| R32 | 68 |  Luis HornaClay | 368 |  Pedro BragaClay | 6-3 6-2 | 3 | 73 | 7 | 3 | 57.1% | 71.4% | 52.4% | 1/2 |
| R32 | 103 |  Tomas BehrendClay | 7 |  Carlos MoyaClay | 6-3 6-3 | 3 | 74 | 4 | 2 | 68.3% | 73.2% | 63.2% | 4/5 |
| R32 | 80 | Ruben Ramirez HidalgoClay | 100 |  Harel LevyClay | 6-4 7-6(3) | 3 | 94 | 2 | 4 | 48.5% | 75.8% | 57.1% | 1/3 |
| R32 | 92 |  Jose AcasusoClay | 113 |  Christophe RochusClay | 6-3 6-4 | 3 | 73 | 5 | 1 | 54.4% | 80.6% | 57.7% | 3/4 |
| R32 | 43 |  Filippo VolandriClay | 32 | Felix MantillaClay | 6-2 6-2 | 3 | 66 | 2 | 1 | 65.1% | 67.9% | 73.3% | 3/4 |
| R32 | 17 | Gustavo KuertenClay | 90 | Oscar HernandezClay | 3-6 6-2 6-3 | 3 | 130 | 9 | 2 | 49.5% | 80.0% | 49.0% | 8/9 |
| R32 | 85 |  Richard GasquetClay | 242 | Franco FerreiroClay | 6-0 7-6(5) | 3 | 104 | 3 | 0 | 50.9% | 71.4% | 59.3% | 1/3 |
| R32 | 133 | Franco SquillariClay | 123 |  Jean-Rene LisnardClay | 6-2 7-5 | 3 | 85 | 2 | 6 | 47.6% | 73.3% | 51.5% | 3/5 |
| R32 | 34 | Gaston GaudioClay | 127 | Ricardo MelloClay | 6-2 6-4 | 3 | 89 | 3 | 3 | 63.0% | 82.4% | 55.0% | 2/2 |
| R32 | 41 | Juan Ignacio ChelaClay | 45 | Flavio SarettaClay | 6-2 6-2 | 3 | 79 | 0 | 1 | 60.9% | 75.0% | 61.1% | 1/2 |
| R32 | 67 | David FerrerClay | 63 |  Nicolas LapenttiClay | 6-4 5-2 RET | 3 | 83 | 1 | 1 | 60.4% | 62.5% | 57.1% | 2/4 |
| R32 | 108 | Fernando VerdascoClay | 141 | Guillermo CanasClay | 6-1 1-0 RET | 3 | 50 | 5 | 1 | 75.0% | 61.9% | 71.4% | 4/4 |
| R32 | 21 | Agustin CalleriClay | 86 | Albert PortasClay | 6-1 6-3 | 3 | 66 | 5 | 3 | 52.1% | 92.0% | 52.2% | 2/2 |
| R32 | 117 | Albert MontanesClay | 26 | Mariano ZabaletaClay | 6-4 6-1 | 3 | 65 | 4 | 3 | 63.3% | 87.1% | 55.6% | 1/1 |
| R32 | 87 | Galo BlancoClay | 56 | David SanchezClay | 6-3 7-6(5) | 3 | 101 | 4 | 1 | 58.5% | 71.1% | 59.3% | 0/2 |
| R32 | 184 | Juan MonacoClay | 13 |  Nicolas MassuClay | 6-4 6-2 | 3 | 103 | 1 | 2 | 68.3% | 65.9% | 57.9% | 2/3 |
| R16 | 103 | Tomas BehrendClay | 80 | Ruben Ramirez HidalgoClay | 6-2 6-2 | 3 | 82 | 2 | 4 | 50.9% | 81.5% | 61.5% | 3/3 |
| R16 | 92 | Jose AcasusoClay | 43 | Filippo VolandriClay | 7-6(4) 6-2 | 3 | 95 | 8 | 0 | 62.9% | 82.1% | 56.5% | 3/4 |
| R16 | 17 | Gustavo KuertenClay | 85 | Richard GasquetClay | 7-6(3) 6-3 | 3 | 89 | 4 | 4 | 55.9% | 86.8% | 56.7% | 3/4 |
| R16 | 133 | Franco SquillariClay | 34 | Gaston GaudioClay | 7-6(3) 6-3 | 3 | 102 | 4 | 7 | 46.6% | 70.6% | 46.2% | 6/10 |
| R16 | 41 | Juan Ignacio ChelaClay | 67 | David FerrerClay | 6-2 6-4 | 3 | 74 | 0 | 2 | 61.1% | 66.7% | 47.6% | 2/5 |
| R16 | 21 | Agustin CalleriClay | 108 | Fernando VerdascoClay | 6-4 6-4 | 3 | 98 | 6 | 1 | 58.3% | 80.0% | 64.0% | 2/2 |
| R16 | 87 | Galo BlancoClay | 117 | Albert MontanesClay | 6-2 7-6(4) | 3 | 97 | 4 | 6 | 57.5% | 73.8% | 61.3% | 7/7 |
| R16 | 68 | Luis HornaClay | 184 | Juan MonacoClay | 6-4 6-1 | 3 | 74 | 2 | 2 | 62.5% | 66.7% | 61.1% | 1/3 |
| QF | 92 | Jose AcasusoClay | 103 | Tomas BehrendClay | 0-6 6-2 6-4 | 3 | 105 | 5 | 5 | 48.7% | 75.7% | 43.6% | 2/5 |
| QF | 17 | Gustavo KuertenClay | 133 | Franco SquillariClay | 3-6 7-5 7-5 | 3 | 147 | 4 | 4 | 56.6% | 76.8% | 39.5% | 4/7 |
| QF | 21 | Agustin CalleriClay | 41 | Juan Ignacio ChelaClay | 6-3 3-6 6-3 | 3 | 139 | 6 | 6 | 59.6% | 67.7% | 40.5% | 9/13 |
| QF | 68 | Luis HornaClay | 87 | Galo BlancoClay | 6-1 7-6(5) | 3 | 75 | 5 | 2 | 66.7% | 73.5% | 70.6% | 0/2 |
| SF | 17 | Gustavo KuertenClay | 92 | Jose AcasusoClay | 6-4 6-3 | 3 | 78 | 8 | 1 | 49.0% | 79.2% | 60.0% | 1/3 |
| SF | 21 | Agustin CalleriClay | 68 | Luis HornaClay | 6-4 5-7 6-1 | 3 | 146 | 19 | 4 | 55.9% | 73.1% | 48.8% | 6/9 |
| F | 17 | Gustavo KuertenClay | 21 | Agustin CalleriClay | 3-6 6-2 6-3 | 3 | 115 | 8 | 3 | 56.9% | 82.9% | 48.4% | 4/6 |
