| R32 | 7 |  Gilles SimonClay | 47 |  Philipp PetzschnerClay | 6-3 6-4 | 3 | 74 | 6 | 1 | 43.3% | 73.1% | 50.0% | 6/8 |
| R32 | 45 | Mischa ZverevClay | 53 |  Guillermo Garcia-LopezClay | 6-2 6-4 | 3 | 92 | 2 | 1 | 55.0% | 78.8% | 48.1% | 6/7 |
| R32 | 49 |  Martin Vassallo ArguelloClay | 71 |  Andrey GolubevClay | 3-6 6-3 6-0 | 3 | 122 | 2 | 0 | 75.0% | 73.7% | 47.4% | 7/8 |
| R32 | 43 | Jeremy ChardyClay | 37 | Jose AcasusoClay | 6-2 7-6(4) | 3 | 76 | 7 | 2 | 51.6% | 87.9% | 54.8% | 0/1 |
| R32 | 40 | Nicolas KieferClay | 21 |  Tomas BerdychClay | 6-3 6-3 | 3 | 78 | 8 | 1 | 42.6% | 75.9% | 53.8% | 6/7 |
| R32 | 87 | Simon GreulClay | 51 | Andreas BeckClay | 7-6(4) 7-6(5) | 3 | 115 | 9 | 7 | 52.7% | 70.8% | 60.5% | 2/3 |
| R32 | 127 |  Lukasz KubotClay | 140 | Pablo AndujarClay | 6-2 6-4 | 3 | 99 | 2 | 0 | 52.8% | 75.0% | 60.0% | 3/4 |
| R32 | 26 | Philipp KohlschreiberClay | 103 | Diego JunqueiraClay | 6-3 6-2 | 3 | 62 | 9 | 6 | 66.7% | 77.8% | 44.4% | 0/1 |
| R32 | 193 | Alexandre SidorenkoClay | 168 | Daniel Munoz de la NavaClay | 7-6(3) 1-6 6-2 | 3 | 107 | 6 | 1 | 55.7% | 77.3% | 54.3% | 5/8 |
| R32 | 56 | Oscar HernandezClay | 79 |  Janko TipsarevicClay | 6-4 6-4 | 3 | 70 | 6 | 0 | 61.7% | 82.8% | 72.2% | 0/1 |
| R32 | 82 | Rainer SchuettlerClay | 63 | Ivo MinarClay | 2-6 7-6(2) 6-4 | 3 | 136 | 2 | 2 | 63.2% | 65.0% | 37.1% | 5/12 |
| R32 | 33 |  Victor HanescuClay | 205 | Dominik MeffertClay | 6-4 7-6(6) | 3 | 91 | 4 | 4 | 66.2% | 80.4% | 46.2% | 5/6 |
| R32 | 67 |  Fabio FogniniClay | 46 | Fabrice SantoroClay | 5-7 7-6(3) 6-1 | 3 | 110 | 3 | 7 | 62.8% | 66.7% | 46.9% | 1/5 |
| R32 | 39 | Paul-Henri MathieuClay | 72 |  Mikhail YouzhnyClay | 7-6(4) 7-6(4) | 3 | 131 | 7 | 5 | 51.5% | 71.2% | 42.9% | 9/13 |
| R32 | 120 | Michael BerrerClay | 154 |  Stefan KoubekClay | 0-6 7-6(3) 7-6(4) | 3 | 132 | 3 | 5 | 77.5% | 57.0% | 52.2% | 5/11 |
| R32 | 11 | Nikolay DavydenkoClay | 104 | Ivan NavarroClay | 4-6 7-5 6-3 | 3 | 156 | 4 | 2 | 61.3% | 70.8% | 51.2% | 7/10 |
| R16 | 45 | Mischa ZverevClay | 7 | Gilles SimonClay | 6-4 6-2 | 3 | 67 | 1 | 1 | 61.8% | 85.3% | 52.4% | 5/5 |
| R16 | 43 | Jeremy ChardyClay | 49 | Martin Vassallo ArguelloClay | 2-6 6-3 6-1 | 3 | 97 | 6 | 6 | 59.7% | 81.1% | 52.0% | 1/3 |
| R16 | 40 | Nicolas KieferClay | 87 | Simon GreulClay | 6-3 6-4 | 3 | 75 | 5 | 1 | 53.4% | 93.5% | 59.3% | 2/2 |
| R16 | 127 | Lukasz KubotClay | 26 | Philipp KohlschreiberClay | 6-2 6-4 | 3 | 71 | 6 | 2 | 66.7% | 90.0% | 60.0% | 0/0 |
| R16 | 193 | Alexandre SidorenkoClay | 56 | Oscar HernandezClay | 2-6 6-4 6-3 | 3 | 126 | 4 | 4 | 51.1% | 71.1% | 48.8% | 2/5 |
| R16 | 33 | Victor HanescuClay | 82 | Rainer SchuettlerClay | 6-2 6-1 | 3 | 56 | 4 | 0 | 76.2% | 81.3% | 60.0% | 0/0 |
| R16 | 67 | Fabio FogniniClay | 39 | Paul-Henri MathieuClay | 6-4 4-1 RET | 3 | 59 | 4 | 3 | 67.5% | 74.1% | 53.8% | 0/1 |
| R16 | 11 | Nikolay DavydenkoClay | 120 | Michael BerrerClay | 6-3 6-3 | 3 | 66 | 2 | 0 | 77.1% | 73.0% | 63.6% | 0/1 |
| QF | 43 | Jeremy ChardyClay | 45 | Mischa ZverevClay | 7-6(4) 6-1 | 3 | 83 | 4 | 1 | 64.3% | 68.9% | 64.0% | 6/7 |
| QF | 40 | Nicolas KieferClay | 127 | Lukasz KubotClay | 6-2 6-1 | 3 | 64 | 7 | 0 | 52.6% | 95.0% | 72.2% | 0/0 |
| QF | 33 | Victor HanescuClay | 193 | Alexandre SidorenkoClay | 7-6(2) 6-4 | 3 | 84 | 6 | 1 | 66.7% | 86.4% | 59.1% | 1/1 |
| QF | 67 | Fabio FogniniClay | 11 | Nikolay DavydenkoClay | 6-1 3-6 7-5 | 3 | 140 | 3 | 2 | 56.4% | 75.5% | 39.0% | 4/7 |
| SF | 43 | Jeremy ChardyClay | 40 | Nicolas KieferClay | 6-3 7-5 | 3 | 79 | 2 | 3 | 59.6% | 83.9% | 52.4% | 1/2 |
| SF | 33 | Victor HanescuClay | 67 | Fabio FogniniClay | 6-3 6-7(4) 6-2 | 3 | 135 | 3 | 4 | 67.0% | 64.6% | 56.3% | 6/10 |
| F | 43 | Jeremy ChardyClay | 33 | Victor HanescuClay | 1-6 6-3 6-4 | 3 | 108 | 10 | 5 | 60.2% | 78.0% | 42.4% | 5/8 |
