| R32 | 75 |  Steve DarcisClay | 86 |  Albert MontanesClay | 6-2 6-4 | 3 | 69 | 5 | 1 | 52.7% | 69.0% | 69.2% | 2/3 |
| R32 | 52 |  Tommy HaasClay | 89 |  Igor AndreevClay | 4-6 6-2 6-2 | 3 | 97 | 8 | 5 | 42.9% | 86.7% | 60.0% | 0/1 |
| R32 | 206 |  Pavol CervenakClay | 92 |  Sergiy StakhovskyClay | 6-1 4-6 6-1 | 3 | 110 | 1 | 3 | 63.2% | 66.7% | 53.6% | 5/7 |
| R32 | 98 | Tobias KamkeClay | 93 |  Flavio CipollaClay | 6-3 6-4 | 3 | 82 | 0 | 7 | 56.9% | 78.8% | 48.0% | 4/5 |
| R32 | 81 | Bjorn PhauClay | 246 |  Martin FischerClay | 6-3 6-3 | 3 | 89 | 1 | 1 | 50.0% | 73.3% | 53.3% | 3/4 |
| R32 | 103 |  Lukas RosolClay | 42 |  Robin HaaseClay | 6-4 7-5 | 3 | 78 | 12 | 1 | 53.8% | 91.4% | 56.7% | 4/4 |
| R32 | 64 |  Thomaz BellucciClay | 658 | Robin KernClay | 7-6(3) 6-2 | 3 | 87 | 5 | 3 | 54.7% | 68.6% | 62.1% | 3/5 |
| R32 | 51 |  Jeremy ChardyClay | 538 | Julian ReisterClay | 6-2 6-4 | 3 | 79 | 6 | 1 | 59.3% | 82.9% | 50.0% | 0/0 |
| R32 | 82 | Cedrik-Marcel StebeClay | 68 |  Lukasz KubotClay | 6-2 0-6 6-3 | 3 | 102 | 4 | 2 | 65.7% | 67.4% | 45.8% | 4/7 |
| R32 | 150 |  Dustin BrownClay | 44 | Nikolay DavydenkoClay | 7-5 3-6 7-6(7) | 3 | 124 | 13 | 9 | 54.6% | 76.9% | 42.6% | 7/11 |
| R32 | 47 | Benoit PaireClay | 139 |  Eduardo SchwankClay | 7-6(5) 6-4 | 3 | 98 | 7 | 10 | 54.8% | 82.5% | 39.4% | 3/6 |
| R32 | 87 | Guillermo Garcia-LopezClay | 83 | Ruben Ramirez HidalgoClay | 6-2 6-3 | 3 | 90 | 7 | 3 | 55.8% | 75.9% | 56.5% | 3/4 |
| R16 | 8 |  Janko TipsarevicClay | 75 | Steve DarcisClay | 6-4 6-2 | 3 | 79 | 5 | 3 | 63.3% | 78.9% | 45.5% | 3/4 |
| R16 | 81 | Bjorn PhauClay | 103 | Lukas RosolClay | 7-6(3) 7-6(2) | 3 | 123 | 7 | 3 | 49.0% | 80.9% | 57.1% | 5/6 |
| R16 | 64 | Thomaz BellucciClay | 45 |  Bernard TomicClay | 7-6(6) 6-3 | 3 | 108 | 9 | 3 | 57.3% | 72.3% | 51.4% | 8/10 |
| R16 | 82 | Cedrik-Marcel StebeClay | 51 | Jeremy ChardyClay | 4-6 7-6(8) 6-3 | 3 | 168 | 6 | 6 | 57.7% | 69.0% | 50.0% | 15/18 |
| R16 | 150 | Dustin BrownClay | 47 | Benoit PaireClay | 7-6(4) 4-6 6-1 | 3 | 98 | 19 | 3 | 53.2% | 77.6% | 52.9% | 9/11 |
| R16 | 87 | Guillermo Garcia-LopezClay | 35 | Pablo AndujarClay | 6-1 4-6 6-1 | 3 | 127 | 1 | 5 | 49.3% | 75.0% | 45.9% | 3/6 |
| R16 | 206 | Pavol CervenakClay | 52 | Tommy HaasClay | 6-4 6-4 | 3 | 93 | 2 | 2 | 63.5% | 63.8% | 59.3% | 8/9 |
| R16 | 14 | Juan MonacoClay | 98 | Tobias KamkeClay | 6-2 6-3 | 3 | 84 | 3 | 1 | 63.5% | 75.0% | 52.2% | 7/8 |
| QF | 8 | Janko TipsarevicClay | 81 | Bjorn PhauClay | 6-7(6) 7-6(2) 6-4 | 3 | 177 | 7 | 2 | 53.4% | 65.1% | 56.4% | 8/12 |
| QF | 64 | Thomaz BellucciClay | 82 | Cedrik-Marcel StebeClay | 6-4 6-1 | 3 | 70 | 1 | 2 | 52.1% | 68.0% | 65.2% | 0/1 |
| QF | 87 | Guillermo Garcia-LopezClay | 150 | Dustin BrownClay | 6-0 6-3 | 3 | 58 | 2 | 2 | 67.4% | 80.6% | 66.7% | 3/3 |
| QF | 14 | Juan MonacoClay | 206 | Pavol CervenakClay | 6-1 7-5 | 3 | 96 | 2 | 3 | 63.8% | 67.6% | 38.1% | 3/7 |
| SF | 8 | Janko TipsarevicClay | 64 | Thomaz BellucciClay | 6-4 2-6 6-4 | 3 | 123 | 3 | 5 | 49.4% | 76.2% | 46.5% | 4/7 |
| SF | 14 | Juan MonacoClay | 87 | Guillermo Garcia-LopezClay | 6-3 3-6 7-5 | 3 | 160 | 1 | 1 | 60.6% | 64.9% | 56.8% | 0/3 |
| F | 8 | Janko TipsarevicClay | 14 | Juan MonacoClay | 6-4 5-7 6-3 | 3 | 156 | 3 | 1 | 54.7% | 68.3% | 47.1% | 0/5 |
