| R32 | 61 |  Andrey GolubevClay | 508 |  Philipp PetzschnerClay | 6-4 6-1 | 3 | 80 | 6 | 4 | 47.6% | 76.7% | 51.5% | 3/4 |
| R32 | 38 |  Federico DelbonisClay | 87 | Juan MonacoClay | 6-4 6-1 | 3 | 80 | 3 | 7 | 55.4% | 75.6% | 51.5% | 7/8 |
| R32 | 60 | Benjamin BeckerClay | 79 |  Benoit PaireClay | 3-6 6-2 6-2 | 3 | 84 | 11 | 6 | 56.3% | 81.6% | 47.4% | 5/6 |
| R32 | 47 | Leonardo MayerClay | 127 | Michael BerrerClay | 2-6 6-3 7-6(5) | 3 | 130 | 7 | 7 | 54.4% | 79.6% | 58.5% | 1/3 |
| R32 | 658 |  Philipp DavydenkoClay | 81 | SLOBlaz RolaClay | 6-4 7-6(8) | 3 | 100 | 2 | 2 | 74.4% | 72.1% | 42.9% | 2/3 |
| R32 | 34 |  Santiago GiraldoClay | 189 |  Mate DelicClay | 6-4 6-2 | 3 | 62 | 2 | 1 | 67.3% | 74.3% | 64.7% | 1/2 |
| R32 | 236 |  Louk SorensenClay | 68 |  Igor SijslingClay | 6-4 6-1 | 3 | 50 | 9 | 1 | 68.9% | 87.1% | 50.0% | 1/2 |
| R32 | 232 |  Yann MartiClay | 259 | Henri LaaksonenClay | 7-5 6-4 | 3 | 92 | 3 | 3 | 56.2% | 68.3% | 43.8% | 5/8 |
| R32 | 32 |  Guillermo Garcia-LopezClay | 140 |  Marco CecchinatoClay | 6-4 1-6 7-5 | 3 | 122 | 2 | 4 | 69.3% | 67.2% | 48.1% | 6/10 |
| R32 | 26 | Philipp KohlschreiberClay | 71 | Jan-Lennard StruffClay | 6-4 6-3 | 3 | 74 | 2 | 1 | 57.8% | 64.9% | 59.3% | 4/5 |
| R32 | 48 |  Lukas RosolClay | 285 | Alexander ZverevClay | 7-6(7) 7-6(9) | 3 | 103 | 5 | 1 | 62.8% | 79.6% | 50.0% | 1/3 |
| R32 | 94 | Daniel Gimeno-TraverClay | 114 | Peter GojowczykClay | 7-5 6-3 | 3 | 79 | 6 | 1 | 45.6% | 73.1% | 71.0% | 0/1 |
| R16 | 15 | Fabio FogniniClay | 61 | Andrey GolubevClay | 6-4 6-4 | 3 | 79 | 0 | 4 | 60.6% | 75.0% | 57.7% | 2/2 |
| R16 | 34 | Santiago GiraldoClay | 658 | Philipp DavydenkoClay | 6-1 6-7(5) 6-3 | 3 | 116 | 2 | 1 | 76.1% | 79.1% | 57.1% | 2/4 |
| R16 | 23 | Roberto Bautista AgutClay | 236 | Louk SorensenClay | 6-3 1-6 6-1 | 3 | 96 | 1 | 3 | 72.1% | 81.8% | 47.1% | 0/2 |
| R16 | 32 | Guillermo Garcia-LopezClay | 232 | Yann MartiClay | 7-6(13) 7-5 | 3 | 125 | 9 | 2 | 63.7% | 69.0% | 45.5% | 7/10 |
| R16 | 48 | Lukas RosolClay | 26 | Philipp KohlschreiberClay | 7-5 7-6(5) | 3 | 81 | 7 | 3 | 61.6% | 84.4% | 50.0% | 0/1 |
| R16 | 24 | Feliciano LopezClay | 94 | Daniel Gimeno-TraverClay | 6-7(3) 6-2 6-3 | 3 | 107 | 7 | 1 | 64.1% | 72.0% | 78.6% | 0/1 |
| R16 | 38 | Federico DelbonisClay | 60 | Benjamin BeckerClay | 6-7(6) 6-4 6-4 | 3 | 133 | 3 | 1 | 63.4% | 74.6% | 63.4% | 1/1 |
| R16 | 22 | Mikhail YouzhnyClay | 47 | Leonardo MayerClay | 6-1 6-1 | 3 | 69 | 0 | 4 | 64.9% | 78.4% | 35.0% | 6/6 |
| QF | 15 | Fabio FogniniClay | 34 | Santiago GiraldoClay | 6-4 6-3 | 3 | 81 | 2 | 3 | 55.7% | 73.5% | 66.7% | 1/1 |
| QF | 23 | Roberto Bautista AgutClay | 32 | Guillermo Garcia-LopezClay | 3-6 6-4 7-6(1) | 3 | 158 | 3 | 4 | 66.7% | 63.6% | 66.7% | 1/5 |
| QF | 48 | Lukas RosolClay | 24 | Feliciano LopezClay | 4-6 6-3 7-6(4) | 3 | 115 | 11 | 2 | 51.4% | 82.1% | 50.9% | 6/8 |
| QF | 22 | Mikhail YouzhnyClay | 38 | Federico DelbonisClay | 7-6(2) 6-2 | 3 | 101 | 4 | 2 | 66.7% | 77.3% | 68.2% | 3/3 |
| SF | 23 | Roberto Bautista AgutClay | 15 | Fabio FogniniClay | 6-3 6-4 | 3 | 74 | 2 | 1 | 68.4% | 82.1% | 55.6% | 5/5 |
| SF | 48 | Lukas RosolClay | 22 | Mikhail YouzhnyClay | 7-6(3) 6-2 | 3 | 89 | 10 | 4 | 52.8% | 76.3% | 50.0% | 3/5 |
| F | 23 | Roberto Bautista AgutClay | 48 | Lukas RosolClay | 6-3 4-6 6-2 | 3 | 102 | 2 | 1 | 70.4% | 73.7% | 62.5% | 5/6 |
