| R32 | 36 |  Ernests GulbisClay | 41 |  Marcel GranollersClay | 4-6 6-1 6-1 | 3 | 94 | 4 | 5 | 56.7% | 78.9% | 55.2% | 4/6 |
| R32 | 46 |  Florian MayerClay | 372 | Andreas BeckClay | 6-4 3-6 6-1 | 3 | 105 | 8 | 3 | 67.9% | 77.4% | 44.0% | 1/3 |
| R32 | 60 |  Gael MonfilsClay | 79 | Paul-Henri MathieuClay | 7-6(0) 6-4 | 3 | 101 | 16 | 2 | 64.9% | 72.9% | 73.1% | 6/6 |
| R32 | 309 | Nils LangerClay | 392 | Robin KernClay | 3-6 6-4 6-3 | 3 | 86 | 1 | 5 | 65.8% | 75.0% | 55.6% | 0/2 |
| R32 | 81 |  Leonardo MayerClay | 49 | Pablo AndujarClay | 3-6 7-6(5) 7-6(5) | 3 | 176 | 12 | 7 | 62.6% | 75.3% | 43.5% | 12/15 |
| R32 | 31 |  Fabio FogniniClay | 382 |  Alexander WardClay | 6-3 7-6(5) | 3 | 81 | 6 | 2 | 67.2% | 73.3% | 63.6% | 0/1 |
| R32 | 153 | Michael BerrerClay | 57 | Daniel Gimeno-TraverClay | 6-4 3-6 6-1 | 3 | 105 | 3 | 4 | 66.7% | 66.1% | 60.7% | 6/8 |
| R32 | 58 | Roberto Bautista AgutClay | 78 | Tobias KamkeClay | 6-3 7-6(4) | 3 | 93 | 1 | 1 | 62.5% | 65.0% | 70.8% | 2/4 |
| R32 | 38 |  Martin KlizanClay | 50 | Albert MontanesClay | 6-2 6-3 | 3 | 77 | 7 | 3 | 45.3% | 83.3% | 62.1% | 4/4 |
| R32 | 56 |  Thomaz BellucciClay | 40 |  Lukas RosolClay | 6-4 6-4 | 3 | 75 | 4 | 5 | 57.6% | 84.2% | 53.6% | 6/6 |
| R32 | 51 |  Victor HanescuClay | 67 |  Dmitry TursunovClay | 3-6 6-3 7-6(7) | 3 | 145 | 8 | 0 | 68.3% | 67.6% | 42.4% | 6/10 |
| R32 | 43 | Nikolay DavydenkoClay | 149 | Daniel Munoz de la NavaClay | 6-7(6) 6-3 6-4 | 3 | 145 | 3 | 6 | 61.8% | 74.6% | 46.2% | 5/8 |
| R16 | 11 | Tommy HaasClay | 36 | Ernests GulbisClay | 6-0 3-6 6-4 | 3 | 91 | 6 | 2 | 59.7% | 80.0% | 59.3% | 3/4 |
| R16 | 31 | Fabio FogniniClay | 81 | Leonardo MayerClay | 6-1 6-3 | 3 | 67 | 4 | 2 | 66.0% | 77.1% | 33.3% | 5/7 |
| R16 | 153 | Michael BerrerClay | 26 | Jeremy ChardyClay | 6-2 6-7(1) 6-3 | 3 | 138 | 7 | 4 | 67.0% | 79.4% | 51.6% | 4/4 |
| R16 | 58 | Roberto Bautista AgutClay | 38 | Martin KlizanClay | 6-7(3) 6-1 6-4 | 3 | 148 | 6 | 3 | 71.4% | 74.3% | 50.0% | 6/7 |
| R16 | 51 | Victor HanescuClay | 56 | Thomaz BellucciClay | 6-1 6-4 | 3 | 69 | 2 | 0 | 75.0% | 68.9% | 66.7% | 2/2 |
| R16 | 27 | Benoit PaireClay | 43 | Nikolay DavydenkoClay | 6-3 6-1 | 3 | 64 | 7 | 4 | 51.5% | 79.4% | 53.1% | 3/3 |
| R16 | 60 | Gael MonfilsClay | 46 | Florian MayerClay | 6-3 6-0 | 3 | 55 | 4 | 2 | 51.3% | 70.0% | 57.9% | 1/2 |
| R16 | 25 | Philipp KohlschreiberClay | 309 | Nils LangerClay | 7-5 6-2 | 3 | 74 | 4 | 2 | 57.8% | 73.0% | 59.3% | 5/6 |
| QF | 31 | Fabio FogniniClay | 11 | Tommy HaasClay | 6-2 6-4 | 3 | 74 | 0 | 1 | 50.0% | 64.3% | 78.6% | 5/5 |
| QF | 58 | Roberto Bautista AgutClay | 153 | Michael BerrerClay | 6-2 0-1 RET | 3 | 40 | 0 | 0 | 80.6% | 56.0% | 66.7% | 2/4 |
| QF | 51 | Victor HanescuClay | 27 | Benoit PaireClay | 7-5 6-2 | 3 | 72 | 5 | 1 | 72.4% | 76.2% | 62.5% | 1/1 |
| QF | 25 | Philipp KohlschreiberClay | 60 | Gael MonfilsClay | 6-4 6-4 | 3 | 71 | 3 | 0 | 58.9% | 69.7% | 60.9% | 3/5 |
| SF | 31 | Fabio FogniniClay | 58 | Roberto Bautista AgutClay | 6-1 6-3 | 3 | 56 | 1 | 4 | 52.4% | 68.2% | 55.0% | 0/2 |
| SF | 25 | Philipp KohlschreiberClay | 51 | Victor HanescuClay | 6-3 6-3 | 3 | 81 | 2 | 2 | 64.3% | 75.0% | 50.0% | 4/5 |
| F | 31 | Fabio FogniniClay | 25 | Philipp KohlschreiberClay | 5-7 6-4 6-4 | 3 | 127 | 3 | 4 | 62.8% | 78.0% | 34.3% | 1/5 |
