| R32 | 109 |  Francisco ClavetClay | 29 |  Jaime YzagaClay | 3-6 6-1 6-2 | 3 | 139 | 0 | 4 | 63.1% | 66.0% | 48.4% | 6/9 |
| R32 | 172 |  Christian MiniussiClay | 120 | Jose Francisco AlturClay | 6-3 6-4 | 3 | 94 | 3 | 4 | 56.7% | 76.5% | 69.2% | 2/3 |
| R32 | 108 |  Jean-Philippe FleurianClay | 116 | Alberto ManciniClay | 7-6(5) 6-3 | 3 | 97 | 2 | 2 | 66.2% | 69.8% | 54.5% | 1/3 |
| R32 | 90 | Alex CorretjaClay | 181 |  Danilo MarcelinoClay | 7-5 6-3 | 3 | 84 | 3 | 3 | 51.6% | 78.1% | 66.7% | 1/2 |
| R32 | 45 | Alberto BerasateguiClay | 233 | Fernando RoeseClay | 6-1 6-3 | 3 | 53 | 2 | 4 | 61.5% | 71.9% | 50.0% | 2/3 |
| R32 | 71 |  Renzo FurlanClay | 99 | Gabriel MarkusClay | 6-3 6-4 | 3 | 83 | 3 | 1 | 49.0% | 70.8% | 60.0% | 3/5 |
| R32 | 87 | Jaime OncinsClay | 65 | Jordi BurilloClay | 6-7(4) 7-5 6-1 | 3 | 135 | 7 | 9 | 47.9% | 71.7% | 44.0% | 3/9 |
| R32 | 59 | MARYounes El AynaouiClay | 303 | Cassio MottaClay | 6-2 6-1 | 3 | 60 | 2 | 8 | 42.1% | 87.5% | 54.5% | 5/5 |
| R32 | 41 | Emilio SanchezClay | 82 |  Marcelo FilippiniClay | 4-6 7-5 6-3 | 3 | 162 | 2 | 4 | 57.3% | 71.2% | 52.3% | 4/7 |
| R32 | 94 |  Gilbert SchallerClay | 281 |  Oliver GrossClay | 7-5 4-6 6-4 | 3 | 153 | 4 | 0 | 56.3% | 63.3% | 50.0% | 3/9 |
| R32 | 96 |  Slava DosedelClay | 151 |  Joao Cunha-SilvaClay | 6-2 7-5 | 3 | 103 | 3 | 1 | 54.5% | 80.6% | 46.7% | 4/5 |
| R32 | 125 | Daniel OrsanicClay | 48 | Luiz MattarClay | 6-1 7-5 | 3 | 81 | 2 | 0 | 70.9% | 69.2% | 62.5% | 0/1 |
| R32 | 67 | Fabrice SantoroClay | 70 | Horacio de la PenaClay | 6-1 2-6 7-5 | 3 | 148 | 1 | 3 | 68.9% | 64.7% | 56.5% | 5/9 |
| R32 | 98 | Jordi ArreseClay | 92 | Tomas CarbonellClay | 2-6 7-5 6-3 | 3 | 167 | 0 | 3 | 75.0% | 60.6% | 45.5% | 5/10 |
| R32 | 101 | Fernando MeligeniClay | 115 |  Robbie WeissClay | 6-3 6-2 | 3 | 72 | 5 | 1 | 48.1% | 76.0% | 59.3% | 0/1 |
| R32 | 73 | Javier FranaClay | 40 |  Richard FrombergClay | 6-2 6-4 | 3 | 62 | 3 | 0 | 69.8% | 90.0% | 76.9% | 0/0 |
| R16 | 109 | Francisco ClavetClay | 172 | Christian MiniussiClay | 6-3 6-3 | 3 | 95 | 0 | 3 | 61.4% | 51.4% | 68.2% | 7/10 |
| R16 | 90 | Alex CorretjaClay | 108 | Jean-Philippe FleurianClay | 6-1 6-2 | 3 | 75 | 3 | 0 | 60.4% | 72.4% | 73.7% | 5/5 |
| R16 | 45 | Alberto BerasateguiClay | 71 | Renzo FurlanClay | 6-2 6-2 | 3 | 54 | 1 | 1 | 46.2% | 94.4% | 71.4% | 0/0 |
| R16 | 59 | MARYounes El AynaouiClay | 87 | Jaime OncinsClay | 6-2 3-6 6-3 | 3 | 138 | 3 | 8 | 52.9% | 82.2% | 45.0% | 6/8 |
| R16 | 94 | Gilbert SchallerClay | 41 | Emilio SanchezClay | 6-4 2-6 6-0 | 3 | 121 | 0 | 0 | 83.8% | 53.7% | 76.9% | 7/11 |
| R16 | 96 | Slava DosedelClay | 125 | Daniel OrsanicClay | 6-3 6-4 | 3 | 103 | 2 | 0 | 59.4% | 52.6% | 57.7% | 2/5 |
| R16 | 98 | Jordi ArreseClay | 67 | Fabrice SantoroClay | 3-6 6-2 6-3 | 3 | 123 | 0 | 2 | 78.9% | 64.3% | 60.0% | 3/6 |
| R16 | 101 | Fernando MeligeniClay | 73 | Javier FranaClay | 5-7 6-4 6-1 | 3 | 147 | 2 | 4 | 46.6% | 81.3% | 34.5% | 13/17 |
| QF | 90 | Alex CorretjaClay | 109 | Francisco ClavetClay | 6-2 6-0 | 3 | 72 | 4 | 3 | 47.7% | 81.0% | 56.5% | 0/0 |
| QF | 45 | Alberto BerasateguiClay | 59 | MARYounes El AynaouiClay | 4-6 6-0 6-3 | 3 | 126 | 2 | 2 | 72.0% | 68.5% | 66.7% | 3/5 |
| QF | 96 | Slava DosedelClay | 94 | Gilbert SchallerClay | 6-3 6-4 | 3 | 94 | 4 | 2 | 62.7% | 70.3% | 68.2% | 1/2 |
| QF | 98 | Jordi ArreseClay | 101 | Fernando MeligeniClay | 5-7 7-5 6-4 | 3 | 205 | 3 | 7 | 69.2% | 64.4% | 45.0% | 16/20 |
| SF | 45 | Alberto BerasateguiClay | 90 | Alex CorretjaClay | 6-3 6-1 | 3 | 70 | 2 | 3 | 71.7% | 68.4% | 60.0% | 7/8 |
| SF | 96 | Slava DosedelClay | 98 | Jordi ArreseClay | 3-6 6-4 6-4 | 3 | 173 | 2 | 0 | 64.1% | 60.0% | 60.7% | 2/6 |
| F | 45 | Alberto BerasateguiClay | 96 | Slava DosedelClay | 6-4 6-3 | 3 | 89 | 1 | 1 | 70.2% | 55.0% | 52.9% | 4/7 |
