| R32 | 64 |  Victor HanescuClay | 7 |  Gael MonfilsClay | 2-6 7-6(7) 6-4 | 3 | 137 | 2 | 2 | 57.6% | 63.2% | 57.1% | 1/5 |
| R32 | 287 |  Pavol CervenakClay | 104 |  Mischa ZverevClay | 6-4 4-6 6-2 | 3 | 121 | 4 | 4 | 54.1% | 73.9% | 48.7% | 4/7 |
| R32 | 45 |  Sergiy StakhovskyClay | 131 |  Jaroslav PospisilClay | 4-6 6-2 7-6(5) | 3 | 160 | 8 | 0 | 52.7% | 79.6% | 65.9% | 5/6 |
| R32 | 240 |  Federico DelbonisClay | 20 | Florian MayerClay | 6-2 6-3 | 3 | 70 | 2 | 5 | 50.0% | 88.9% | 55.6% | 5/5 |
| R32 | 17 |  Mikhail YouzhnyClay | 76 | Philipp PetzschnerClay | 6-3 6-3 | 3 | 71 | 4 | 3 | 63.5% | 81.8% | 52.6% | 1/2 |
| R32 | 85 |  Juan Carlos FerreroClay | 184 | Bastian KnittelClay | 6-2 6-4 | 3 | 82 | 3 | 4 | 48.1% | 73.1% | 60.7% | 5/7 |
| R32 | 126 | Benoit PaireClay | 154 | Evgeny DonskoyClay | 6-7(3) 6-4 6-2 | 3 | 127 | 8 | 5 | 50.8% | 75.0% | 50.0% | 12/14 |
| R32 | 52 | Marcel GranollersClay | 37 |  Andreas SeppiClay | 6-3 3-6 6-1 | 3 | 195 | 3 | 5 | 61.0% | 66.0% | 53.1% | 6/9 |
| R32 | 197 | Cedrik-Marcel StebeClay | 29 | Nikolay DavydenkoClay | 3-6 6-1 6-4 | 3 | 123 | 2 | 5 | 54.7% | 61.7% | 43.6% | 6/11 |
| R32 | 39 | Fabio FogniniClay | 1143 | Robin KernClay | 6-4 6-1 | 3 | 64 | 1 | 5 | 38.0% | 84.2% | 51.6% | 3/4 |
| R32 | 55 | Pablo AndujarClay | 195 | Victor CrivoiClay | 6-2 6-1 | 3 | 72 | 1 | 3 | 66.0% | 57.6% | 52.9% | 6/8 |
| R32 | 41 | Albert MontanesClay | 18 | Gilles SimonClay | 4-6 7-6(5) 6-2 | 3 | 119 | 4 | 10 | 51.6% | 68.8% | 51.1% | 8/13 |
| R32 | 38 | Guillermo Garcia-LopezClay | 57 | Radek StepanekClay | 6-1 6-3 | 3 | 76 | 3 | 4 | 53.7% | 75.9% | 52.0% | 4/4 |
| R32 | 69 |  Lukasz KubotClay | 60 | Daniel Gimeno-TraverClay | 7-6(2) 3-6 6-2 | 3 | 122 | 4 | 7 | 60.2% | 81.1% | 51.4% | 5/7 |
| R32 | 58 | Jeremy ChardyClay | 88 | Tobias KamkeClay | 7-6(1) 6-1 | 3 | 77 | 8 | 3 | 52.1% | 81.6% | 51.4% | 2/3 |
| R32 | 61 |  Santiago GiraldoClay | 12 |  Jurgen MelzerClay | 6-4 7-5 | 3 | 89 | 7 | 0 | 57.6% | 79.4% | 56.0% | 3/5 |
| R16 | 287 | Pavol CervenakClay | 64 | Victor HanescuClay | 6-3 7-6(6) | 3 | 88 | 4 | 4 | 61.6% | 73.3% | 53.6% | 4/6 |
| R16 | 240 | Federico DelbonisClay | 45 | Sergiy StakhovskyClay | 6-4 6-3 | 3 | 77 | 3 | 3 | 61.9% | 66.7% | 54.2% | 4/6 |
| R16 | 85 | Juan Carlos FerreroClay | 17 | Mikhail YouzhnyClay | 6-7(6) 6-2 6-2 | 3 | 136 | 5 | 0 | 61.7% | 72.4% | 61.1% | 3/5 |
| R16 | 52 | Marcel GranollersClay | 126 | Benoit PaireClay | 6-4 7-5 | 3 | 104 | 0 | 1 | 75.3% | 65.5% | 50.0% | 5/7 |
| R16 | 197 | Cedrik-Marcel StebeClay | 39 | Fabio FogniniClay | 7-6(5) 6-4 | 3 | 147 | 1 | 6 | 49.0% | 48.0% | 53.8% | 11/16 |
| R16 | 55 | Pablo AndujarClay | 41 | Albert MontanesClay | 2-6 6-4 6-3 | 3 | 129 | 3 | 4 | 49.4% | 69.0% | 46.5% | 6/10 |
| R16 | 69 | Lukasz KubotClay | 38 | Guillermo Garcia-LopezClay | 4-6 6-4 6-3 | 3 | 145 | 2 | 6 | 64.8% | 71.9% | 54.8% | 2/5 |
| R16 | 61 | Santiago GiraldoClay | 58 | Jeremy ChardyClay | 1-6 7-5 6-4 | 3 | 121 | 4 | 2 | 59.4% | 66.7% | 53.8% | 7/11 |
| QF | 240 | Federico DelbonisClay | 287 | Pavol CervenakClay | 6-1 6-2 | 3 | 71 | 2 | 1 | 50.0% | 68.0% | 72.0% | 1/1 |
| QF | 85 | Juan Carlos FerreroClay | 52 | Marcel GranollersClay | 6-4 6-3 | 3 | 88 | 1 | 3 | 56.7% | 58.8% | 57.7% | 5/8 |
| QF | 55 | Pablo AndujarClay | 197 | Cedrik-Marcel StebeClay | 6-2 6-1 | 3 | 67 | 0 | 2 | 65.9% | 72.4% | 53.3% | 2/3 |
| QF | 69 | Lukasz KubotClay | 61 | Santiago GiraldoClay | 7-5 5-7 6-3 | 3 | 148 | 4 | 4 | 59.6% | 62.9% | 59.5% | 6/9 |
| SF | 85 | Juan Carlos FerreroClay | 240 | Federico DelbonisClay | 3-6 6-4 6-4 | 3 | 125 | 1 | 1 | 57.3% | 60.0% | 65.9% | 9/11 |
| SF | 55 | Pablo AndujarClay | 69 | Lukasz KubotClay | 6-4 3-6 6-4 | 3 | 144 | 3 | 5 | 56.8% | 66.0% | 52.6% | 7/11 |
| F | 85 | Juan Carlos FerreroClay | 55 | Pablo AndujarClay | 6-4 6-0 | 3 | 79 | 3 | 0 | 55.6% | 76.0% | 55.0% | 0/1 |
