| R32 | 140 |  Joao SouzaClay | 91 |  Ruben Ramirez HidalgoClay | 7-6(6) RET | 3 | 67 | 7 | 1 | 66.7% | 88.5% | 76.9% | 1/1 |
| R32 | 92 |  Guido PellaClay | 44 |  Fabio FogniniClay | 7-6(6) 1-6 6-1 | 3 | 93 | 7 | 4 | 60.0% | 72.9% | 53.1% | 2/5 |
| R32 | 93 | David NalbandianClay | 191 |  Jorge AguilarClay | 7-5 5-7 6-3 | 3 | 132 | 11 | 5 | 61.4% | 77.4% | 51.3% | 2/5 |
| R32 | 151 | Paul CapdevilleClay | 43 | Horacio ZeballosClay | 6-7(5) 6-0 3-0 RET | 3 | 76 | 8 | 2 | 66.7% | 86.8% | 57.9% | 1/1 |
| R32 | 78 | Carlos BerlocqClay | 81 |  Andrey KuznetsovClay | 6-3 6-4 | 3 | 72 | 7 | 1 | 55.4% | 83.9% | 72.0% | 3/3 |
| R32 | 52 | Albert Ramos-VinolasClay | 83 | Guillermo Garcia-LopezClay | 6-3 7-5 | 3 | 97 | 3 | 2 | 62.9% | 71.8% | 34.8% | 1/4 |
| R32 | 111 | Martin AlundClay | 346 | Ricardo MelloClay | 6-4 6-4 | 3 | 94 | 2 | 2 | 67.1% | 73.5% | 50.0% | 5/6 |
| R32 | 88 | Filippo VolandriClay | 60 | Daniel Gimeno-TraverClay | 6-3 3-6 7-6(6) | 3 | 123 | 0 | 2 | 73.1% | 60.5% | 67.9% | 7/11 |
| R32 | 35 | Thomaz BellucciClay | 234 | Guilherme ClezarClay | 7-6(4) 5-7 7-6(1) | 3 | 157 | 19 | 13 | 53.2% | 81.0% | 47.1% | 2/6 |
| R32 | 46 | Pablo AndujarClay | 68 |  Santiago GiraldoClay | 6-4 7-6(5) | 3 | 98 | 3 | 3 | 56.7% | 73.7% | 62.1% | 0/1 |
| R32 | 96 | Albert MontanesClay | 58 | Paolo LorenziClay | 6-4 6-4 | 3 | 87 | 4 | 2 | 60.6% | 67.5% | 69.2% | 0/0 |
| R32 | 80 | Simone BolelliClay | 94 | Tommy RobredoClay | 6-2 6-4 | 3 | 77 | 3 | 2 | 53.7% | 82.8% | 64.0% | 2/2 |
| R16 | 5 | Rafael NadalClay | 140 | Joao SouzaClay | 6-3 6-4 | 3 | 79 | 5 | 1 | 71.2% | 76.2% | 64.7% | 1/1 |
| R16 | 78 | Carlos BerlocqClay | 52 | Albert Ramos-VinolasClay | 7-6(7) 6-4 | 3 | 120 | 7 | 7 | 62.3% | 79.2% | 48.3% | 2/3 |
| R16 | 111 | Martin AlundClay | 25 |  Jeremy ChardyClay | 6-4 4-6 7-6(5) | 3 | 156 | 5 | 4 | 57.0% | 70.5% | 58.7% | 4/6 |
| R16 | 88 | Filippo VolandriClay | 35 | Thomaz BellucciClay | 6-3 6-2 | 3 | 70 | 1 | 0 | 70.2% | 69.7% | 57.1% | 4/6 |
| R16 | 96 | Albert MontanesClay | 46 | Pablo AndujarClay | 7-5 6-2 | 3 | 94 | 4 | 3 | 58.0% | 74.5% | 50.0% | 7/7 |
| R16 | 80 | Simone BolelliClay | 15 | Juan MonacoClay | 7-5 6-2 | 3 | 76 | 3 | 0 | 65.4% | 70.6% | 83.3% | 0/1 |
| R16 | 93 | David NalbandianClay | 92 | Guido PellaClay | 6-4 6-2 | 3 | 63 | 8 | 2 | 67.4% | 89.7% | 71.4% | 0/0 |
| R16 | 11 | Nicolas AlmagroClay | 151 | Paul CapdevilleClay | 6-4 6-7(3) 6-2 | 3 | 106 | 18 | 2 | 48.2% | 82.9% | 54.5% | 1/3 |
| QF | 5 | Rafael NadalClay | 78 | Carlos BerlocqClay | 3-6 6-4 6-4 | 3 | 145 | 5 | 3 | 57.3% | 80.9% | 45.7% | 3/6 |
| QF | 111 | Martin AlundClay | 88 | Filippo VolandriClay | 7-5 7-6(5) | 3 | 104 | 8 | 0 | 64.4% | 80.9% | 53.8% | 3/4 |
| QF | 80 | Simone BolelliClay | 96 | Albert MontanesClay | 6-4 6-4 | 3 | 86 | 9 | 2 | 67.3% | 78.4% | 44.4% | 0/1 |
| QF | 93 | David NalbandianClay | 11 | Nicolas AlmagroClay | 7-6(5) 3-6 7-6(3) | 3 | 138 | 5 | 6 | 65.4% | 80.0% | 51.4% | 9/11 |
| SF | 5 | Rafael NadalClay | 111 | Martin AlundClay | 6-3 6-7(2) 6-1 | 3 | 117 | 5 | 2 | 67.5% | 90.7% | 53.8% | 2/2 |
| SF | 93 | David NalbandianClay | 80 | Simone BolelliClay | 6-3 7-5 | 3 | 85 | 11 | 3 | 54.2% | 78.1% | 44.4% | 1/4 |
| F | 5 | Rafael NadalClay | 93 | David NalbandianClay | 6-2 6-3 | 3 | 78 | 3 | 4 | 60.3% | 65.7% | 47.8% | 2/4 |
