| R16 | 20 |  Carlos MoyaClay | 131 | Emilio Benfele AlvarezClay | 6-4 5-7 6-1 | 3 | 134 | 5 | 7 | 65.2% | 81.7% | 37.5% | 2/4 |
| R16 | 156 |  Attila SavoltClay | 88 |  Agustin CalleriClay | 3-6 2-3 RET | 3 | 68 | 1 | 1 | 60.0% | 74.1% | 44.4% | 4/6 |
| R16 | 111 | David NalbandianClay | 38 |  Bohdan UlihrachClay | 6-2 6-1 | 3 | 52 | 2 | 1 | 64.3% | 70.4% | 53.3% | 2/3 |
| R16 | 82 | Felix MantillaClay | 170 | Oscar SerranoClay | 6-2 6-2 | 3 | 72 | 4 | 4 | 52.7% | 72.4% | 53.8% | 2/3 |
| R16 | 60 |  Jerome GolmardClay | 136 |  Luis HornaClay | 2-2 RET | 3 | 19 | 2 | 0 | 70.0% | 100.0% | 33.3% | 0/0 |
| R16 | 108 | Albert MontanesClay | 48 | Michal TabaraClay | 6-2 6-0 | 3 | 55 | 0 | 2 | 57.8% | 69.2% | 68.4% | 1/1 |
| R16 | 76 |  Ivan LjubicicClay | 115 |  Federico LuzziClay | 6-2 7-6(2) | 3 | 101 | 2 | 1 | 78.6% | 68.2% | 66.7% | 1/1 |
| R16 | 107 |  Adrian VoineaClay | 26 | Albert PortasClay | 7-6(1) 0-6 6-4 | 3 | 117 | 5 | 5 | 51.1% | 72.9% | 37.0% | 9/15 |
| QF | 20 | Carlos MoyaClay | 156 | Attila SavoltClay | 6-4 6-4 | 3 | 84 | 0 | 0 | 67.2% | 76.7% | 28.6% | 4/6 |
| QF | 111 | David NalbandianClay | 82 | Felix MantillaClay | 6-2 6-3 | 3 | 75 | 2 | 0 | 78.0% | 59.0% | 54.5% | 3/5 |
| QF | 60 | Jerome GolmardClay | 108 | Albert MontanesClay | 7-5 7-5 | 3 | 122 | 1 | 2 | 62.9% | 75.0% | 51.5% | 9/9 |
| QF | 107 | Adrian VoineaClay | 76 | Ivan LjubicicClay | 7-6(6) 4-6 6-3 | 3 | 140 | 11 | 4 | 44.9% | 84.1% | 55.6% | 7/9 |
| SF | 20 | Carlos MoyaClay | 111 | David NalbandianClay | 6-4 7-5 | 3 | 79 | 5 | 2 | 66.1% | 73.2% | 42.9% | 0/3 |
| SF | 60 | Jerome GolmardClay | 107 | Adrian VoineaClay | 7-5 6-3 | 3 | 93 | 4 | 1 | 74.6% | 67.9% | 61.1% | 2/3 |
| F | 20 | Carlos MoyaClay | 60 | Jerome GolmardClay | 6-4 3-6 7-6(2) | 3 | 162 | 11 | 2 | 71.6% | 67.9% | 48.4% | 9/12 |
| R32 | 20 | Carlos MoyaClay | 93 | Jiri VanekClay | 5-7 6-4 6-3 | 3 | 112 | 8 | 2 | 56.4% | 81.8% | 61.8% | 0/2 |
| R32 | 131 | Emilio Benfele AlvarezClay | 143 | Tomas ZibClay | 6-1 6-2 | 3 | 60 | 2 | 2 | 61.5% | 83.3% | 53.3% | 0/1 |
| R32 | 156 | Attila SavoltClay | 305 | SLOMarko TkalecClay | 4-6 7-6(7) 6-3 | 3 | 134 | 11 | 2 | 58.7% | 68.9% | 44.2% | 2/7 |
| R32 | 88 | Agustin CalleriClay | 124 | Mariano PuertaClay | 4-6 7-6(5) 6-0 | 3 | 124 | 19 | 5 | 61.5% | 81.3% | 37.5% | 9/12 |
| R32 | 38 | Bohdan UlihrachClay | 125 |  Tomas BehrendClay | 6-4 6-3 | 3 | 72 | 2 | 3 | 53.2% | 60.6% | 58.6% | 5/7 |
| R32 | 111 | David NalbandianClay | 384 | Ion MoldovanClay | 3-6 6-1 6-1 | 3 | 82 | 3 | 5 | 63.6% | 75.5% | 53.6% | 7/9 |
| R32 | 170 | Oscar SerranoClay | 496 | SLOIztok BozicClay | 6-3 6-7(10) 6-3 | 3 | 138 | 3 | 6 | 57.6% | 75.0% | 44.0% | 5/8 |
| R32 | 82 | Felix MantillaClay | 147 | Markus HantschkClay | 7-6(3) 6-2 | 3 | 85 | 6 | 1 | 55.0% | 90.9% | 55.6% | 1/1 |
| R32 | 60 | Jerome GolmardClay | 119 |  George BastlClay | 6-3 6-3 | 3 | 77 | 5 | 3 | 48.0% | 79.2% | 46.2% | 0/2 |
| R32 | 136 | Luis HornaClay | 194 | Martin DammClay | 6-2 6-3 | 3 | 64 | 3 | 2 | 66.7% | 72.2% | 55.6% | 1/3 |
| R32 | 108 | Albert MontanesClay | 177 | Giorgio GalimbertiClay | 6-3 3-6 6-1 | 3 | 122 | 9 | 7 | 59.8% | 67.3% | 42.9% | 6/10 |
| R32 | 48 | Michal TabaraClay | 345 | Marzio MartelliClay | 6-4 6-4 | 3 | 90 | 8 | 7 | 52.4% | 64.8% | 55.1% | 10/11 |
| R32 | 76 | Ivan LjubicicClay | 623 | Federico BrowneClay | 7-6(8) 6-2 | 3 | 87 | 4 | 4 | 54.1% | 87.9% | 53.6% | 0/1 |
| R32 | 115 | Federico LuzziClay | 239 | Ivan VajdaClay | 6-2 7-5 | 3 | 86 | 1 | 3 | 62.5% | 65.7% | 57.1% | 1/3 |
| R32 | 107 | Adrian VoineaClay | 99 | Slava DosedelClay | 6-1 6-4 | 3 | 64 | 6 | 0 | 52.9% | 77.8% | 58.3% | 1/2 |
| R32 | 26 | Albert PortasClay | 105 | German PuentesClay | 6-1 6-4 | 3 | 64 | 2 | 1 | 60.4% | 65.5% | 52.6% | 2/4 |
