| R32 | 114 |  Brian DabulClay | 89 |  Denis GremelmayrClay | 6-3 5-7 6-3 | 3 | 152 | 3 | 2 | 73.5% | 57.3% | 59.3% | 6/10 |
| R32 | 122 | Andreas BeckClay | 243 | Daniel BrandsClay | 3-6 6-3 6-4 | 3 | 117 | 4 | 2 | 62.7% | 71.9% | 52.6% | 4/5 |
| R32 | 62 | Eduardo SchwankClay | 557 | Guillermo CoriaClay | 0-6 6-1 6-2 | 3 | 116 | 5 | 1 | 71.8% | 58.8% | 45.0% | 2/6 |
| R32 | 154 |  Yuri SchukinClay | 116 | Carlos BerlocqClay | 4-6 7-5 6-3 | 3 | 162 | 0 | 2 | 72.3% | 52.9% | 53.8% | 6/12 |
| R32 | 65 | Juan Martin del PotroClay | 84 | Evgeny KorolevClay | 6-3 7-5 | 3 | 93 | 5 | 5 | 54.1% | 72.7% | 64.3% | 1/3 |
| R32 | 47 |  Simone BolelliClay | 81 | Mischa ZverevClay | 6-7(6) 6-4 6-2 | 3 | 152 | 3 | 1 | 75.0% | 75.3% | 48.1% | 4/4 |
| R32 | 52 | Agustin CalleriClay | 63 |  Jurgen MelzerClay | 7-6(3) 6-4 | 3 | 84 | 8 | 5 | 50.8% | 78.8% | 59.4% | 2/4 |
| R32 | 117 |  Pablo CuevasClay | 160 |  Santiago GiraldoClay | 4-6 6-4 7-6(11) | 3 | 158 | 9 | 7 | 48.5% | 66.7% | 43.3% | 7/13 |
| R32 | 104 | Michael BerrerClay | 127 |  Eric ProdonClay | 6-3 6-4 | 3 | 70 | 12 | 11 | 55.1% | 84.2% | 35.5% | 10/12 |
| R32 | 70 |  Albert MontanesClay | 53 | Jose AcasusoClay | 6-3 7-6(5) | 3 | 94 | 6 | 4 | 50.0% | 77.1% | 62.9% | 0/1 |
| R32 | 110 | Oscar HernandezClay | 95 | Santiago VenturaClay | 6-1 6-4 | 3 | 85 | 3 | 2 | 73.6% | 71.8% | 57.1% | 1/2 |
| R32 | 188 |  Lukas RosolClay | 255 | Martin FischerClay | 6-2 6-4 | 3 | 66 | 3 | 4 | 55.6% | 76.7% | 45.8% | 2/4 |
| R16 | 139 | Jan HernychClay | 114 | Brian DabulClay | 7-6(5) 0-6 7-6(5) | 3 | 150 | 7 | 1 | 73.0% | 65.8% | 55.6% | 4/8 |
| R16 | 62 | Eduardo SchwankClay | 122 | Andreas BeckClay | 7-6(5) 6-2 | 3 | 93 | 11 | 1 | 67.2% | 86.7% | 50.0% | 1/1 |
| R16 | 35 | Philipp KohlschreiberClay | 154 | Yuri SchukinClay | 6-3 6-3 | 3 | 81 | 4 | 4 | 57.7% | 73.3% | 54.5% | 1/2 |
| R16 | 65 | Juan Martin del PotroClay | 47 | Simone BolelliClay | 6-3 3-6 6-3 | 3 | 121 | 4 | 6 | 47.4% | 88.9% | 50.0% | 0/2 |
| R16 | 52 | Agustin CalleriClay | 117 | Pablo CuevasClay | 5-7 7-5 6-1 | 3 | 108 | 10 | 3 | 59.1% | 80.8% | 50.0% | 3/5 |
| R16 | 104 | Michael BerrerClay | 11 | Nicolas AlmagroClay | 7-5 RET | 3 | 44 | 0 | 0 | 50.0% | 85.7% | 85.7% | 0/0 |
| R16 | 70 | Albert MontanesClay | 110 | Oscar HernandezClay | 7-6(4) 6-4 | 3 | 113 | 8 | 1 | 53.1% | 79.4% | 66.7% | 1/2 |
| R16 | 15 | Richard GasquetClay | 188 | Lukas RosolClay | 6-7(7) 6-2 6-2 | 3 | 112 | 12 | 2 | 61.4% | 74.1% | 44.1% | 3/6 |
| QF | 62 | Eduardo SchwankClay | 139 | Jan HernychClay | 6-0 4-6 6-3 | 3 | 115 | 1 | 2 | 61.5% | 77.1% | 50.0% | 5/7 |
| QF | 65 | Juan Martin del PotroClay | 35 | Philipp KohlschreiberClay | 7-6(3) 6-3 | 3 | 132 | 9 | 2 | 47.0% | 90.3% | 68.6% | 4/4 |
| QF | 52 | Agustin CalleriClay | 104 | Michael BerrerClay | 6-4 6-2 | 3 | 66 | 9 | 4 | 64.4% | 96.6% | 50.0% | 0/0 |
| QF | 15 | Richard GasquetClay | 70 | Albert MontanesClay | 6-3 7-6(5) | 3 | 96 | 7 | 4 | 52.1% | 71.1% | 65.7% | 7/8 |
| SF | 65 | Juan Martin del PotroClay | 62 | Eduardo SchwankClay | 6-2 6-4 | 3 | 87 | 4 | 3 | 60.7% | 73.5% | 63.6% | 0/0 |
| SF | 15 | Richard GasquetClay | 52 | Agustin CalleriClay | 6-7(3) 6-2 6-3 | 3 | 125 | 10 | 0 | 56.5% | 79.2% | 62.2% | 3/4 |
| F | 65 | Juan Martin del PotroClay | 15 | Richard GasquetClay | 6-4 7-5 | 3 | 95 | 2 | 1 | 58.5% | 71.0% | 77.3% | 0/2 |
