| R32 | 14 |  Albert CostaClay | 123 |  Omar CamporeseClay | 6-2 7-5 | 3 | 73 | 4 | 3 | 79.4% | 68.0% | 38.5% | 1/3 |
| R32 | 119 |  Oleg OgorodovClay | 136 |  Sandor NoszalyClay | 6-1 6-4 | 3 | 65 | 5 | 3 | 58.6% | 76.5% | 54.2% | 3/4 |
| R32 | 449 |  Stefan KoubekClay | 127 |  Frederik FetterleinClay | 4-6 6-3 6-3 | 3 | 97 | 1 | 3 | 69.7% | 62.9% | 40.7% | 9/14 |
| R32 | 48 |  Slava DosedelClay | 396 |  Goran OresicClay | 6-4 6-0 | 3 | 65 | 0 | 1 | 80.4% | 75.7% | 66.7% | 1/1 |
| R32 | 19 | Felix MantillaClay | 71 | Roberto CarreteroClay | 7-6(2) 6-3 | 3 | 80 | 3 | 0 | 82.5% | 85.1% | 50.0% | 0/0 |
| R32 | 130 |  Mariano ZabaletaClay | 312 | Petr PalaClay | 6-3 6-1 | 3 | 73 | 0 | 2 | 77.8% | 73.8% | 33.3% | 2/3 |
| R32 | 52 | Gilbert SchallerClay | 132 |  Joao Cunha-SilvaClay | 7-6(2) 6-0 | 3 | 99 | 2 | 1 | 67.3% | 80.0% | 52.9% | 1/2 |
| R32 | 38 | Carlos CostaClay | 363 |  Andrei RybalkoClay | 6-1 6-4 | 3 | 72 | 0 | 0 | 53.5% | 60.9% | 45.0% | 0/3 |
| R32 | 124 | Marcos Aurelio GorrizClay | 40 | Hernan GumyClay | 3-6 7-5 6-1 | 3 | - | 4 | 3 | 59.8% | 61.5% | 54.3% | 3/7 |
| R32 | 98 | David RiklClay | 1272 | Goran PrpicClay | 6-4 6-4 | 3 | 75 | 1 | 1 | 64.4% | 68.4% | 52.4% | 2/4 |
| R32 | 97 | Galo BlancoClay | 128 |  Luis Adrian MorejonClay | 6-7(2) 6-4 6-1 | 3 | 123 | 4 | 3 | 62.4% | 69.0% | 57.1% | 3/5 |
| R32 | 29 | Carlos MoyaClay | 63 | Javier SanchezClay | 6-1 7-6(8) | 3 | 80 | 1 | 2 | 58.8% | 77.5% | 46.4% | 6/7 |
| R32 | 53 | MARKarim AlamiClay | 104 |  Fernando MeligeniClay | 6-4 7-6(4) | 3 | 89 | 3 | 3 | 58.9% | 74.4% | 56.7% | 1/2 |
| R32 | 68 |  Christian RuudClay | 107 |  Jerome GolmardClay | 6-1 7-5 | 3 | 78 | 2 | 3 | 71.2% | 78.4% | 26.7% | 2/4 |
| R32 | 969 | Ivan LjubicicClay | 61 | Tomas CarbonellClay | 6-3 RET | 3 | 33 | 0 | 1 | 46.2% | 91.7% | 64.3% | 0/0 |
| R32 | 115 | Gustavo KuertenClay | 21 | Alberto BerasateguiClay | 6-3 6-4 | 3 | 61 | 4 | 1 | 71.2% | 81.1% | 53.3% | 0/1 |
| R16 | 14 | Albert CostaClay | 119 | Oleg OgorodovClay | 7-6(5) 6-1 | 3 | 78 | 1 | 2 | 67.2% | 67.4% | 81.0% | 0/1 |
| R16 | 48 | Slava DosedelClay | 449 | Stefan KoubekClay | 6-0 6-2 | 3 | 45 | 0 | 1 | 88.1% | 64.9% | 40.0% | 2/4 |
| R16 | 19 | Felix MantillaClay | 130 | Mariano ZabaletaClay | 6-3 6-3 | 3 | 90 | 0 | 1 | 62.1% | 61.0% | 52.0% | 5/7 |
| R16 | 52 | Gilbert SchallerClay | 38 | Carlos CostaClay | 4-6 6-2 6-0 | 3 | 108 | 6 | 0 | 68.1% | 68.1% | 54.5% | 3/6 |
| R16 | 124 | Marcos Aurelio GorrizClay | 98 | David RiklClay | 6-3 6-1 | 3 | 64 | 2 | 1 | 68.8% | 75.8% | 46.7% | 2/3 |
| R16 | 29 | Carlos MoyaClay | 97 | Galo BlancoClay | 6-3 6-2 | 3 | 55 | 1 | 1 | 65.9% | 69.0% | 53.3% | 1/3 |
| R16 | 68 | Christian RuudClay | 53 | MARKarim AlamiClay | 6-3 6-3 | 3 | 81 | 1 | 2 | 72.9% | 60.5% | 56.3% | 2/4 |
| R16 | 115 | Gustavo KuertenClay | 969 | Ivan LjubicicClay | 6-2 6-1 | 3 | 52 | 0 | 2 | 57.4% | 70.4% | 45.0% | 1/3 |
| QF | 48 | Slava DosedelClay | 14 | Albert CostaClay | 6-3 6-4 | 3 | 74 | 2 | 1 | 79.0% | 59.2% | 61.5% | 2/5 |
| QF | 19 | Felix MantillaClay | 52 | Gilbert SchallerClay | 6-3 7-6(4) | 3 | 99 | 0 | 2 | 69.0% | 56.9% | 50.0% | 6/10 |
| QF | 29 | Carlos MoyaClay | 124 | Marcos Aurelio GorrizClay | 6-2 6-1 | 3 | 70 | 0 | 0 | 61.1% | 69.7% | 61.9% | 2/2 |
| QF | 68 | Christian RuudClay | 115 | Gustavo KuertenClay | 7-5 6-4 | 3 | 91 | 1 | 3 | 69.0% | 65.3% | 54.5% | 1/3 |
| SF | 19 | Felix MantillaClay | 48 | Slava DosedelClay | 4-2 RET | 3 | 23 | 1 | 0 | 65.0% | 69.2% | 42.9% | 2/3 |
| SF | 29 | Carlos MoyaClay | 68 | Christian RuudClay | 6-1 6-2 | 3 | 54 | 2 | 0 | 75.6% | 79.4% | 81.8% | 4/4 |
| F | 29 | Carlos MoyaClay | 19 | Felix MantillaClay | 6-0 7-6(4) | 3 | 76 | 1 | 2 | 71.2% | 67.6% | 60.0% | 0/3 |
