| QF | 27 |  Juan Carlos FerreroClay | 85 |  Potito StaraceClay | 5-7 6-2 6-2 | 3 | 110 | 0 | 0 | 75.0% | 76.5% | 70.6% | 3/5 |
| QF | 152 |  Flavio SarettaClay | 31 | Nicolas AlmagroClay | 6-4 6-4 | 3 | 87 | 1 | 1 | 69.1% | 74.5% | 52.4% | 5/6 |
| QF | 39 |  Juan Ignacio ChelaClay | 69 | Juan MonacoClay | 6-4 2-6 7-5 | 3 | 127 | 3 | 5 | 54.8% | 80.4% | 44.7% | 1/4 |
| QF | 107 | Guillermo CanasClay | 28 | Agustin CalleriClay | 7-6(3) 6-1 | 3 | 85 | 4 | 3 | 58.0% | 82.8% | 66.7% | 0/1 |
| SF | 27 | Juan Carlos FerreroClay | 152 | Flavio SarettaClay | 6-2 6-4 | 3 | 92 | 1 | 2 | 68.7% | 65.2% | 61.9% | 4/5 |
| SF | 107 | Guillermo CanasClay | 39 | Juan Ignacio ChelaClay | 7-6(6) 6-1 | 3 | 123 | 2 | 0 | 54.5% | 75.0% | 40.0% | 3/5 |
| F | 107 | Guillermo CanasClay | 27 | Juan Carlos FerreroClay | 7-6(4) 6-2 | 3 | 121 | 5 | 3 | 52.8% | 81.6% | 50.0% | 4/5 |
| R32 | 27 | Juan Carlos FerreroClay | 77 | Sergio RoitmanClay | 6-4 6-4 | 3 | 95 | 3 | 4 | 73.9% | 74.5% | 38.9% | 4/5 |
| R32 | 104 |  Nicolas DevilderClay | 213 | Rogerio Dutra SilvaClay | 6-1 6-3 | 3 | 77 | 2 | 0 | 72.9% | 74.3% | 61.5% | 0/0 |
| R32 | 62 | Martin Vassallo ArguelloClay | 112 | Olivier PatienceClay | 6-4 6-3 | 3 | 94 | 5 | 0 | 65.3% | 69.4% | 57.7% | 6/6 |
| R32 | 85 | Potito StaraceClay | 37 | Gaston GaudioClay | 6-4 6-3 | 3 | 76 | 2 | 1 | 80.4% | 73.2% | 60.0% | 1/3 |
| R32 | 31 | Nicolas AlmagroClay | 111 | Fernando VicenteClay | 6-0 6-1 | 3 | 58 | 1 | 1 | 71.4% | 80.0% | 58.3% | 3/3 |
| R32 | 120 |  Lukas DlouhyClay | 147 |  Igor AndreevClay | W/O | 3 | 58 | 1 | 1 | 71.4% | 80.0% | 58.3% | 3/3 |
| R32 | 152 | Flavio SarettaClay | 98 | Alessio Di MauroClay | 6-1 6-2 | 3 | 74 | 1 | 3 | 52.0% | 84.6% | 50.0% | 5/6 |
| R32 | 1076 | Gustavo KuertenClay | 44 | Filippo VolandriClay | 6-3 6-1 | 3 | 47 | 13 | 1 | 79.5% | 93.5% | 37.5% | 0/0 |
| R32 | 39 | Juan Ignacio ChelaClay | 56 | Alberto MartinClay | 6-4 6-2 | 3 | 87 | 1 | 1 | 66.0% | 81.8% | 64.7% | 0/0 |
| R32 | 57 | Ruben Ramirez HidalgoClay | 113 | Stefano GalvaniClay | 7-6(4) 6-3 | 3 | 111 | 5 | 3 | 59.1% | 82.1% | 51.9% | 4/5 |
| R32 | 69 | Juan MonacoClay | 101 | Jiri VanekClay | 6-3 4-6 6-3 | 3 | 130 | 4 | 1 | 66.3% | 66.0% | 51.9% | 4/8 |
| R32 | 131 | Thiago AlvesClay | 36 | Carlos MoyaClay | 2-6 7-5 6-3 | 3 | 120 | 3 | 3 | 66.3% | 67.9% | 48.1% | 1/6 |
| R32 | 133 | Albert PortasClay | 305 | Eduardo SchwankClay | 6-2 6-2 | 3 | 62 | 4 | 1 | 62.8% | 85.2% | 37.5% | 0/1 |
| R32 | 107 | Guillermo CanasClay | 160 | Marcos DanielClay | 6-1 6-4 | 3 | 71 | 5 | 3 | 68.5% | 83.8% | 52.9% | 0/0 |
| R32 | 78 | Albert MontanesClay | 216 | Pablo AndujarClay | 6-2 7-6(6) | 3 | 99 | 2 | 2 | 52.7% | 76.9% | 45.7% | 5/7 |
| R32 | 28 | Agustin CalleriClay | 118 | Diego HartfieldClay | 6-4 6-1 | 3 | 72 | 4 | 3 | 55.1% | 77.8% | 54.5% | 2/3 |
| R16 | 27 | Juan Carlos FerreroClay | 104 | Nicolas DevilderClay | 6-2 6-4 | 3 | 101 | 4 | 1 | 70.3% | 73.3% | 42.1% | 11/12 |
| R16 | 85 | Potito StaraceClay | 62 | Martin Vassallo ArguelloClay | 7-5 6-3 | 3 | 97 | 0 | 3 | 70.0% | 78.6% | 44.4% | 0/2 |
| R16 | 31 | Nicolas AlmagroClay | 120 | Lukas DlouhyClay | 6-3 6-3 | 3 | 59 | 8 | 5 | 75.5% | 85.0% | 38.5% | 2/2 |
| R16 | 152 | Flavio SarettaClay | 1076 | Gustavo KuertenClay | 6-2 3-6 7-5 | 3 | 179 | 5 | 4 | 54.4% | 75.5% | 46.3% | 5/7 |
| R16 | 39 | Juan Ignacio ChelaClay | 57 | Ruben Ramirez HidalgoClay | 6-2 6-3 | 3 | 101 | 0 | 3 | 52.8% | 71.4% | 48.0% | 4/6 |
| R16 | 69 | Juan MonacoClay | 131 | Thiago AlvesClay | 6-2 6-3 | 3 | 55 | 5 | 0 | 58.5% | 87.5% | 88.2% | 0/0 |
| R16 | 107 | Guillermo CanasClay | 133 | Albert PortasClay | 6-4 6-0 | 3 | 74 | 6 | 0 | 65.8% | 88.0% | 61.5% | 0/1 |
| R16 | 28 | Agustin CalleriClay | 78 | Albert MontanesClay | 3-6 6-3 6-4 | 3 | 108 | 9 | 4 | 48.6% | 77.1% | 51.4% | 2/6 |
