| R32 | 111 |  Carlos BerlocqClay | 113 |  Stefano GalvaniClay | 6-2 6-2 | 3 | 68 | 1 | 0 | 75.6% | 70.6% | 63.6% | 3/4 |
| R32 | 373 | Juan-Pablo GuzmanClay | 80 |  Guillermo Garcia-LopezClay | 4-6 6-3 6-4 | 3 | 142 | 1 | 6 | 61.1% | 66.7% | 52.4% | 5/7 |
| R32 | 76 |  Simon GreulClay | 93 | Alessio Di MauroClay | 7-5 7-6(5) | 3 | 135 | 2 | 5 | 51.6% | 74.5% | 45.5% | 6/9 |
| R32 | 42 | Carlos MoyaClay | 130 |  Jiri NovakClay | 6-4 6-7(6) 7-6(3) | 3 | 153 | 10 | 2 | 50.8% | 71.7% | 62.1% | 7/8 |
| R32 | 28 |  Novak DjokovicClay | 1543 |  Luka BelicClay | 6-3 6-3 | 3 | 60 | 3 | 2 | 73.9% | 73.5% | 58.3% | 0/2 |
| R32 | 559 | Stefano IanniClay | 99 |  Teymuraz GabashviliClay | 6-6(4) RET | 3 | 57 | 3 | 4 | 66.7% | 64.7% | 47.1% | 4/6 |
| R32 | 110 | Jiri VanekClay | 288 | Santiago VenturaClay | 7-5 6-4 | 3 | 80 | 1 | 1 | 74.2% | 71.7% | 56.3% | 2/3 |
| R32 | 79 | Lukas DlouhyClay | 53 |  Julien BenneteauClay | 2-6 6-3 6-2 | 3 | 110 | 4 | 3 | 62.4% | 58.5% | 68.8% | 5/8 |
| R32 | 69 |  Stan WawrinkaClay | 48 | Alberto MartinClay | 7-6(3) 6-4 | 3 | 114 | 3 | 3 | 52.5% | 69.0% | 55.3% | 2/4 |
| R32 | 209 | Marin CilicClay | 115 |  Evgeny KorolevClay | 6-7(5) 6-4 6-3 | 3 | 167 | 10 | 6 | 50.0% | 81.1% | 45.3% | 5/8 |
| R32 | 133 | Juan Martin del PotroClay | 94 |  Raemon SluiterClay | 6-3 6-2 | 3 | 59 | 6 | 3 | 75.0% | 83.3% | 58.3% | 2/2 |
| R32 | 74 | Robin VikClay | 27 | Guillermo CoriaClay | 6-2 6-3 | 3 | 70 | 2 | 6 | 49.2% | 58.6% | 40.0% | 2/6 |
| R32 | 57 | Filippo VolandriClay | 84 | Marc GicquelClay | 6-1 RET | 3 | 26 | 1 | 3 | 68.2% | 80.0% | 42.9% | 2/3 |
| R32 | 55 | Ruben Ramirez HidalgoClay | 100 | Fernando VicenteClay | 5-7 6-0 6-1 | 3 | 96 | 2 | 1 | 64.7% | 81.8% | 58.3% | 6/8 |
| R32 | 104 | Jan HernychClay | 143 | Flavio CipollaClay | 6-2 6-1 | 3 | 72 | 1 | 0 | 78.8% | 75.6% | 27.3% | 2/3 |
| R32 | 122 | Albert PortasClay | 30 | Juan Carlos FerreroClay | 7-6(4) 6-7(5) 7-5 | 3 | 168 | 15 | 7 | 56.2% | 76.5% | 39.6% | 10/14 |
| R16 | 373 | Juan-Pablo GuzmanClay | 111 | Carlos BerlocqClay | 3-6 6-3 6-2 | 3 | 133 | 0 | 3 | 71.1% | 67.2% | 57.7% | 8/10 |
| R16 | 42 | Carlos MoyaClay | 76 | Simon GreulClay | 6-2 6-1 | 3 | 60 | 4 | 1 | 57.9% | 78.8% | 37.5% | 4/6 |
| R16 | 28 | Novak DjokovicClay | 559 | Stefano IanniClay | 6-3 6-4 | 3 | 172 | 3 | 1 | 62.5% | 82.9% | 57.1% | 3/4 |
| R16 | 110 | Jiri VanekClay | 79 | Lukas DlouhyClay | 7-6(4) 6-4 | 3 | 107 | 7 | 7 | 62.2% | 64.7% | 45.2% | 4/8 |
| R16 | 69 | Stan WawrinkaClay | 209 | Marin CilicClay | 6-4 2-6 6-4 | 3 | 139 | 5 | 5 | 68.4% | 66.2% | 40.0% | 11/15 |
| R16 | 133 | Juan Martin del PotroClay | 74 | Robin VikClay | 2-6 6-4 6-3 | 3 | 121 | 3 | 4 | 74.5% | 57.1% | 45.8% | 4/9 |
| R16 | 57 | Filippo VolandriClay | 55 | Ruben Ramirez HidalgoClay | 4-6 7-6(4) 7-6(5) | 3 | 183 | 0 | 4 | 63.2% | 58.1% | 53.5% | 2/9 |
| R16 | 122 | Albert PortasClay | 104 | Jan HernychClay | 5-7 6-4 6-2 | 3 | 125 | 5 | 5 | 54.8% | 80.4% | 45.2% | 6/9 |
| QF | 42 | Carlos MoyaClay | 373 | Juan-Pablo GuzmanClay | 6-1 6-4 | 3 | 72 | 2 | 3 | 50.0% | 92.0% | 52.0% | 0/1 |
| QF | 28 | Novak DjokovicClay | 110 | Jiri VanekClay | 6-1 3-6 7-5 | 3 | 110 | 6 | 6 | 56.3% | 64.4% | 51.4% | 3/8 |
| QF | 69 | Stan WawrinkaClay | 133 | Juan Martin del PotroClay | 6-1 2-6 6-4 | 3 | 118 | 2 | 1 | 56.8% | 67.4% | 54.3% | 4/7 |
| QF | 57 | Filippo VolandriClay | 122 | Albert PortasClay | 7-6(4) 6-4 | 3 | 98 | 1 | 3 | 76.6% | 61.0% | 50.0% | 4/7 |
| SF | 28 | Novak DjokovicClay | 42 | Carlos MoyaClay | 6-1 7-5 | 3 | 82 | 0 | 3 | 67.2% | 73.2% | 55.0% | 2/3 |
| SF | 69 | Stan WawrinkaClay | 57 | Filippo VolandriClay | 7-5 2-6 6-4 | 3 | 124 | 4 | 2 | 51.9% | 64.3% | 35.9% | 3/10 |
| F | 69 | Stan WawrinkaClay | 28 | Novak DjokovicClay | 6-6(1) RET | 3 | 73 | 0 | 1 | 57.8% | 65.4% | 47.4% | 3/5 |
