 | Ernests GulbisClay | 6-2 3-6 6-1 | 3 | 126 | 4 | 6 | 64.0% | 83.3% | 40.7% | 4/6 |
| R16 | 137 | Andrey KuznetsovClay | 547 | Mate PavicClay | 7-6(0) 6-1 | 3 | 89 | 2 | 3 | 51.7% | 80.6% | 62.1% | 2/3 |
| R16 | 24 | Marcel GranollersClay | 95 | Potito StaraceClay | 6-4 3-6 6-3 | 3 | 146 | 3 | 2 | 67.1% | 76.4% | 37.0% | 5/8 |
| R16 | 108 | Matthias BachingerClay | 60 | Martin KlizanClay | 6-0 2-6 6-4 | 3 | 114 | 8 | 1 | 52.0% | 71.8% | 44.4% | 5/8 |
| R16 | 38 | Carlos BerlocqClay | 250 | Marco TrungellitiClay | 7-6(4) 4-6 6-1 | 3 | 187 | 2 | 5 | 66.0% | 60.3% | 40.0% | 6/12 |
| R16 | 19 |  Alexandr DolgopolovClay | 63 | Fabio FogniniClay | 6-2 6-4 | 3 | 76 | 1 | 0 | 53.6% | 80.0% | 57.7% | 2/2 |
| R16 | 130 | Wayne OdesnikClay | 71 | SLOBlaz KavcicClay | 3-6 7-5 7-6(3) | 3 | 188 | 2 | 7 | 58.3% | 60.0% | 42.0% | 11/19 |
| R16 | 15 | Marin CilicClay | 120 | Daniel BrandsClay | 6-3 6-2 | 3 | 65 | 6 | 0 | 55.8% | 72.4% | 60.9% | 2/3 |
| QF | 16 | Fernando VerdascoClay | 137 | Andrey KuznetsovClay | 6-2 6-2 | 3 | 85 | 2 | 3 | 73.8% | 80.0% | 37.5% | 6/6 |
| QF | 24 | Marcel GranollersClay | 108 | Matthias BachingerClay | 1-6 6-3 7-5 | 3 | 137 | 0 | 2 | 63.3% | 78.0% | 55.2% | 7/10 |
| QF | 19 | Alexandr DolgopolovClay | 38 | Carlos BerlocqClay | 6-4 6-4 | 3 | 84 | 4 | 2 | 46.7% | 85.7% | 56.3% | 4/5 |
| QF | 15 | Marin CilicClay | 130 | Wayne OdesnikClay | 6-4 6-0 | 3 | 92 | 8 | 2 | 60.0% | 74.4% | 42.3% | 5/6 |
| SF | 24 | Marcel GranollersClay | 16 | Fernando VerdascoClay | 6-2 6-7(5) 6-1 | 3 | 172 | 5 | 2 | 61.7% | 63.8% | 63.9% | 0/2 |
| SF | 15 | Marin CilicClay | 19 | Alexandr DolgopolovClay | 7-5 6-2 | 3 | 81 | 1 | 2 | 44.1% | 65.4% | 63.6% | 0/2 |
| F | 15 | Marin CilicClay | 24 | Marcel GranollersClay | 6-4 6-2 | 3 | 92 | 0 | 1 | 60.4% | 68.8% | 57.1% | 1/3 |
