| R32 | 93 |  Mariano ZabaletaClay | 36 |  Olivier RochusClay | 4-6 6-2 6-3 | 3 | 115 | 9 | 3 | 53.8% | 71.4% | 61.1% | 4/7 |
| R32 | 56 |  Paul-Henri MathieuClay | 100 |  Albert CostaClay | 6-3 6-4 | 3 | 103 | 2 | 1 | 53.2% | 69.7% | 51.7% | 1/3 |
| R32 | 13 | Gaston GaudioClay | 357 |  Andreas BeckClay | 6-3 6-3 | 3 | 78 | 9 | 2 | 49.1% | 88.5% | 51.9% | 3/4 |
| R32 | 89 | Rainer SchuettlerClay | 25 |  Mikhail YouzhnyClay | 7-5 6-3 | 3 | 93 | 3 | 6 | 64.8% | 65.2% | 44.0% | 6/9 |
| R32 | 38 |  Tomas BerdychClay | 64 | Philipp KohlschreiberClay | 7-6(4) 1-6 6-3 | 3 | 107 | 2 | 7 | 57.1% | 87.5% | 41.7% | 3/5 |
| R32 | 121 | Alexander WaskeClay | 44 | Jose AcasusoClay | 7-5 6-4 | 3 | 79 | 10 | 2 | 69.1% | 76.3% | 58.8% | 1/3 |
| R32 | 7 | Nikolay DavydenkoClay | 147 | Ruben Ramirez HidalgoClay | 6-4 6-1 | 3 | 70 | 6 | 2 | 68.3% | 71.4% | 53.8% | 0/2 |
| R16 | 3 | Rafael NadalClay | 58 | Fernando VerdascoClay | 6-3 6-2 | 3 | 77 | 3 | 1 | 60.9% | 78.6% | 66.7% | 3/3 |
| R16 | 57 | Tomas ZibClay | 67 | Juan MonacoClay | 6-4 7-6(4) | 3 | 101 | 1 | 3 | 52.8% | 63.2% | 52.9% | 1/5 |
| R16 | 77 |  Andreas SeppiClay | 16 | Tommy RobredoClay | 7-5 2-6 6-1 | 3 | 92 | 2 | 4 | 58.8% | 68.1% | 60.6% | 7/10 |
| R16 | 66 |  Jarkko NieminenClay | 23 | Jiri NovakClay | 2-6 6-2 7-6(8) | 3 | 108 | 2 | 1 | 60.0% | 66.7% | 38.9% | 4/9 |
| R16 | 93 | Mariano ZabaletaClay | 132 | Gilles SimonClay | 7-6(3) 6-1 | 3 | 83 | 3 | 7 | 50.7% | 66.7% | 54.3% | 1/3 |
| R16 | 13 | Gaston GaudioClay | 56 | Paul-Henri MathieuClay | 6-2 6-7(3) 6-0 | 3 | 121 | 2 | 2 | 60.0% | 58.8% | 64.7% | 2/4 |
| R16 | 38 | Tomas BerdychClay | 89 | Rainer SchuettlerClay | 7-6(4) 6-1 | 3 | 75 | 5 | 0 | 64.2% | 73.5% | 63.2% | 1/2 |
| R16 | 7 | Nikolay DavydenkoClay | 121 | Alexander WaskeClay | 7-6(3) 6-3 | 3 | 91 | 2 | 2 | 71.4% | 72.0% | 55.0% | 1/3 |
| QF | 3 | Rafael NadalClay | 57 | Tomas ZibClay | 6-2 6-1 | 3 | 80 | 6 | 1 | 60.5% | 73.1% | 70.6% | 2/2 |
| QF | 66 | Jarkko NieminenClay | 77 | Andreas SeppiClay | 6-2 6-3 | 3 | 83 | 1 | 1 | 71.2% | 66.0% | 52.6% | 4/5 |
| QF | 13 | Gaston GaudioClay | 93 | Mariano ZabaletaClay | 6-4 1-6 6-2 | 3 | 103 | 1 | 0 | 70.8% | 66.7% | 52.4% | 5/8 |
| QF | 7 | Nikolay DavydenkoClay | 38 | Tomas BerdychClay | 6-4 6-2 | 3 | 72 | 3 | 3 | 53.1% | 80.8% | 69.6% | 0/0 |
| SF | 3 | Rafael NadalClay | 66 | Jarkko NieminenClay | 6-2 7-5 | 3 | 89 | 2 | 1 | 62.0% | 80.6% | 52.6% | 0/2 |
| SF | 13 | Gaston GaudioClay | 7 | Nikolay DavydenkoClay | 6-3 2-1 RET | 3 | 56 | 2 | 1 | 57.5% | 65.2% | 47.1% | 2/4 |
| F | 3 | Rafael NadalClay | 13 | Gaston GaudioClay | 6-3 6-3 6-4 | 5 | 161 | 3 | 2 | 69.2% | 69.8% | 46.4% | 3/5 |
| R64 | 167 |  Hugo ArmandoClay | 208 |  Gustavo KuertenClay | 6-4 6-1 | 3 | 79 | 3 | 1 | 53.1% | 79.4% | 43.3% | 4/5 |
| R64 | 58 | Fernando VerdascoClay | 82 | Nicolas AlmagroClay | 7-6(4) 6-0 | 3 | 74 | 7 | 1 | 63.6% | 71.4% | 50.0% | 3/3 |
