| R32 | 132 |  Andrei PavelClay | 12 |  Ivan LjubicicClay | 7-6(5) 7-5 | 3 | 128 | 1 | 2 | 65.4% | 68.6% | 44.4% | 4/7 |
| R32 | 16 |  David FerrerClay | 52 | Albert MontanesClay | 6-2 6-2 | 3 | 73 | 1 | 2 | 60.4% | 79.3% | 47.4% | 2/3 |
| R32 | 3 |  Novak DjokovicClay | 182 | Pablo AndujarClay | 6-1 6-3 | 3 | 71 | 3 | 1 | 67.9% | 73.7% | 61.1% | 6/6 |
| R32 | 176 | Viktor TroickiClay | 261 | MKDPredrag RusevskiClay | 6-3 1-6 6-4 | 3 | 134 | 6 | 3 | 52.3% | 69.6% | 52.4% | 5/8 |
| R32 | 75 |  Carlos BerlocqClay | 260 | Maximo GonzalezClay | 6-3 6-4 | 3 | 91 | 4 | 4 | 52.7% | 79.3% | 50.0% | 1/3 |
| R32 | 257 | Victor HanescuClay | 48 | Janko TipsarevicClay | 2-0 RET | 3 | 4 | 1 | 0 | 100.0% | 100.0% | NaN% | 0/0 |
| R32 | 105 |  Robin HaaseClay | 421 | Felix MantillaClay | 2-6 6-4 6-4 | 3 | 117 | 3 | 2 | 60.8% | 62.7% | 55.3% | 3/6 |
| R32 | 134 |  Mischa ZverevClay | 77 |  Florent SerraClay | 6-0 7-5 | 3 | 81 | 3 | 1 | 54.4% | 74.2% | 69.2% | 3/4 |
| R32 | 25 |  Filippo VolandriClay | 122 |  Lukas DlouhyClay | 6-2 6-1 | 3 | 63 | 0 | 1 | 85.1% | 59.6% | 60.0% | 4/6 |
| R32 | 20 | Carlos MoyaClay | 35 |  Stan WawrinkaClay | 6-3 6-2 | 3 | 65 | 2 | 4 | 64.4% | 89.7% | 37.5% | 2/3 |
| R32 | 398 | Pere RibaClay | 698 | Luka BelicClay | 6-2 2-6 6-4 | 3 | 141 | 2 | 3 | 58.8% | 63.8% | 57.6% | 5/8 |
| R32 | 70 | Jose AcasusoClay | 84 | Edouard Roger-VasselinClay | 6-2 6-0 | 3 | 51 | 2 | 4 | 45.2% | 84.2% | 65.2% | 1/1 |
| R32 | 15 | Guillermo CanasClay | 200 | Roko KaranusicClay | 6-3 6-3 | 3 | 94 | 2 | 1 | 57.8% | 70.3% | 63.0% | 5/5 |
| R32 | 108 | Ruben Ramirez HidalgoClay | 117 | Gaston GaudioClay | 6-0 6-4 | 3 | 74 | 4 | 2 | 70.5% | 67.7% | 69.2% | 1/2 |
| R32 | 114 | Marin CilicClay | 128 | Mathieu MontcourtClay | 3-6 6-4 6-1 | 3 | 125 | 6 | 3 | 42.4% | 80.6% | 51.0% | 8/11 |
| R32 | 50 | Gilles SimonClay | 4 |  Nikolay DavydenkoClay | 6-2 2-6 6-3 | 3 | 137 | 5 | 4 | 42.1% | 72.9% | 47.0% | 16/19 |
| R16 | 176 | Viktor TroickiClay | 3 | Novak DjokovicClay | 2-6 6-4 7-5 | 3 | 142 | 2 | 3 | 55.0% | 67.3% | 37.8% | 8/14 |
| R16 | 75 | Carlos BerlocqClay | 257 | Victor HanescuClay | 6-7(13) 6-4 6-2 | 3 | 189 | 6 | 1 | 59.5% | 76.8% | 53.2% | 10/10 |
| R16 | 132 | Andrei PavelClay | 105 | Robin HaaseClay | 7-5 6-4 | 3 | 87 | 3 | 2 | 61.3% | 76.3% | 66.7% | 3/4 |
| R16 | 25 | Filippo VolandriClay | 134 | Mischa ZverevClay | 7-6(2) 7-5 | 3 | 102 | 1 | 3 | 73.8% | 71.2% | 42.9% | 4/7 |
| R16 | 20 | Carlos MoyaClay | 398 | Pere RibaClay | 6-0 6-3 | 3 | 51 | 1 | 0 | 51.3% | 85.0% | 68.4% | 2/2 |
| R16 | 16 | David FerrerClay | 70 | Jose AcasusoClay | 2-6 7-6(4) 6-2 | 3 | 144 | 6 | 2 | 64.9% | 74.6% | 41.2% | 6/9 |
| R16 | 15 | Guillermo CanasClay | 108 | Ruben Ramirez HidalgoClay | 6-4 6-3 | 3 | 114 | 8 | 2 | 48.9% | 82.6% | 45.8% | 1/4 |
| R16 | 50 | Gilles SimonClay | 114 | Marin CilicClay | 7-5 2-6 6-3 | 3 | 147 | 4 | 1 | 55.1% | 59.3% | 47.7% | 10/16 |
| QF | 176 | Viktor TroickiClay | 75 | Carlos BerlocqClay | 7-5 6-2 | 3 | 95 | 2 | 4 | 68.3% | 67.4% | 60.0% | 2/4 |
| QF | 132 | Andrei PavelClay | 25 | Filippo VolandriClay | 1-6 6-2 6-3 | 3 | 107 | 4 | 1 | 53.3% | 75.0% | 54.3% | 2/4 |
| QF | 20 | Carlos MoyaClay | 16 | David FerrerClay | 7-5 6-4 | 3 | 97 | 2 | 1 | 67.1% | 58.5% | 53.8% | 2/5 |
| QF | 15 | Guillermo CanasClay | 50 | Gilles SimonClay | 6-2 6-1 | 3 | 74 | 2 | 0 | 44.2% | 57.9% | 66.7% | 4/6 |
| SF | 132 | Andrei PavelClay | 176 | Viktor TroickiClay | 6-3 6-3 | 3 | 90 | 0 | 3 | 57.9% | 69.7% | 45.8% | 1/3 |
| SF | 20 | Carlos MoyaClay | 15 | Guillermo CanasClay | 6-3 6-2 | 3 | 84 | 1 | 0 | 68.0% | 73.5% | 50.0% | 1/2 |
| F | 20 | Carlos MoyaClay | 132 | Andrei PavelClay | 6-4 6-2 | 3 | 88 | 9 | 2 | 68.2% | 82.2% | 47.6% | 4/4 |
