| QF | 65 |  Filippo VolandriClay | 109 |  Kristof VliegenClay | 6-2 6-2 | 3 | 67 | 0 | 3 | 66.7% | 63.9% | 50.0% | 6/8 |
| R32 | 4 |  Carlos MoyaClay | 147 |  Roko KaranusicClay | 6-4 6-4 | 3 | 75 | 1 | 2 | 56.5% | 82.9% | 59.3% | 5/5 |
| R32 | 453 | Zeljko KrajanClay | 160 |  Jiri VanekClay | 6-0 3-6 6-3 | 3 | 119 | 1 | 3 | 52.8% | 70.2% | 38.1% | 9/13 |
| R32 | 130 | Nicolas AlmagroClay | 139 |  Tomas BehrendClay | 7-6(4) 6-4 | 3 | 87 | 2 | 1 | 67.7% | 85.7% | 55.0% | 1/2 |
| R32 | 61 | Alberto MartinClay | 351 |  Jerome GolmardClay | 6-2 4-6 6-2 | 3 | 111 | 3 | 6 | 62.3% | 81.4% | 50.0% | 1/3 |
| R32 | 65 | Filippo VolandriClay | 368 |  Novak DjokovicClay | 7-6(5) 6-1 | 3 | 90 | 0 | 7 | 52.7% | 56.4% | 51.4% | 6/10 |
| R32 | 223 | Florent SerraClay | 118 | Bohdan UlihrachClay | 6-3 6-1 | 3 | 59 | 0 | 0 | 76.6% | 75.0% | 45.5% | 1/2 |
| R32 | 109 | Kristof VliegenClay | 95 | Olivier MutisClay | 6-0 6-2 | 3 | 42 | 4 | 2 | 56.3% | 94.4% | 78.6% | 0/0 |
| R32 | 100 | Olivier RochusClay | 81 |  Karol KuceraClay | 6-2 6-2 | 3 | 63 | 0 | 2 | 64.0% | 65.6% | 61.1% | 4/6 |
| R32 | 42 |  Guillermo CanasClay | 87 | Olivier PatienceClay | 6-3 6-2 | 3 | 76 | 3 | 1 | 51.3% | 75.0% | 73.7% | 0/1 |
| R32 | 197 | Fernando VicenteClay | 266 | Sasa TuksarClay | 6-7(5) 6-4 6-3 | 3 | 130 | 6 | 1 | 62.9% | 73.8% | 52.8% | 2/5 |
| R32 | 99 | Alex CalatravaClay | 314 | Arnaud Di PasqualeClay | 6-4 6-3 | 3 | 90 | 3 | 3 | 67.2% | 60.0% | 54.5% | 5/7 |
| R32 | 143 | Tomas ZibClay | 55 |  Igor AndreevClay | 6-3 6-4 | 3 | 65 | 2 | 1 | 50.0% | 95.8% | 62.5% | 1/2 |
| R32 | 78 |  Flavio SarettaClay | 153 |  Stan WawrinkaClay | 6-3 6-1 | 3 | 63 | 2 | 0 | 69.8% | 76.7% | 69.2% | 0/0 |
| R32 | 138 | Guillermo Garcia-LopezClay | 85 |  Victor HanescuClay | 5-7 6-4 6-4 | 3 | 140 | 1 | 2 | 62.2% | 75.4% | 48.6% | 2/5 |
| R32 | 125 | Christophe RochusClay | 93 | Jose AcasusoClay | 6-3 7-5 | 3 | 92 | 2 | 1 | 73.7% | 64.3% | 65.0% | 8/10 |
| R32 | 23 | Jiri NovakClay | 108 | Ruben Ramirez HidalgoClay | 6-4 6-2 | 3 | 79 | 11 | 2 | 64.6% | 87.1% | 58.8% | 0/0 |
| R16 | 4 | Carlos MoyaClay | 453 | Zeljko KrajanClay | 3-3 RET | 3 | 26 | 0 | 1 | 62.5% | 50.0% | 66.7% | 0/1 |
| R16 | 61 | Alberto MartinClay | 130 | Nicolas AlmagroClay | 6-3 6-1 | 3 | 76 | 1 | 5 | 52.7% | 86.2% | 50.0% | 3/3 |
| R16 | 65 | Filippo VolandriClay | 223 | Florent SerraClay | 7-5 6-0 | 3 | 77 | 1 | 1 | 59.3% | 71.9% | 59.1% | 2/3 |
| R16 | 109 | Kristof VliegenClay | 100 | Olivier RochusClay | 7-6(3) 3-6 6-4 | 3 | 165 | 12 | 3 | 54.0% | 66.7% | 47.8% | 5/10 |
| R16 | 42 | Guillermo CanasClay | 197 | Fernando VicenteClay | 6-2 6-1 | 3 | 59 | 1 | 1 | 63.6% | 71.4% | 83.3% | 0/1 |
| R16 | 99 | Alex CalatravaClay | 143 | Tomas ZibClay | 7-5 6-3 | 3 | 110 | 5 | 2 | 59.1% | 66.7% | 55.6% | 6/9 |
| R16 | 138 | Guillermo Garcia-LopezClay | 78 | Flavio SarettaClay | 7-5 6-0 | 3 | 92 | 0 | 2 | 50.0% | 60.9% | 47.8% | 3/7 |
| R16 | 23 | Jiri NovakClay | 125 | Christophe RochusClay | 4-6 6-3 6-1 | 3 | 115 | 7 | 1 | 60.8% | 62.5% | 61.3% | 3/6 |
| QF | 4 | Carlos MoyaClay | 61 | Alberto MartinClay | 6-1 7-6(2) | 3 | 87 | 3 | 4 | 51.4% | 83.8% | 45.7% | 6/7 |
| QF | 42 | Guillermo CanasClay | 99 | Alex CalatravaClay | 6-2 7-6(4) | 3 | 105 | 8 | 0 | 63.2% | 69.4% | 71.4% | 1/3 |
| QF | 138 | Guillermo Garcia-LopezClay | 23 | Jiri NovakClay | 6-3 6-3 | 3 | 66 | 1 | 2 | 61.0% | 63.9% | 73.9% | 0/0 |
| SF | 65 | Filippo VolandriClay | 4 | Carlos MoyaClay | 6-3 6-2 | 3 | 69 | 0 | 1 | 64.2% | 82.4% | 57.9% | 1/1 |
| SF | 42 | Guillermo CanasClay | 138 | Guillermo Garcia-LopezClay | 6-2 6-2 | 3 | 76 | 3 | 0 | 63.0% | 72.4% | 64.7% | 1/2 |
| F | 42 | Guillermo CanasClay | 65 | Filippo VolandriClay | 7-5 6-3 | 3 | 98 | 1 | 5 | 56.5% | 71.4% | 44.4% | 4/7 |
