| R64 | 76 | Radek StepanekClay | 160 | Juan-Pablo GuzmanClay | 7-6(4) 6-3 | 3 | 83 | 4 | 3 | 57.7% | 82.9% | 60.0% | 3/3 |
| R64 | 162 | Franco SquillariClay | 109 | Nicolas AlmagroClay | 6-3 7-6(1) | 3 | 92 | 2 | 3 | 57.8% | 64.6% | 74.3% | 4/4 |
| R64 | 70 | Guillermo CanasClay | 168 | Dick NormanClay | 6-0 7-5 | 3 | 57 | 6 | 4 | 60.0% | 88.9% | 66.7% | 0/0 |
| R64 | 101 | Stefan KoubekClay | 90 | Olivier PatienceClay | 6-2 7-6(5) | 3 | 70 | 5 | 3 | 66.7% | 84.2% | 63.2% | 0/1 |
| R64 | 122 | Bohdan UlihrachClay | 85 | Victor HanescuClay | 7-6(3) 4-1 RET | 3 | 69 | 2 | 2 | 57.1% | 71.9% | 50.0% | 3/5 |
| R64 | 473 | Andreas BeckClay | 120 | Alexander PeyaClay | 7-6(2) 6-1 | 3 | 81 | 1 | 3 | 59.3% | 68.6% | 50.0% | 0/2 |
| R64 | 111 | Felix MantillaClay | 192 | Jerome HaehnelClay | 6-7(1) 6-2 6-2 | 3 | 116 | 5 | 3 | 59.5% | 70.2% | 59.4% | 2/5 |
| R64 | 129 | Marc LopezClay | 104 | Daniel ElsnerClay | 6-1 6-7(5) 6-3 | 3 | 114 | 1 | 1 | 58.8% | 64.9% | 47.5% | 5/9 |
| R64 | 130 | Richard GasquetClay | 185 | Edouard Roger-VasselinClay | 6-2 6-4 | 3 | 72 | 5 | 2 | 43.1% | 77.3% | 65.5% | 2/3 |
| R64 | 356 | Arnaud Di PasqualeClay | 105 | Galo BlancoClay | 6-3 6-1 | 3 | 61 | 2 | 4 | 58.7% | 81.5% | 42.1% | 3/4 |
| R64 | 132 | Martin Vassallo ArguelloClay | 135 | Philipp KohlschreiberClay | 6-3 3-6 6-2 | 3 | 115 | 1 | 9 | 64.4% | 70.8% | 41.7% | 11/13 |
| R64 | 242 | Jan Frode AndersenClay | 113 | Lars BurgsmullerClay | 6-4 6-2 | 3 | 99 | 3 | 2 | 66.7% | 70.5% | 54.5% | 5/5 |
| R64 | 86 | Thierry AscioneClay | 142 | Tomas ZibClay | 6-3 7-6(8) | 3 | 81 | 7 | 3 | 73.0% | 81.5% | 60.0% | 3/3 |
| R64 | 84 | Alexander PoppClay | 191 | Alexander WaskeClay | 6-2 1-6 6-1 | 3 | 84 | 0 | 2 | 76.2% | 75.0% | 40.0% | 4/6 |
| R64 | 178 | Bjorn PhauClay | 125 | Ivo HeubergerClay | 6-3 6-2 | 3 | 63 | 1 | 2 | 48.9% | 82.6% | 62.5% | 3/3 |
| R64 | 280 | Hugo ArmandoClay | 1249 | Sebastian RieschickClay | 6-1 6-4 | 3 | 59 | 2 | 2 | 50.0% | 82.1% | 46.4% | 0/1 |
| R32 | 76 | Radek StepanekClay | 8 | Rainer SchuettlerClay | 6-7(6) 6-3 6-2 | 3 | 119 | 8 | 2 | 60.0% | 78.3% | 50.0% | 4/4 |
| R32 | 59 | Ivo KarlovicClay | 162 | Franco SquillariClay | 6-3 7-6(0) | 3 | 78 | 13 | 2 | 69.4% | 82.0% | 54.5% | 4/4 |
| R32 | 70 | Guillermo CanasClay | 37 | Florian MayerClay | 6-7(3) 7-6(5) 6-4 | 3 | 178 | 5 | 3 | 50.4% | 66.7% | 51.8% | 8/13 |
| R32 | 101 | Stefan KoubekClay | 23 | Feliciano LopezClay | 6-3 6-4 | 3 | 63 | 2 | 1 | 76.5% | 82.1% | 75.0% | 0/0 |
| R32 | 17 | Andrei PavelClay | 122 | Bohdan UlihrachClay | 6-1 6-1 | 3 | 43 | 3 | 0 | 67.5% | 74.1% | 69.2% | 3/3 |
| R32 | 63 | Nikolay DavydenkoClay | 473 | Andreas BeckClay | 6-3 6-3 | 3 | 75 | 4 | 3 | 57.9% | 69.7% | 62.5% | 5/6 |
| R32 | 52 | Albert CostaClay | 111 | Felix MantillaClay | 7-5 6-4 | 3 | 92 | 5 | 0 | 63.2% | 74.4% | 64.0% | 0/0 |
