| R32 | 85 |  Rui MachadoClay | 238 |  Facundo BagnisClay | 6-4 6-2 | 3 | 102 | 2 | 1 | 75.7% | 71.7% | 47.1% | 7/7 |
| R32 | 131 |  Joao SouzaClay | 719 | Guilherme ClezarClay | 6-3 6-2 | 3 | 71 | 5 | 1 | 68.8% | 75.8% | 86.7% | 1/1 |
| R32 | 88 |  Filippo VolandriClay | 56 |  Victor HanescuClay | 7-5 6-1 | 3 | 88 | 0 | 2 | 76.4% | 69.1% | 47.1% | 2/3 |
| R32 | 66 | Carlos BerlocqClay | 403 | Andre GhemClay | 6-4 6-3 | 3 | 89 | 2 | 2 | 54.0% | 85.2% | 60.9% | 1/1 |
| R32 | 103 |  Lukasz KubotClay | 111 | Eduardo SchwankClay | 6-7(5) 7-5 7-6(2) | 3 | 189 | 6 | 5 | 55.9% | 78.8% | 48.1% | 4/7 |
| R32 | 39 | Juan Ignacio ChelaClay | 160 | Rogerio Dutra SilvaClay | 6-7(4) 7-6(4) 6-3 | 3 | 177 | 2 | 1 | 75.0% | 74.7% | 56.0% | 1/2 |
| R32 | 46 | Potito StaraceClay | 63 |  Pablo CuevasClay | 6-4 5-7 6-4 | 3 | 129 | 3 | 1 | 82.4% | 72.9% | 40.0% | 1/5 |
| R32 | 109 | Leonardo MayerClay | 73 |  Igor AndreevClay | 4-6 6-4 7-6(2) | 3 | 154 | 4 | 5 | 57.3% | 76.4% | 56.1% | 6/8 |
| R32 | 79 |  Ruben Ramirez HidalgoClay | 244 | Fernando RomboliClay | 6-4 6-2 | 3 | 78 | 2 | 2 | 57.7% | 80.0% | 54.5% | 0/1 |
| R32 | 31 | Tommy RobredoClay | 54 | Fabio FogniniClay | 6-3 6-7(4) 6-3 | 3 | 151 | 9 | 1 | 62.6% | 75.4% | 67.6% | 3/5 |
| R32 | 69 | Pablo AndujarClay | 58 | Daniel Gimeno-TraverClay | 6-3 6-1 | 3 | 78 | 0 | 0 | 74.0% | 67.6% | 69.2% | 1/1 |
| R32 | 78 | Ricardo MelloClay | 47 |  Santiago GiraldoClay | 6-4 6-3 | 3 | 73 | 2 | 0 | 59.7% | 78.4% | 56.0% | 5/6 |
| R16 | 13 | Nicolas AlmagroClay | 131 | Joao SouzaClay | 6-2 6-2 | 3 | 71 | 7 | 1 | 41.2% | 85.7% | 56.7% | 1/1 |
| R16 | 85 | Rui MachadoClay | 88 | Filippo VolandriClay | 6-2 6-1 | 3 | 72 | 0 | 1 | 84.2% | 75.0% | 66.7% | 0/0 |
| R16 | 37 | Thomaz BellucciClay | 66 | Carlos BerlocqClay | 6-4 7-5 | 3 | 104 | 6 | 3 | 60.0% | 86.1% | 41.7% | 2/4 |
| R16 | 39 | Juan Ignacio ChelaClay | 103 | Lukasz KubotClay | 3-6 7-5 6-3 | 3 | 164 | 1 | 1 | 62.2% | 63.9% | 45.9% | 7/12 |
| R16 | 46 | Potito StaraceClay | 109 | Leonardo MayerClay | 6-4 7-6(9) | 3 | 109 | 2 | 0 | 77.2% | 70.5% | 61.1% | 1/1 |
| R16 | 32 |  Alexandr DolgopolovClay | 79 | Ruben Ramirez HidalgoClay | 7-5 6-4 | 3 | 97 | 14 | 1 | 59.1% | 79.5% | 63.0% | 2/2 |
| R16 | 69 | Pablo AndujarClay | 31 | Tommy RobredoClay | 6-4 5-7 6-2 | 3 | 152 | 1 | 2 | 70.6% | 61.0% | 59.4% | 8/11 |
| R16 | 78 | Ricardo MelloClay | 25 | Albert MontanesClay | 6-3 6-3 | 3 | 66 | 2 | 0 | 62.8% | 88.9% | 75.0% | 0/0 |
| QF | 13 | Nicolas AlmagroClay | 85 | Rui MachadoClay | 6-2 6-4 | 3 | 86 | 12 | 9 | 47.2% | 79.4% | 42.1% | 6/8 |
| QF | 39 | Juan Ignacio ChelaClay | 37 | Thomaz BellucciClay | 6-1 6-2 | 3 | 81 | 0 | 1 | 64.2% | 70.6% | 63.2% | 3/3 |
| QF | 32 | Alexandr DolgopolovClay | 46 | Potito StaraceClay | 6-3 6-4 | 3 | 74 | 10 | 3 | 47.6% | 80.0% | 51.5% | 6/7 |
| QF | 78 | Ricardo MelloClay | 69 | Pablo AndujarClay | 6-1 6-0 | 3 | 59 | 4 | 0 | 67.4% | 72.4% | 71.4% | 1/1 |
| SF | 13 | Nicolas AlmagroClay | 39 | Juan Ignacio ChelaClay | 1-6 6-2 6-4 | 3 | 99 | 4 | 0 | 65.2% | 73.3% | 58.3% | 2/4 |
| SF | 32 | Alexandr DolgopolovClay | 78 | Ricardo MelloClay | 6-2 6-1 | 3 | 59 | 4 | 2 | 60.9% | 82.1% | 55.6% | 3/3 |
| F | 13 | Nicolas AlmagroClay | 32 | Alexandr DolgopolovClay | 6-3 7-6(3) | 3 | 89 | 3 | 1 | 54.9% | 76.9% | 62.5% | 0/0 |
