| R32 | 11 |  Fernando GonzalezClay | 71 |  Oscar HernandezClay | 6-2 6-1 | 3 | 59 | 6 | 1 | 47.7% | 95.2% | 56.5% | 1/1 |
| R32 | 156 | Ruben Ramirez HidalgoClay | 120 |  Victor CrivoiClay | 6-4 6-2 | 3 | 89 | 3 | 5 | 63.3% | 73.7% | 36.4% | 3/5 |
| R32 | 112 | Marcel GranollersClay | 99 |  Martin Vassallo ArguelloClay | 4-6 6-3 RET | 3 | 107 | 3 | 3 | 59.1% | 79.5% | 48.1% | 3/4 |
| R32 | 61 |  Lukasz KubotClay | 51 | Horacio ZeballosClay | 3-6 7-5 6-3 | 3 | 146 | 5 | 3 | 54.8% | 73.9% | 55.3% | 2/4 |
| R32 | 35 |  Thomaz BellucciClay | 97 |  Nicolas LapenttiClay | 3-6 6-1 6-1 | 3 | 106 | 3 | 4 | 60.7% | 75.7% | 45.8% | 1/4 |
| R32 | 143 | Paul CapdevilleClay | 395 | Cristobal Saavedra-CorvalanClay | 4-6 6-2 6-1 | 3 | 117 | 1 | 2 | 59.2% | 76.2% | 58.6% | 4/6 |
| R32 | 79 | Eduardo SchwankClay | 86 |  Paolo LorenziClay | 4-6 7-6(3) 6-3 | 3 | 191 | 3 | 4 | 72.3% | 69.8% | 42.4% | 8/11 |
| R32 | 49 | Jose AcasusoClay | 517 | Hans Podlipnik-CastilloClay | 6-1 6-1 | 3 | 55 | 6 | 1 | 66.7% | 86.4% | 81.8% | 0/0 |
| R32 | 208 | Joao SouzaClay | 63 |  Simon GreulClay | 3-6 6-4 7-6(5) | 3 | 144 | 4 | 2 | 64.6% | 65.6% | 57.1% | 4/7 |
| R32 | 119 | Pere RibaClay | 107 | Santiago VenturaClay | 6-3 7-5 | 3 | 92 | 3 | 3 | 58.2% | 71.8% | 46.4% | 1/3 |
| R32 | 129 | Alberto MartinClay | 89 | Marcos DanielClay | 6-7(5) 7-5 6-4 | 3 | 156 | 1 | 7 | 63.7% | 68.4% | 44.4% | 8/12 |
| R32 | 138 | Ricardo MelloClay | 47 |  Pablo CuevasClay | 7-6(5) 6-3 | 3 | 91 | 2 | 3 | 60.0% | 66.7% | 53.8% | 3/6 |
| R32 | 73 |  Peter LuczakClay | 64 | Potito StaraceClay | 7-6(3) 6-4 | 3 | 106 | 5 | 1 | 51.4% | 71.1% | 66.7% | 3/3 |
| R32 | 158 | David MarreroClay | 257 | Juan-Martin ArangurenClay | 7-6(4) 2-6 7-6(2) | 3 | 165 | 7 | 3 | 67.8% | 72.5% | 31.6% | 4/9 |
| R32 | 77 | Juan Ignacio ChelaClay | 223 | Jorge AguilarClay | 7-5 6-2 | 3 | 93 | 0 | 3 | 41.5% | 63.0% | 55.3% | 5/8 |
| R32 | 29 | Juan MonacoClay | 98 | Nicolas MassuClay | 6-3 6-4 | 3 | 105 | 6 | 2 | 56.1% | 81.1% | 48.3% | 6/7 |
| R16 | 11 | Fernando GonzalezClay | 156 | Ruben Ramirez HidalgoClay | 6-4 6-3 | 3 | 70 | 8 | 3 | 61.7% | 86.2% | 55.6% | 2/3 |
| R16 | 112 | Marcel GranollersClay | 61 | Lukasz KubotClay | 6-4 6-2 | 3 | 87 | 4 | 2 | 75.5% | 70.0% | 61.5% | 3/4 |
| R16 | 35 | Thomaz BellucciClay | 143 | Paul CapdevilleClay | 5-7 6-4 7-5 | 3 | 174 | 8 | 4 | 53.3% | 73.7% | 42.0% | 4/9 |
| R16 | 79 | Eduardo SchwankClay | 49 | Jose AcasusoClay | 6-7(3) 6-2 RET | 3 | 100 | 4 | 3 | 65.5% | 86.1% | 47.4% | 0/1 |
| R16 | 208 | Joao SouzaClay | 119 | Pere RibaClay | 6-4 6-4 | 3 | 88 | 3 | 3 | 62.3% | 73.7% | 47.8% | 3/5 |
| R16 | 129 | Alberto MartinClay | 138 | Ricardo MelloClay | 6-3 6-4 | 3 | 77 | 4 | 2 | 64.4% | 81.6% | 47.6% | 4/5 |
| R16 | 73 | Peter LuczakClay | 158 | David MarreroClay | 6-3 7-6(4) | 3 | 98 | 12 | 0 | 61.9% | 87.2% | 75.0% | 0/0 |
| R16 | 29 | Juan MonacoClay | 77 | Juan Ignacio ChelaClay | 6-3 7-5 | 3 | 89 | 5 | 4 | 59.2% | 71.4% | 48.3% | 6/9 |
| QF | 11 | Fernando GonzalezClay | 112 | Marcel GranollersClay | 7-6(8) 7-6(9) | 3 | 136 | 4 | 6 | 65.3% | 77.3% | 37.1% | 6/9 |
| QF | 35 | Thomaz BellucciClay | 79 | Eduardo SchwankClay | 6-4 6-4 | 3 | 77 | 6 | 1 | 78.0% | 84.6% | 63.6% | 0/0 |
| QF | 208 | Joao SouzaClay | 129 | Alberto MartinClay | 6-2 6-4 | 3 | 72 | 5 | 1 | 72.7% | 72.5% | 46.7% | 1/2 |
| QF | 29 | Juan MonacoClay | 73 | Peter LuczakClay | 6-4 3-6 6-3 | 3 | 117 | 11 | 5 | 63.5% | 79.6% | 45.2% | 8/10 |
| SF | 35 | Thomaz BellucciClay | 11 | Fernando GonzalezClay | 3-6 6-4 6-3 | 3 | 114 | 2 | 2 | 71.4% | 74.5% | 54.5% | 4/6 |
| SF | 29 | Juan MonacoClay | 208 | Joao SouzaClay | 6-1 6-4 | 3 | 74 | 5 | 3 | 45.6% | 76.9% | 61.3% | 1/2 |
| F | 35 | Thomaz BellucciClay | 29 | Juan MonacoClay | 6-2 0-6 6-4 | 3 | 125 | 5 | 4 | 65.6% | 59.0% | 46.9% | 9/13 |