| R32 | 30 | Mariano ZabaletaClay | 129 | Marc LopezClay | 7-6(2) 6-2 | 3 | 89 | 5 | 2 | 58.7% | 73.0% | 65.4% | 1/2 |
| R32 | 130 | Richard GasquetClay | 19 | Tommy RobredoClay | 6-1 6-4 | 3 | 62 | 4 | 3 | 53.8% | 78.6% | 58.3% | 1/2 |
| R32 | 47 | David FerrerClay | 356 | Arnaud Di PasqualeClay | 6-4 1-6 6-1 | 3 | 93 | 2 | 1 | 65.3% | 61.7% | 56.0% | 1/5 |
| R32 | 57 | Rafael NadalClay | 132 | Martin Vassallo ArguelloClay | 7-6(4) 6-4 | 3 | 128 | 1 | 3 | 58.8% | 64.0% | 42.9% | 7/12 |
| R32 | 16 | Juan Ignacio ChelaClay | 242 | Jan Frode AndersenClay | 6-3 6-1 | 3 | 62 | 4 | 2 | 58.0% | 65.5% | 66.7% | 3/4 |
| R32 | 25 | Jiri NovakClay | 86 | Thierry AscioneClay | 6-2 6-4 | 3 | 54 | 3 | 1 | 61.7% | 79.3% | 55.6% | 3/5 |
| R32 | 41 | Mikhail YouzhnyClay | 84 | Alexander PoppClay | 6-3 7-6(7) | 3 | 88 | 6 | 2 | 49.4% | 73.8% | 58.1% | 8/9 |
| R32 | 67 | Tomas BerdychClay | 178 | Bjorn PhauClay | 6-2 6-3 | 3 | 51 | 7 | 1 | 60.4% | 82.8% | 68.4% | 0/0 |
| R32 | 11 | Gaston GaudioClay | 280 | Hugo ArmandoClay | 3-6 6-2 7-6(5) | 3 | 140 | 7 | 2 | 55.8% | 75.5% | 52.4% | 4/6 |
| R16 | 76 | Radek StepanekClay | 59 | Ivo KarlovicClay | 6-2 7-5 | 3 | 71 | 3 | 2 | 65.6% | 69.0% | 59.1% | 3/4 |
| R16 | 70 | Guillermo CanasClay | 101 | Stefan KoubekClay | 6-4 6-2 | 3 | 81 | 1 | 5 | 50.0% | 76.7% | 53.3% | 3/4 |
| R16 | 63 | Nikolay DavydenkoClay | 17 | Andrei PavelClay | 7-5 1-6 6-4 | 3 | 111 | 2 | 0 | 54.9% | 69.2% | 53.1% | 5/10 |
| R16 | 52 | Albert CostaClay | 30 | Mariano ZabaletaClay | 7-5 7-6(4) | 3 | 123 | 1 | 1 | 70.9% | 70.5% | 52.0% | 3/5 |
| R16 | 47 | David FerrerClay | 130 | Richard GasquetClay | 6-4 6-2 | 3 | 78 | 0 | 0 | 64.3% | 69.4% | 70.0% | 1/1 |
| R16 | 57 | Rafael NadalClay | 16 | Juan Ignacio ChelaClay | 6-2 6-3 | 3 | 76 | 3 | 1 | 48.1% | 80.0% | 70.4% | 0/0 |
| R16 | 25 | Jiri NovakClay | 41 | Mikhail YouzhnyClay | 7-6(4) 4-6 6-1 | 3 | 110 | 6 | 2 | 60.2% | 78.0% | 48.7% | 5/8 |
| R16 | 11 | Gaston GaudioClay | 67 | Tomas BerdychClay | 6-2 6-4 | 3 | 66 | 2 | 1 | 64.6% | 83.9% | 70.6% | 0/0 |
| QF | 70 | Guillermo CanasClay | 76 | Radek StepanekClay | 6-4 6-4 | 3 | 74 | 4 | 1 | 62.3% | 84.8% | 70.0% | 0/0 |
| QF | 63 | Nikolay DavydenkoClay | 52 | Albert CostaClay | 6-3 6-4 | 3 | 90 | 4 | 1 | 64.2% | 60.5% | 54.2% | 7/10 |
| QF | 47 | David FerrerClay | 57 | Rafael NadalClay | 6-3 6-7(3) 7-5 | 3 | 146 | 3 | 3 | 62.5% | 67.1% | 45.2% | 2/6 |
| QF | 11 | Gaston GaudioClay | 25 | Jiri NovakClay | 6-4 6-3 | 3 | 71 | 2 | 3 | 69.6% | 69.2% | 58.8% | 1/2 |
| SF | 70 | Guillermo CanasClay | 63 | Nikolay DavydenkoClay | 3-6 6-1 6-2 | 3 | 118 | 1 | 0 | 65.1% | 68.3% | 68.2% | 4/7 |
| SF | 11 | Gaston GaudioClay | 47 | David FerrerClay | 6-3 5-7 6-4 | 3 | 143 | 1 | 2 | 63.5% | 59.0% | 54.3% | 7/12 |
| F | 70 | Guillermo CanasClay | 11 | Gaston GaudioClay | 5-7 6-2 6-0 1-6 6-3 | 5 | 220 | 14 | 6 | 60.3% | 67.1% | 42.9% | 12/19 |