| R64 | 57 | Tomas ZibClay | 140 | Simon GreulClay | 4-6 7-6(7) 6-2 | 3 | 114 | 6 | 4 | 60.2% | 76.3% | 53.8% | 5/8 |
| R64 | 67 | Juan MonacoClay | 168 | Tobias SummererClay | 6-1 6-4 | 3 | 71 | 2 | 2 | 67.2% | 62.2% | 59.1% | 1/2 |
| R64 | 95 | Potito StaraceClay | 65 | Gael MonfilsClay | 6-2 6-3 | 3 | 58 | 0 | 1 | 78.6% | 78.8% | 77.8% | 0/0 |
| R64 | 77 | Andreas SeppiClay | 83 | Florian MayerClay | 7-6(3) 6-3 | 3 | 74 | 7 | 2 | 53.7% | 77.8% | 61.3% | 4/5 |
| R64 | 66 | Jarkko NieminenClay | 85 | Lars BurgsmullerClay | 6-7(5) 6-0 6-1 | 3 | 113 | 0 | 3 | 62.6% | 66.7% | 55.9% | 6/8 |
| R64 | 79 |  Razvan SabauClay | 138 | Carlos BerlocqClay | 6-2 6-2 | 3 | 61 | 1 | 2 | 61.5% | 75.0% | 60.0% | 5/5 |
| R64 | 132 | Gilles SimonClay | 84 | Albert MontanesClay | 6-7(3) 6-1 6-1 | 3 | 204 | 7 | 5 | 60.4% | 75.9% | 57.9% | 4/4 |
| R64 | 93 | Mariano ZabaletaClay | 1473 | Aljoscha ThronClay | 6-2 6-3 | 3 | 84 | 4 | 5 | 55.4% | 67.7% | 60.0% | 10/11 |
| R64 | 100 | Albert CostaClay | 292 | Galo BlancoClay | 6-4 6-4 | 3 | 97 | 4 | 3 | 63.1% | 70.7% | 45.8% | 4/6 |
| R64 | 357 | Andreas BeckClay | 105 | Alessio Di MauroClay | 6-4 6-3 | 3 | 92 | 1 | 3 | 63.3% | 68.4% | 63.6% | 0/1 |
| R64 | 89 | Rainer SchuettlerClay | 122 | Fernando VicenteClay | 7-6(3) 6-4 | 3 | 93 | 1 | 1 | 71.8% | 64.7% | 50.0% | 2/5 |
| R64 | 64 | Philipp KohlschreiberClay | 136 | Juan Pablo BrzezickiClay | 3-6 6-3 6-3 | 3 | 119 | 2 | 1 | 66.7% | 57.7% | 65.4% | 6/10 |
| R64 | 121 | Alexander WaskeClay | 108 | Jerome HaehnelClay | 7-5 6-2 | 3 | 75 | 8 | 2 | 62.7% | 81.1% | 45.5% | 3/5 |
| R64 | 147 | Ruben Ramirez HidalgoClay | 87 |  Stefan KoubekClay | 6-4 6-3 | 3 | 85 | 3 | 0 | 63.9% | 69.2% | 50.0% | 4/5 |
| R32 | 3 | Rafael NadalClay | 167 | Hugo ArmandoClay | 6-1 6-2 | 3 | 62 | 2 | 1 | 46.3% | 78.9% | 68.2% | 1/1 |
| R32 | 58 | Fernando VerdascoClay | 48 | Igor AndreevClay | 6-4 5-7 7-6(5) | 3 | 142 | 9 | 8 | 60.2% | 67.6% | 60.0% | 10/13 |
| R32 | 57 | Tomas ZibClay | 41 | Andrei PavelClay | 5-7 6-3 6-1 | 3 | 124 | 6 | 4 | 51.4% | 67.9% | 54.7% | 2/4 |
| R32 | 67 | Juan MonacoClay | 20 | David FerrerClay | 6-4 6-2 | 3 | 74 | 1 | 1 | 68.8% | 75.0% | 50.0% | 4/4 |
| R32 | 16 | Tommy RobredoClay | 95 | Potito StaraceClay | 6-7(4) 6-3 6-2 | 3 | 125 | 4 | 1 | 58.1% | 75.0% | 53.1% | 13/14 |
| R32 | 77 | Andreas SeppiClay | 52 | Alberto MartinClay | 6-4 6-4 | 3 | 95 | 4 | 3 | 50.6% | 77.5% | 48.7% | 13/14 |
| R32 | 66 | Jarkko NieminenClay | 37 | Jurgen MelzerClay | 6-4 6-7(4) 6-4 | 3 | 124 | 2 | 2 | 65.0% | 51.3% | 59.5% | 5/11 |
| R32 | 23 | Jiri NovakClay | 79 | Razvan SabauClay | 4-6 6-4 6-0 | 3 | 94 | 6 | 2 | 63.4% | 65.4% | 53.3% | 3/6 |
| R32 | 132 | Gilles SimonClay | 34 | Filippo VolandriClay | 6-3 2-6 6-4 | 3 | 104 | 3 | 2 | 54.9% | 60.7% | 37.0% | 8/15 |
