| R32 | 88 |  Daniel Gimeno-TraverClay | 50 |  Jeremy ChardyClay | 7-5 6-7(6) 6-3 | 3 | 155 | 18 | 5 | 60.9% | 73.1% | 60.5% | 1/3 |
| R32 | 98 |  Bjorn PhauClay | 182 |  Victor CrivoiClay | 6-2 6-3 | 3 | 69 | 2 | 3 | 56.4% | 71.0% | 62.5% | 4/4 |
| R32 | 66 |  Marco ChiudinelliClay | 37 | Victor HanescuClay | 7-6(4) 6-3 | 3 | 95 | 4 | 6 | 58.0% | 80.9% | 52.9% | 4/4 |
| R32 | 125 | Pablo AndujarClay | 222 | Bastian KnittelClay | 4-6 6-4 6-3 | 3 | 148 | 1 | 3 | 75.6% | 72.1% | 45.5% | 1/3 |
| R32 | 39 | Guillermo Garcia-LopezClay | 146 | Ivan NavarroClay | 4-6 6-3 6-2 | 3 | 136 | 3 | 1 | 66.3% | 72.7% | 60.7% | 0/2 |
| R32 | 56 | Florian MayerClay | 35 | Philipp KohlschreiberClay | 6-4 6-2 | 3 | 83 | 1 | 1 | 67.2% | 74.4% | 57.1% | 7/7 |
| R32 | 33 | Gilles SimonClay | 99 |  Dustin BrownClay | 6-3 3-6 7-6(1) | 3 | 111 | 4 | 2 | 65.2% | 81.7% | 53.1% | 2/3 |
| R32 | 73 | Simon GreulClay | 45 | Michael BerrerClay | 7-6(6) 6-4 | 3 | 117 | 3 | 4 | 57.3% | 72.3% | 60.0% | 8/9 |
| R32 | 43 |  Horacio ZeballosClay | 79 | Andreas BeckClay | 6-4 7-5 | 3 | 87 | 9 | 0 | 74.6% | 81.8% | 60.0% | 1/1 |
| R32 | 30 | Albert MontanesClay | 38 | Philipp PetzschnerClay | 2-6 7-5 6-2 | 3 | 105 | 5 | 3 | 73.0% | 72.2% | 75.0% | 2/4 |
| R32 | 54 | Juan Ignacio ChelaClay | 52 | Eduardo SchwankClay | 6-2 7-5 | 3 | 84 | 2 | 0 | 56.1% | 65.6% | 68.0% | 3/5 |
| R32 | 150 | Mischa ZverevClay | 48 |  Sergiy StakhovskyClay | 6-4 6-3 | 3 | 86 | 2 | 1 | 58.3% | 78.6% | 45.0% | 1/3 |
| R16 | 88 | Daniel Gimeno-TraverClay | 6 |  Nikolay DavydenkoClay | 7-6(7) 2-6 6-1 | 3 | 132 | 12 | 7 | 53.9% | 72.7% | 51.1% | 6/9 |
| R16 | 66 | Marco ChiudinelliClay | 98 | Bjorn PhauClay | 7-6(3) 6-3 | 3 | 104 | 9 | 4 | 60.0% | 77.8% | 53.3% | 3/4 |
| R16 | 17 | Gael MonfilsClay | 125 | Pablo AndujarClay | 6-4 5-7 6-4 | 3 | 135 | 7 | 1 | 64.4% | 75.0% | 58.1% | 3/6 |
| R16 | 56 | Florian MayerClay | 39 | Guillermo Garcia-LopezClay | 6-3 6-1 | 3 | 81 | 2 | 2 | 46.9% | 91.3% | 42.3% | 4/5 |
| R16 | 73 | Simon GreulClay | 33 | Gilles SimonClay | 6-4 7-5 | 3 | 89 | 4 | 2 | 66.2% | 74.5% | 62.5% | 7/8 |
| R16 | 21 | Juan Carlos FerreroClay | 43 | Horacio ZeballosClay | 6-7(1) 7-6(3) 6-2 | 3 | 136 | 10 | 2 | 68.9% | 67.1% | 66.7% | 5/7 |
| R16 | 30 | Albert MontanesClay | 54 | Juan Ignacio ChelaClay | 7-5 3-6 6-2 | 3 | 130 | 4 | 7 | 54.3% | 70.5% | 32.4% | 4/10 |
| R16 | 15 |  Jurgen MelzerClay | 150 | Mischa ZverevClay | 7-5 7-5 | 3 | 101 | 4 | 3 | 57.9% | 63.6% | 62.5% | 4/6 |
| QF | 88 | Daniel Gimeno-TraverClay | 66 | Marco ChiudinelliClay | 6-1 6-3 | 3 | 62 | 8 | 3 | 58.1% | 84.0% | 66.7% | 2/2 |
| QF | 17 | Gael MonfilsClay | 56 | Florian MayerClay | 5-7 6-3 6-4 | 3 | 131 | 11 | 4 | 56.6% | 70.2% | 69.4% | 3/6 |
| QF | 21 | Juan Carlos FerreroClay | 73 | Simon GreulClay | 6-3 7-5 | 3 | 77 | 1 | 1 | 73.3% | 77.3% | 50.0% | 1/2 |
| QF | 30 | Albert MontanesClay | 15 | Jurgen MelzerClay | 6-4 6-1 | 3 | 57 | 6 | 1 | 55.3% | 80.8% | 66.7% | 0/1 |
| SF | 17 | Gael MonfilsClay | 88 | Daniel Gimeno-TraverClay | 6-4 4-6 6-0 | 3 | 113 | 12 | 4 | 51.7% | 76.1% | 58.1% | 3/4 |
| SF | 30 | Albert MontanesClay | 21 | Juan Carlos FerreroClay | 6-3 7-6(6) | 3 | 103 | 5 | 3 | 56.7% | 78.9% | 48.3% | 0/2 |
| F | 30 | Albert MontanesClay | 17 | Gael MonfilsClay | 6-2 1-2 RET | 3 | 55 | 1 | 0 | 65.5% | 73.7% | 70.0% | 0/0 |
