| R32 | 56 |  Ricardo MelloClay | 96 |  Albert MontanesClay | 3-6 6-4 6-4 | 3 | 122 | 4 | 3 | 56.2% | 74.6% | 45.7% | 8/10 |
| R32 | 227 |  Martin Vassallo ArguelloClay | 97 | Felix MantillaClay | 7-6(1) 4-6 6-3 | 3 | 177 | 3 | 1 | 64.1% | 65.2% | 67.6% | 4/8 |
| R32 | 84 | Santiago VenturaClay | 89 | Nicolas AlmagroClay | 4-6 6-4 6-1 | 3 | 98 | 4 | 3 | 57.9% | 65.9% | 53.1% | 4/8 |
| R32 | 126 | Alex CorretjaClay | 47 | David FerrerClay | 0-6 7-5 RET | 3 | 92 | 1 | 2 | 60.0% | 57.6% | 45.5% | 5/10 |
| R32 | 23 | Juan Ignacio ChelaClay | 91 |  Lars BurgsmullerClay | 6-4 6-0 | 3 | 73 | 1 | 1 | 57.1% | 82.1% | 38.1% | 5/7 |
| R32 | 60 | Agustin CalleriClay | 65 |  Potito StaraceClay | 6-1 6-1 | 3 | 52 | 10 | 1 | 56.1% | 91.3% | 50.0% | 1/1 |
| R32 | 86 | Alex CalatravaClay | 266 |  Juan Antonio MarinClay | 6-3 6-4 | 3 | 84 | 3 | 2 | 79.0% | 69.4% | 53.8% | 4/5 |
| R32 | 48 | Rafael NadalClay | 55 | Jose AcasusoClay | 7-6(1) 6-3 | 3 | 114 | 5 | 1 | 78.9% | 71.4% | 66.7% | 6/7 |
| R32 | 51 | Mariano ZabaletaClay | 75 | Mariano PuertaClay | 6-4 6-2 | 3 | 52 | 12 | 0 | 48.8% | 85.0% | 90.5% | 0/0 |
| R32 | 88 | Guillermo Garcia-LopezClay | 80 | Juan MonacoClay | 6-1 6-3 | 3 | 79 | 2 | 2 | 55.1% | 81.5% | 59.1% | 0/0 |
| R32 | 101 |  Paul-Henri MathieuClay | 95 | David SanchezClay | 6-4 6-0 | 3 | 82 | 1 | 3 | 62.5% | 66.7% | 61.1% | 2/3 |
| R32 | 61 | Alberto MartinClay | 41 | Filippo VolandriClay | 7-5 1-0 RET | 3 | 49 | 1 | 3 | 51.7% | 86.7% | 64.3% | 1/2 |
| R32 | 54 | Albert CostaClay | 83 | Oscar HernandezClay | 7-6(2) 4-6 4-4 RET | 3 | 173 | 4 | 3 | 62.5% | 58.5% | 61.5% | 8/13 |
| R32 | 123 | Edgardo MassaClay | 130 | Flavio SarettaClay | 6-3 6-1 | 3 | 73 | 2 | 1 | 54.7% | 69.0% | 50.0% | 8/10 |
| R32 | 159 | Andre SaClay | 183 | Julio SilvaClay | 6-2 6-4 | 3 | 82 | 0 | 1 | 73.7% | 61.9% | 46.7% | 2/5 |
| R32 | 155 |  Peter LuczakClay | 17 |  Fernando GonzalezClay | 3-6 6-3 7-5 | 3 | 116 | 6 | 2 | 72.7% | 70.8% | 51.9% | 9/11 |
| R16 | 56 | Ricardo MelloClay | 227 | Martin Vassallo ArguelloClay | 6-3 1-0 RET | 3 | 67 | 5 | 0 | 63.3% | 78.9% | 63.6% | 1/1 |
| R16 | 84 | Santiago VenturaClay | 126 | Alex CorretjaClay | 6-4 6-4 | 3 | 106 | 5 | 3 | 59.7% | 78.4% | 48.0% | 4/6 |
| R16 | 60 | Agustin CalleriClay | 23 | Juan Ignacio ChelaClay | 7-6(2) 6-1 | 3 | 90 | 8 | 3 | 56.9% | 78.8% | 60.0% | 0/1 |
| R16 | 48 | Rafael NadalClay | 86 | Alex CalatravaClay | 6-3 6-3 | 3 | 163 | 2 | 0 | 62.0% | 80.6% | 73.7% | 1/1 |
| R16 | 51 | Mariano ZabaletaClay | 88 | Guillermo Garcia-LopezClay | 6-2 6-2 | 3 | 63 | 2 | 2 | 57.4% | 77.8% | 50.0% | 0/1 |
| R16 | 61 | Alberto MartinClay | 101 | Paul-Henri MathieuClay | 6-2 7-5 | 3 | 96 | 3 | 6 | 42.9% | 70.4% | 52.8% | 2/5 |
| R16 | 123 | Edgardo MassaClay | 54 | Albert CostaClay | 6-7(3) 6-1 7-6(7) | 3 | 156 | 5 | 3 | 60.5% | 71.0% | 64.4% | 5/6 |
| R16 | 155 | Peter LuczakClay | 159 | Andre SaClay | 3-6 6-3 6-0 | 3 | 112 | 6 | 0 | 75.9% | 56.7% | 57.9% | 4/9 |
| QF | 56 | Ricardo MelloClay | 84 | Santiago VenturaClay | 7-5 6-1 | 3 | 80 | 6 | 4 | 52.7% | 72.4% | 53.8% | 1/3 |
| QF | 48 | Rafael NadalClay | 60 | Agustin CalleriClay | 6-2 6-7(5) 6-4 | 3 | 151 | 0 | 0 | 80.0% | 67.5% | 70.0% | 6/8 |
| QF | 61 | Alberto MartinClay | 51 | Mariano ZabaletaClay | 7-6(6) 6-4 | 3 | 136 | 4 | 6 | 52.2% | 79.2% | 43.2% | 5/7 |
| QF | 155 | Peter LuczakClay | 123 | Edgardo MassaClay | 1-6 7-5 6-1 | 3 | 109 | 2 | 0 | 74.4% | 65.6% | 66.7% | 4/6 |
| SF | 48 | Rafael NadalClay | 56 | Ricardo MelloClay | 2-6 6-2 6-4 | 3 | 151 | 0 | 2 | 74.7% | 59.3% | 55.0% | 2/6 |
| SF | 61 | Alberto MartinClay | 155 | Peter LuczakClay | 6-2 6-3 | 3 | 71 | 4 | 2 | 59.3% | 71.4% | 50.0% | 6/8 |
| F | 48 | Rafael NadalClay | 61 | Alberto MartinClay | 6-0 6-7(2) 6-1 | 3 | 126 | 0 | 2 | 67.6% | 62.0% | 50.0% | 5/8 |
