| R32 | 15 |  David FerrerClay | 188 |  Lukas LackoClay | 6-2 6-2 | 3 | 51 | 2 | 0 | 72.5% | 89.7% | 63.6% | 3/3 |
| R32 | 2 | Rafael NadalClay | 135 |  Alexander WaskeClay | 6-1 6-1 | 3 | 73 | 4 | 2 | 67.4% | 75.9% | 64.3% | 2/2 |
| R32 | 37 | Philipp KohlschreiberClay | 140 | Simon GreulClay | 6-1 6-2 | 3 | 54 | 1 | 2 | 64.4% | 72.4% | 68.8% | 0/0 |
| R32 | 67 |  Stefan KoubekClay | 49 |  Jose AcasusoClay | 6-2 7-5 | 3 | 91 | 10 | 1 | 57.8% | 86.5% | 44.4% | 5/6 |
| R32 | 29 | Juan MonacoClay | 115 |  Jan HernychClay | 6-2 6-1 | 3 | 61 | 5 | 0 | 45.5% | 95.0% | 62.5% | 0/0 |
| R32 | 10 | Tomas BerdychClay | 58 |  Nicolas LapenttiClay | 6-1 6-1 | 3 | 50 | 3 | 1 | 46.2% | 83.3% | 71.4% | 1/1 |
| R32 | 84 | Feliciano LopezClay | 73 | Carlos BerlocqClay | 6-7(5) 7-6(7) 6-4 | 3 | 155 | 16 | 2 | 55.5% | 86.9% | 53.1% | 7/8 |
| R32 | 87 | Diego HartfieldClay | 193 | Jan HajekClay | 6-4 6-2 | 3 | 74 | 3 | 1 | 62.5% | 86.7% | 55.6% | 0/0 |
| R32 | 17 | Juan Carlos FerreroClay | 114 | Gaston GaudioClay | 6-1 6-2 | 3 | 72 | 4 | 2 | 44.7% | 76.2% | 50.0% | 3/4 |
| R32 | 19 | Juan Ignacio ChelaClay | 90 |  Max MirnyiClay | 6-3 6-3 | 3 | 75 | 4 | 7 | 55.4% | 77.4% | 52.0% | 6/7 |
| R32 | 132 |  Boris PashanskiClay | 80 | Guillermo Garcia-LopezClay | 1-6 6-2 6-4 | 3 | 138 | 5 | 8 | 49.5% | 65.2% | 48.9% | 8/12 |
| R32 | 48 | Fernando VerdascoClay | 35 | Florian MayerClay | 6-3 6-2 | 3 | 69 | 3 | 2 | 66.0% | 69.7% | 70.6% | 2/3 |
| R32 | 50 |  Stan WawrinkaClay | 16 | Guillermo CanasClay | 6-7(5) 6-2 1-0 RET | 3 | 134 | 6 | 3 | 45.5% | 73.3% | 66.7% | 4/5 |
| R32 | 121 |  Marin CilicClay | 46 | Benjamin BeckerClay | 6-3 6-2 | 3 | 70 | 14 | 4 | 49.0% | 84.0% | 53.8% | 4/5 |
| R32 | 117 | Jiri VanekClay | 94 | Ivan NavarroClay | 6-1 6-1 | 3 | 73 | 5 | 1 | 58.5% | 75.0% | 70.6% | 1/1 |
| R32 | 56 |  Gael MonfilsClay | 7 | Tommy RobredoClay | 7-6(5) 6-2 | 3 | 90 | 11 | 2 | 53.0% | 80.0% | 64.5% | 3/3 |
| R16 | 2 | Rafael NadalClay | 37 | Philipp KohlschreiberClay | 6-3 6-3 | 3 | 101 | 1 | 1 | 61.7% | 75.9% | 61.1% | 0/1 |
| R16 | 29 | Juan MonacoClay | 67 | Stefan KoubekClay | 6-2 3-6 6-3 | 3 | 104 | 8 | 1 | 58.4% | 73.3% | 56.3% | 3/5 |
| R16 | 84 | Feliciano LopezClay | 10 | Tomas BerdychClay | 6-0 6-3 | 3 | 51 | 5 | 1 | 57.9% | 95.5% | 68.8% | 0/0 |
| R16 | 17 | Juan Carlos FerreroClay | 87 | Diego HartfieldClay | 6-4 1-6 6-3 | 3 | 123 | 5 | 5 | 61.1% | 69.1% | 51.4% | 6/8 |
| R16 | 19 | Juan Ignacio ChelaClay | 132 | Boris PashanskiClay | 7-5 4-6 6-4 | 3 | 168 | 3 | 5 | 51.9% | 65.5% | 56.9% | 7/10 |
| R16 | 48 | Fernando VerdascoClay | 15 | David FerrerClay | 7-5 6-3 | 3 | 93 | 2 | 1 | 83.9% | 67.3% | 50.0% | 3/5 |
| R16 | 50 | Stan WawrinkaClay | 121 | Marin CilicClay | 6-4 6-1 | 3 | 79 | 2 | 4 | 48.3% | 78.6% | 50.0% | 1/2 |
| R16 | 117 | Jiri VanekClay | 56 | Gael MonfilsClay | 1-6 7-6(4) 6-2 | 3 | 111 | 3 | 4 | 47.3% | 74.4% | 54.2% | 6/8 |
| QF | 2 | Rafael NadalClay | 29 | Juan MonacoClay | 6-1 6-3 | 3 | 77 | 3 | 0 | 71.8% | 82.1% | 81.8% | 0/0 |
| QF | 84 | Feliciano LopezClay | 17 | Juan Carlos FerreroClay | 6-4 3-6 6-4 | 3 | 125 | 10 | 8 | 52.1% | 70.0% | 58.7% | 4/6 |
| QF | 19 | Juan Ignacio ChelaClay | 48 | Fernando VerdascoClay | 2-6 6-3 6-2 | 3 | 124 | 2 | 4 | 61.9% | 67.3% | 59.4% | 5/7 |
| QF | 50 | Stan WawrinkaClay | 117 | Jiri VanekClay | 6-1 6-4 | 3 | 60 | 8 | 6 | 52.7% | 82.8% | 46.2% | 2/3 |
| SF | 2 | Rafael NadalClay | 84 | Feliciano LopezClay | 6-1 7-5 | 3 | 86 | 5 | 1 | 67.3% | 82.9% | 70.6% | 0/0 |
| SF | 50 | Stan WawrinkaClay | 19 | Juan Ignacio ChelaClay | 6-7(2) 6-4 6-1 | 3 | 155 | 8 | 2 | 64.3% | 61.9% | 57.1% | 8/11 |
| F | 2 | Rafael NadalClay | 50 | Stan WawrinkaClay | 6-4 7-5 | 3 | 129 | 1 | 3 | 70.9% | 64.3% | 43.5% | 6/9 |
