| R32 | 18 |  Nicolas AlmagroClay | 161 |  Ricardo HocevarClay | 7-6(4) 7-5 | 3 | 103 | 11 | 3 | 51.6% | 93.9% | 64.5% | 0/0 |
| R32 | 69 |  Martin Vassallo ArguelloClay | 83 |  Nicolas MassuClay | 7-6(4) 2-6 6-4 | 3 | 186 | 2 | 4 | 67.8% | 64.1% | 45.9% | 6/11 |
| R32 | 86 |  Fred GilClay | 96 | Pablo AndujarClay | 3-6 6-4 6-3 | 3 | 154 | 4 | 3 | 52.2% | 60.4% | 61.4% | 6/9 |
| R32 | 47 | Marcel GranollersClay | 544 | Flavio SarettaClay | 6-2 2-6 6-1 | 3 | 122 | 3 | 2 | 51.3% | 70.0% | 47.4% | 6/9 |
| R32 | 101 | Juan Carlos FerreroClay | 42 | Albert MontanesClay | 6-7(4) 6-2 6-2 | 3 | 131 | 5 | 4 | 70.3% | 70.4% | 50.0% | 8/11 |
| R32 | 87 | Brian DabulClay | 94 | Paul CapdevilleClay | 6-1 RET | 3 | 31 | 2 | 1 | 78.9% | 93.3% | 50.0% | 0/0 |
| R32 | 197 |  Lukasz KubotClay | 90 | Daniel Gimeno-TraverClay | 7-6(7) 1-6 6-3 | 3 | 148 | 2 | 4 | 61.0% | 63.9% | 53.8% | 7/11 |
| R32 | 84 | Thomaz BellucciClay | 66 |  Potito StaraceClay | 6-3 6-4 | 3 | 83 | 7 | 5 | 51.8% | 89.7% | 51.9% | 0/1 |
| R32 | 52 | Eduardo SchwankClay | 77 | Diego JunqueiraClay | 6-1 7-5 | 3 | 91 | 3 | 2 | 63.8% | 64.9% | 71.4% | 0/1 |
| R32 | 151 | Rui MachadoClay | 75 | Ivan NavarroClay | 6-4 6-1 | 3 | 102 | 1 | 0 | 66.7% | 68.8% | 75.0% | 1/1 |
| R32 | 149 |  Pablo CuevasClay | 74 | Oscar HernandezClay | 4-6 6-4 6-1 | 3 | 126 | 8 | 1 | 66.3% | 71.7% | 63.0% | 2/4 |
| R32 | 41 | Jose AcasusoClay | 68 | Juan MonacoClay | 7-6(3) 6-4 | 3 | 117 | 2 | 1 | 52.1% | 81.6% | 62.9% | 4/5 |
| R32 | 64 |  Nicolas DevilderClay | 263 | Daniel Dutra da SilvaClay | 7-6(5) 6-2 | 3 | 111 | 2 | 3 | 69.3% | 67.3% | 60.9% | 7/9 |
| R32 | 93 | Alberto MartinClay | 85 |  Nicolas LapenttiClay | 6-4 7-5 | 3 | 94 | 2 | 0 | 63.9% | 82.1% | 50.0% | 2/3 |
| R32 | 92 | Fabio FogniniClay | 255 | Caio ZampieriClay | 0-6 7-6(5) 6-2 | 3 | 114 | 3 | 2 | 48.1% | 61.5% | 52.4% | 2/7 |
| R32 | 19 | Tommy RobredoClay | 125 | Thiago AlvesClay | 6-4 6-2 | 3 | 73 | 5 | 1 | 69.0% | 86.2% | 84.6% | 0/0 |
| R16 | 18 | Nicolas AlmagroClay | 69 | Martin Vassallo ArguelloClay | 6-4 6-4 | 3 | 93 | 5 | 2 | 54.5% | 72.2% | 46.7% | 4/6 |
| R16 | 86 | Fred GilClay | 47 | Marcel GranollersClay | 7-5 3-6 6-3 | 3 | 157 | 0 | 2 | 62.9% | 67.2% | 52.8% | 4/7 |
| R16 | 101 | Juan Carlos FerreroClay | 87 | Brian DabulClay | 6-1 6-2 | 3 | 73 | 3 | 0 | 62.2% | 75.0% | 70.6% | 1/1 |
| R16 | 84 | Thomaz BellucciClay | 197 | Lukasz KubotClay | 5-7 6-4 6-4 | 3 | 149 | 18 | 2 | 53.8% | 71.4% | 64.3% | 3/6 |
| R16 | 52 | Eduardo SchwankClay | 151 | Rui MachadoClay | 2-6 7-6(4) 7-6(6) | 3 | 188 | 5 | 5 | 58.1% | 61.8% | 40.8% | 3/10 |
| R16 | 41 | Jose AcasusoClay | 149 | Pablo CuevasClay | 6-3 6-2 | 3 | 77 | 2 | 0 | 61.5% | 75.0% | 70.0% | 2/2 |
| R16 | 93 | Alberto MartinClay | 64 | Nicolas DevilderClay | 6-2 7-6(4) | 3 | 109 | 1 | 3 | 64.6% | 66.0% | 62.1% | 9/9 |
| R16 | 19 | Tommy RobredoClay | 92 | Fabio FogniniClay | 6-2 6-2 | 3 | 64 | 3 | 2 | 66.0% | 87.1% | 43.8% | 4/4 |
| QF | 86 | Fred GilClay | 18 | Nicolas AlmagroClay | 7-6(5) 7-6(4) | 3 | 125 | 6 | 3 | 68.5% | 79.4% | 34.5% | 9/11 |
| QF | 84 | Thomaz BellucciClay | 101 | Juan Carlos FerreroClay | 7-6(5) 1-6 6-3 | 3 | 146 | 13 | 7 | 66.4% | 74.6% | 36.1% | 7/11 |
| QF | 41 | Jose AcasusoClay | 52 | Eduardo SchwankClay | 6-4 6-3 | 3 | 100 | 4 | 1 | 51.7% | 64.5% | 51.7% | 7/9 |
| QF | 19 | Tommy RobredoClay | 93 | Alberto MartinClay | 6-2 6-2 | 3 | 61 | 2 | 0 | 63.4% | 84.6% | 80.0% | 2/2 |
| SF | 84 | Thomaz BellucciClay | 86 | Fred GilClay | 7-6(3) 7-6(4) | 3 | 136 | 3 | 1 | 57.7% | 85.4% | 63.3% | 3/4 |
| SF | 19 | Tommy RobredoClay | 41 | Jose AcasusoClay | 6-2 6-1 | 3 | 63 | 6 | 1 | 71.7% | 78.8% | 61.5% | 2/2 |
| F | 19 | Tommy RobredoClay | 84 | Thomaz BellucciClay | 6-3 3-6 6-4 | 3 | 133 | 1 | 4 | 57.3% | 68.1% | 62.9% | 3/5 |
