| R16 | 28 |  Juan Carlos FerreroClay | 97 |  Novak DjokovicClay | 6-4 6-2 | 3 | 78 | 0 | 2 | 78.2% | 69.8% | 50.0% | 2/4 |
| R32 | 129 |  Lukas DlouhyClay | 58 | Alberto MartinClay | 7-5 6-3 | 3 | 92 | 2 | 5 | 72.4% | 67.3% | 33.3% | 2/5 |
| R32 | 388 | Ilija BozoljacClay | 117 |  Francesco AldiClay | 6-3 6-3 | 3 | 64 | 12 | 2 | 49.1% | 85.2% | 46.4% | 5/6 |
| R32 | 133 | Albert PortasClay | 82 | Jiri VanekClay | 6-1 6-0 | 3 | 40 | 6 | 3 | 57.9% | 81.8% | 68.8% | 1/1 |
| R32 | 24 | Jiri NovakClay | 84 | Albert MontanesClay | 6-3 6-3 | 3 | 61 | 6 | 0 | 68.8% | 84.8% | 53.3% | 0/0 |
| R32 | 21 | David FerrerClay | 94 | Potito StaraceClay | 6-3 3-6 6-2 | 3 | 113 | 1 | 3 | 66.7% | 64.8% | 51.9% | 3/6 |
| R32 | 126 | Fernando VicenteClay | 207 |  Victor IonitaClay | 6-2 6-2 | 3 | 65 | 1 | 0 | 52.9% | 70.4% | 45.8% | 3/5 |
| R32 | 127 |  Kristof VliegenClay | 864 |  Marin CilicClay | 7-5 6-2 | 3 | 95 | 2 | 0 | 57.1% | 69.4% | 63.0% | 1/2 |
| R32 | 29 | Carlos MoyaClay | 123 | Bohdan UlihrachClay | 6-2 RET | 3 | 46 | 0 | 2 | 41.9% | 69.2% | 66.7% | 1/1 |
| R32 | 37 | Filippo VolandriClay | 179 | Sasa TuksarClay | 6-2 6-1 | 3 | 53 | 2 | 2 | 84.4% | 68.4% | 42.9% | 1/2 |
| R32 | 86 | Guillermo Garcia-LopezClay | 79 | Oscar HernandezClay | 6-2 6-2 | 3 | 54 | 1 | 3 | 52.3% | 69.6% | 66.7% | 1/2 |
| R32 | 92 | Janko TipsarevicClay | 104 | Dick NormanClay | 6-0 6-0 | 3 | 45 | 2 | 2 | 39.0% | 68.8% | 68.0% | 5/5 |
| R32 | 16 | Tommy RobredoClay | 202 |  Gustavo KuertenClay | 6-4 6-4 | 3 | 89 | 3 | 5 | 59.0% | 72.2% | 40.0% | 4/7 |
| R32 | 28 | Juan Carlos FerreroClay | 56 |  Jarkko NieminenClay | 6-0 3-1 RET | 3 | 40 | 1 | 2 | 69.7% | 82.6% | 30.0% | 0/0 |
| R32 | 97 | Novak DjokovicClay | 163 | Alex CalatravaClay | 6-1 6-4 | 3 | 63 | 1 | 0 | 69.2% | 72.2% | 81.3% | 4/4 |
| R32 | 88 | Felix MantillaClay | 233 |  Alan MackinClay | 6-2 6-1 | 3 | 59 | 2 | 0 | 53.3% | 66.7% | 57.1% | 2/4 |
| R32 | 15 |  Guillermo CoriaClay | 681 | Zeljko KrajanClay | 5-7 6-3 6-4 | 3 | 159 | 8 | 10 | 50.0% | 76.1% | 30.4% | 3/9 |
| R16 | 129 | Lukas DlouhyClay | 388 | Ilija BozoljacClay | 6-3 6-2 | 3 | 56 | 2 | 3 | 65.9% | 77.8% | 50.0% | 1/3 |
| R16 | 24 | Jiri NovakClay | 133 | Albert PortasClay | 6-0 4-6 7-5 | 3 | 113 | 7 | 3 | 62.8% | 79.6% | 43.8% | 6/9 |
| R16 | 21 | David FerrerClay | 126 | Fernando VicenteClay | 6-2 6-3 | 3 | 79 | 1 | 1 | 75.4% | 76.7% | 64.3% | 3/3 |
| R16 | 29 | Carlos MoyaClay | 127 | Kristof VliegenClay | 6-3 6-1 | 3 | 68 | 1 | 2 | 53.2% | 76.0% | 59.1% | 2/3 |
| R16 | 37 | Filippo VolandriClay | 86 | Guillermo Garcia-LopezClay | 6-1 6-1 | 3 | 66 | 1 | 2 | 57.5% | 69.6% | 47.1% | 3/5 |
| R16 | 16 | Tommy RobredoClay | 92 | Janko TipsarevicClay | 6-3 6-1 | 3 | 68 | 2 | 1 | 37.8% | 76.5% | 71.4% | 3/3 |
| R16 | 15 | Guillermo CoriaClay | 88 | Felix MantillaClay | 3-6 6-2 6-1 | 3 | 128 | 3 | 3 | 68.8% | 67.3% | 60.0% | 4/6 |
| QF | 24 | Jiri NovakClay | 129 | Lukas DlouhyClay | 6-0 6-3 | 3 | 54 | 2 | 0 | 76.4% | 71.4% | 46.2% | 2/3 |
| QF | 29 | Carlos MoyaClay | 21 | David FerrerClay | 6-4 0-6 6-3 | 3 | 111 | 3 | 5 | 48.4% | 70.5% | 42.6% | 7/11 |
| QF | 37 | Filippo VolandriClay | 16 | Tommy RobredoClay | 3-6 6-3 6-3 | 3 | 117 | 0 | 3 | 78.5% | 62.9% | 41.2% | 5/9 |
| QF | 15 | Guillermo CoriaClay | 28 | Juan Carlos FerreroClay | 6-3 6-0 | 3 | 86 | 3 | 2 | 60.9% | 78.6% | 55.6% | 1/1 |
| SF | 29 | Carlos MoyaClay | 24 | Jiri NovakClay | 6-4 6-4 | 3 | 87 | 3 | 4 | 61.2% | 65.9% | 50.0% | 3/5 |
| SF | 15 | Guillermo CoriaClay | 37 | Filippo VolandriClay | 4-6 6-3 6-2 | 3 | 118 | 4 | 4 | 54.1% | 65.2% | 66.7% | 10/12 |
| F | 15 | Guillermo CoriaClay | 29 | Carlos MoyaClay | 6-2 4-6 6-2 | 3 | 130 | 0 | 9 | 61.4% | 68.5% | 55.9% | 4/6 |
